Environmental Sciences Commons^™

Detecting The Cause Of Acidification At A Seasonal Wetland On The Swan Coastal Plain, Western Australia, Through Laboratory And Field Mesocosm Experiments, Kelli O'Neill

Theses : Honours

Acidification (pH< 4.5) was detected at Lake Jandabup, a shallow, seasonal wetland on the Swan Coastal Plain. Western Australia. Concern has been raised because populations of invertebrate species have declined or disappeared since acidification, potentially compromising the status of the lake as a nature reserve. The Jake bed is underlain with pyrite (feS₂), which oxidises when dry producing sulfates, hydrogen ions and ferrous iron. Being seasonal, Lake Jandabup would be expected to be naturally acidic, but the more recent trend has been a prolonged (> 1 year) and extreme acidification (pH < 4.0). This study endeavoured to explain why the Jake may have undergone an acidic change, why it may have recovered and whether it will happen again. It was hypothesised that the acidification may have been caused by prolonged drying of the lake causing excessive oxidation of pyrite which produced more acid than the wetland could neutralise through buffering. The hypothesis was tested through laboratory and field experiments. The laboratory experiment involved taking intact sediment cores from around the lake, drying them for various lengths of time, and measuring pH, sulfate, total iron, total alkalinity and total aridity upon rehydration. Dried sediment from diatomaceous earth under Fe(OH)₃ precipitate gave the lowest pH of less than 4.0. High sulfates, low alkalinity and low pH were interrelated. While drying in its own right produced low pH, generally there was no significant difference between drying times for release of selected variables. The field experiment involved the establishment of small in situ mesocosms to test for the effects …