Environmental Sciences Commons^™

The Synthesis And Optimization Of Sulfide And Halide Solid Electrolytes For All Solid-State Batteries, Teerth Brahmbhatt

Doctoral Dissertations

Countries and organizations around the world have established ambitious targets to transition away from fossil fuel-based energy sources and devices. The transition is focused on cleaning up power generation by converting coal, natural gas, and oil-based power generation to renewables and nuclear energy. Decarbonizing other sectors of energy use, transportation for example, will require broader electrification. To drive this move away from fossil fuel powered transportation will require portable energy storage devices. Conventional lithium-ion batteries are a popular candidate to lead this shift. However, these batteries often rely on flammable liquid electrolytes and carbon anodes that suffer from low energy …

Heat Pump Integrated Thermal Storage For Building Demand Response And Decarbonization, Sara Sultan

Doctoral Dissertations

This work presents a novel thermal energy storage (TES) integrated with existing residential heat pump (HP). The research focuses on controls and configuration for energy, demand, cost and carbon emissions savings for residential buildings’ energy consumption. This work will be significant in developing a framework especially for reduced energy demand and carbon emissions associated with space heating and cooling in residential buildings. Since buildings account for about 40% primary energy consumption in U.S. and half of that is associated with HP.

An existing air source HP in integrated with a phase change material (PCM) based TES via active configuration where …

Impact Of Cover Crop Species Diversity On Soil Nutrient Availability And Crop Productivity, Amanda Kramer

Masters Theses

Cover crops provide multiple environmental benefits that improve both soil and water quality; however, farmers only utilize them on approximately 5% of harvested U.S. cropland. Low adoption rates are attributed to yield impact concerns, seed and planting costs, and lack of advocacy. This study, which began in October 2019, assessed the effects of nitrogen rate and cover crop diversity on weed biomass, soil coverage, in-situ residue decomposition, soil nitrogen and phosphorus availability, and cash crop yield to better understand the costs and benefits of cover crop adoption at two locations in Tennessee (Milan and Spring Hill). Treatments were replicated 4 …

Microplastic Accumulation In Terrestrial Gastropods And Soils, Gregory B. Bonilla

Masters Theses

Microplastics (MPs) have become an emerging threat to ecosystems across the world. Transport, impacts, and fates are grossly understudied, especially in terrestrial environments. Current research on MP bioaccumulation has focused mainly on aquatic organisms with little study of terrestrial organisms, including snails where data are nearly nonexistent. To address this, we collected and examined land snails and their surrounding soil for MP content in shell and tissue. From September 11, 2020, to October 25, 2021, cover boards were placed (n=30) along relatively undisturbed sites in hardwood, forested areas, and tall grasses in a Wildlife Management Area (WMA) in Oak Ridge …

Science Education To The Rescue? Assessing The Relationship Between Scientific Literacy And Carbon Emissions, Anthony Schmidt

Doctoral Dissertations

Human activities have radically changed the climate, negatively impacting all life on earth. The technical means to address this climate crisis exist, but there are major social and political hurdles that stand in the way. Education has been touted as one possible means for helping to move forward necessary action on climate change. A hybrid model of planned behavior and human capital helps explain how education can affect climate change. The current dissertation sought to assess what relationship may exist between changes in per capita carbon emissions and science education as measured by the Programme for International Student Achievement (PISA). …

The Characterization Of Dynamic Soil Properties And Their Relation To Soil Organic Carbon In East Tennessee Soils, Shannon Marissa Newell

Masters Theses

Quantifying how dynamic soil properties (DSPs) are affected by different management regimes is essential for understanding how these vital resources can be better managed. The Dewey soil series is a critical soil series in East Tennessee. For this study, the University of Tennessee, Knoxville (UTK) worked alongside the National Cooperative Soil Survey (NCSS) in an effort to better understand the dynamics of the Dewey soil series through a wide range of DSP data. To accomplish this, Dewey soil was collected from five sites which are considered representative of five management regimes: well-managed cropland (WMC), poorly-managed cropland (PMC), well-managed pasture (WMP), …

Evaluation Of Microbiometer As A Tool To Estimate Soil Health In A West Tennessee Cotton Crop, Daniel T. Sain

Masters Theses

Healthy soils are critical for optimized yields and sustainability in agriculture. Soil health testing can provide valuable information on how management practices are affecting soil health. In west Tennessee, existing soil health tests were unable to discern between significant differences in management practices. A new soil health test called microBIOMETER® has been developed by Prolific Earth Sciences® (Montgomery, NY). MicroBIOMETER® utilizes a new methodology for estimating microbial biomass and uses that estimate as a soil health score. This test has not been validated for use in west Tennessee. This research was focused on the validation of microBIOMETER® in a continuous …

Assessment Of Soil Health Under Native Warm-Season Grasses And Different Grazing Management, Kara Leigh Grosso

Masters Theses

This research uses analysis of soil quality indicators (SQIs) to compare vegetation species and grazing management over the 2021 grazing season. The soil health effect of the native warm-season grasses (NWSG) big bluestem (BB) (Andropogon gerardii) mixed with indian grass (IG) (Sorghastrum nutans) (BBIG), and switchgrass (SG) (Panicum virgatum), inter-seeded with a 12 species biodiversity mix was investigated in a 5 pressure grazing system (no graze (NG), no rest (NR), early, middle, and late rest (ER, MR, LR)). Additionally, there is a need for inexpensive tools for land owners to assess soil quality, and a validation study …

A Connectivity Framework To Explore The Role Of Anthropogenic Activity And Climate On The Propagation Of Water And Sediment At The Catchment Scale, Christos Giannopoulos

Doctoral Dissertations

Anthropogenic disturbance in intensively managed landscapes (IMLs) has dramatically altered critical zone processes, resulting in fundamental changes in material fluxes. Mitigating the negative effects of anthropogenic disturbance and making informed decisions for optimal placement and assessment of best management practices (BMPs) requires fundamental understanding of how different practices affect the connectivity or lack thereof of governing transport processes and resulting material fluxes across different landscape compartments within the hillslope-channel continuum of IMLs. However, there are no models operating at the event timescale that can accurately predict material flux transport from the hillslope to the catchment scale capturing the spatial and …

Birds And Bioenergy: A Modeling Framework For Managed Landscapes At Multiple Spatial Scales, Jasmine Asha Kreig

Doctoral Dissertations

This dissertation examines the design and management of bioenergy landscapes at multiple spatial scales given numerous objectives. Objectives include biodiversity outcomes, biomass feedstock yields, and economic value.

Our study examined biodiversity metrics for 25 avian species in Iowa, including subsets of these species related to ecosystem services. We used our species distribution model (SDM) framework to determine the importance of predictors related to switchgrass production on species richness. We found that distance to water, mean diurnal temperature range, and herbicide application rate were the three most important predictors of biodiversity overall. We found that 76% of species responded positively to …

Investigation Of Interactions Between 1,3 Dialkyl Imidazolium Ionic Liquids And Lignocellulosic Polymers, Aparna Annamraju

Doctoral Dissertations

Lignocellulosic biomass is a potential energy source for fuels, chemicals and materials production in a sustainable manner. A network of covalent and non-covalent bonds between the three main polymers of biomass, i.e., cellulose, hemicellulose and lignin, results in a compact structure that is resistant to chemical and biological attacks and therefore challenging for the efficient utilization of lignocellulosic biomass. Ionic liquids (ILs) have been reported to disrupt the bonds between these polymers and dissolve biomass at temperatures below 100 ˚C. Research through the years has shown that biomass pretreatment with IL brings out the selective dissolution of biomass polymers and …

Future Energy: Opportunities & Challenges, Thomas W. Kerlin

Open Textbooks

Future Energy: Opportunities & Challenges was originally published in 2013 by the International Society of Automation. Rights for this work have been reverted to the authors by the original publisher. The author has chosen to license this work with a Creative Commons Attribution 4.0 International license (see https://creativecommons.org/licenses/by/4.0/).

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Conservation Agriculture As A Climate Change Mitigation Strategy In Zimbabwe, Deb O'Dell, Neal Eash, Bruce B. Hicks, Joel Oetting, Thomas J. Sauer, Dayton M. Lambert, Tarirai Muoni, Joanne Logan, James A. Zahn, John J. Goddard

Biosystems Engineering and Soil Science Publications and Other Works

There is a need to quantify agriculture’s potential to sequester carbon (C) to inform global approaches aimed at mitigating climate change effects. Many factors including climate, crop, soil management practices, and soil type can influence the contribution of agriculture to the global carbon cycle. The objective of this study was to investigate the C sequestration potential of conservation agriculture (CA) (defined by minimal soil disturbance, maintaining permanent soil cover, and crop rotations). This study used micrometeorological methods to measure carbon dioxide (CO₂) flux from several alternative CA practices in Harare, central Zimbabwe. Micrometeorological methods can detect differences in …

Ecosystem Services Of Urban Tree Canopy For The Mitigation Of Climate Change: Measuring Carbon Sequestration And Understory Temperature Reduction Of Knoxville’S Urban Forest, Tyler Hounshell

Pursuit - The Journal of Undergraduate Research at The University of Tennessee

In the future, the city of Knoxville, Tennessee will be impacted by climate warming due to anthropogenic climate change. Yet, the ecosystem services provided by urban tree canopy in Knoxville’s urban forest can help mitigate the effects of climate warming. In addition to improving air quality, regulating water flow, and reducing noise pollution, Knoxville’s urban forest serves as a carbon sink and sequesters carbon dioxide on an annual basis. Utilizing methods for calculating carbon sequestration by trees in urban and suburban settings developed by the U.S. Energy Information Administration, the sequestration potential and its uncertainty is calculated until the year …

Supply Chain Sustainability: Understanding The Financial Impact, Matthew J. Guinn

EURēCA: Exhibition of Undergraduate Research and Creative Achievement

The purpose of this study is to determine if there is a differential impact on the financial performance of a company between environmental and social events.

This study uses a randomization of publicly traded companies within specific, pre-determined SIC codes, which is a collection of 66 companies, split between manufacturing and retail, to get the most accurate representation.

This study utilizes multiple regression models via STATA to analyze data compiled from the Wharton Research Database Services (WRDS) utilizing the MSCI ESG KLD, and Bloomberg, to analyze the percent increase in stock price which is the overarching models independent variable. Then, …

Development Of High-Performing Polydimethylsiloxane-Based Membranes For Carbon Dioxide Separation, Tao Hong

Doctoral Dissertations

Membrane separation is highlighted as one of the most promising approaches to mitigate the excessive CO₂ [carbon dioxide] emission, due to its significant reduction of energy cost compared with many conventional separation techniques. Unfortunately, the separation performance of current membranes does not meet the practical CO₂/N₂ [nitrogen] separation requirements. And due to the huge volume of industrial flue gas, membranes with exceptionally high permeability are needed for practical reasons.

Currently, the separation mechanism of most polymeric membranes is based on size-sieving. However, this method is not sufficient for CO₂/N₂ separations due to the …

Effects Of Switchgrass Related Land-Use Changes On Aquatic Macroinvertebrates, Latha Malar Baskaran

Doctoral Dissertations

This research examines if switchgrass-based land-management practices have the potential to influence aquatic macroinvertebrates through changes in stream flow and water quality. The number of taxa in Ephemeroptera, Plecoptera, and Trichoptera orders (EPT taxa richness/EPT-TR) is analyzed as an aquatic macroinvertebrate bioindicator in the context of regional environmental effects, and changes in stream flow and water quality. This dissertation is structured as three manuscripts that link together to address the overall research question.

The first manuscript focuses on identifying regional environmental variables that influence EPT-TR across ecoregions in Tennessee. The influences of temperature, precipitation, geology, soil, stream flow and velocity …

Sustainability Education In Primary And Secondary Schools: Great Needs And Possible Solutions, Allison Watson

Chancellor’s Honors Program Projects

No abstract provided.

Lignin-Based Li-Ion Anode Materials Synthesized From Low-Cost Renewable Resources, Nicholas William Mcnutt

Doctoral Dissertations

In today’s world, the demand for novel methods of energy storage is increasing rapidly, particularly with the rise of portable electronic devices, electric vehicles, and the personal consumption and storage of solar energy. While other technologies have arguably improved at a rate that is exponential in accordance with Moore’s law, battery technology has lagged behind largely due to the difficulty in devising new electric storage systems that are simultaneously high performing, inexpensive, and safe.

In order to tackle these challenges, novel Li-ion battery anodes have been developed at Oak Ridge National Laboratory that are made from lignin, a low-cost, renewable …

Mathematical Approaches To Sustainability Assessment And Protocol Development For The Bioenergy Sustainability Target Assessment Resource (Bio-Star), Nathan Louis Pollesch

Doctoral Dissertations

Bioenergy is renewable energy made of materials derived from biological, non-fossil sources. In addition to the benefits of utilizing an energy source that is renewable, bioenergy is being researched for its potential positive impact on climate change mitigation, job creation, and regional energy security. It has also been studied to investigate possible challenges related to indirect and direct land-use change and food security. Bioenergy sustainability assessment provides a method to identify, quantify, and interpret indicators, or metrics, of bioenergy sustainability in order to study trade-offs between environmental, social, and economic aspects of bioenergy production and use. Assessment is crucial to …

Opportunities In Sustainability: Maize Seeders For The Developing World And Alternative Fertilizers In The United States, Rebecca Mattingly Harman

Masters Theses

Sustainable agricultural systems are needed for both large and small-scale farmers the world over. Central to the sustainability of these systems is the availability of cheap and effective seeders for smallholder farmers and effective utilization of less energy intensive nitrogen sources. In the first two chapters, this thesis considers maize seeders for smallholder use in a Conservation Agriculture system. To sustain the smallholder sector, soil fertility and soil erosion must be addressed and a Conservation Agriculture model seeks to improve soil conditions in agriculture. The technologies available to smallholder farmers, though, need to be tested in a no-till system before …

Impacts Of Biofumigation And Anaerobic Soil Disinfestation On Strawberry Production, Jennifer Renee’ Wheeler

Masters Theses

Due to the phase-out of methyl bromide, there is a need for alternative, nonchemical fumigation treatments in strawberry production. Anaerobic soil disinfestation and biofumigation are two non-chemical methods for controlling soilborne plant pathogens of strawberry. This study was designed to observe strawberry fruit nutrition and soil volatiles of a strawberry field being treated with biofumigation treatments, anaerobic soil disinfestation treatments, and a combination of the two alternative methods. A trial was conducted with 11 pre-plant soil-incorporated treatments arranged in a randomized complete block design with 6 rows (blocks). Biofumigation treatments consisted of deactivated mustard meal, deoiled mustard meal, mustard pellets, …

Engineering Photosystem I Complexes For Use In Bio-Hybrid Dye-Sensitized Solar Cells, Richard Franklin Simmerman

Doctoral Dissertations

Increasing global population, growing per capita energy needs, diminishing fossil fuels, and climate change collectively will require new, innovative, and sustainable alternatives to meet the world’s growing energy needs. One of the most promising yet simple approaches are dye-sensitized solar cells (DSSCs). However, conventional DSSCs use semi-conductor anodes sensitized with complex synthetic organometallic dyes. Most dyes utilize ruthenium complexes to absorb photons, which upon excitation, inject electrons into the anode, while holes migrate to the cathode via liquid electrolyte. However, these dyes are expensive, difficult to make, and resource-limited. This dissertation focuses on replacing synthetic dyes with the naturally occurring, …

Characterizing Groundwater Ch4 And 222rn In Relation To Hydraulic Fracturing And Other Environmental Processes In Letcher County, Ky, St. Thomas Majeau Ledoux

Masters Theses

Hydraulic fracturing of shale deposits has greatly increased the productivity of the natural gas industry by allowing it to exploit previously inaccessible reservoirs. However, previous research has demonstrated that this practice can contaminate shallow aquifers with CH₄ [methane] from deeper formations. This study compares concentrations and isotope compositions of CH₄ sampled from domestic groundwater wells in Letcher County, Kentucky in order to characterize its occurrence and origins in relation to neighboring hydraulically fractured natural gas wells. Additionally, this study tests the reliability of ²²²Rn [radon] as an alternative tracer to CH₄ in identifying processes of gas …

Measuring Carbon Dioxide (Co2) Flux Of Agricultural Practices In Sub-Saharan Africa, Debra Blumberg O'Dell

Masters Theses

Agriculture has an important role in addressing two of the world’s most pressing problems: meeting global food demand and mitigating climate change. If agriculture is not practiced sustainably it will fail to meet future food demand and likely intensify the pace of global climate change. There are some agricultural practices, such as Conservation Agriculture, that can produce food sustainably and have the potential to mitigate climate change. However it is not clear which agricultural practices contribute to climate mitigation and by how much. By measuring the carbon dioxide (CO2) emissions of specific agricultural practices, the ability of practices to sequester …

Stability, Erosion, And Morphology Considerations For Sustainable Slope Design, Isaac Andres Jeldes Halty

Doctoral Dissertations

The construction of more natural and sustainable earth slopes requires the consideration of erosion and runoff characteristics as an integral part of the design. These effects not only result in high costs for removal of sediment, but also a profound damage to the ecosystem. In this dissertation, innovative techniques are developed such that more natural appearing slopes can be designed to minimize sediment delivery, while meeting mechanical equilibrium requirements. This was accomplished by: a) examining the fundamental failure modes of slopes built with minimum compaction (FRA) to enhance quick establishment of forest, b) investigating the geomechanical and erosion stability of …

A Multidimensional Analysis Of The Great Green Wall: The Environmental And Social Effects Of Reafforestation In Senegal, Anna Eugenia Alsobrook

Masters Theses

The north-central region of Senegal is home to the Great Green Wall (GGW)—a reafforestation project aimed at restoring decades–old, degraded land conditions by establishing tree belts and community gardens. Its presence on the ground has changed the local landscape and altered the social institutions governing the daily lives of the people it aims to protect.

My study is an in-progress assessment of the GGW towards its two major goals: 1) improving the lives of the people of the Sahel and increasing their capacity to adapt to climate change and drought, and 2) improving the state of the ecosystem and increasing …

A Gis-Based Multi-Objective Optimization Of A Lignocellulosic Biomass Supply Chain: A Case Study In Tennessee, Zidong Wang

Masters Theses

To achieve an economically and environmentally sustainable lignocellulosic biomass (LCB)-based biofuel industry sector, the design and location of a sustainable LCB supply chain is important. In this study, a multi-objective optimization model integrated with high-resolution geographical data was developed to examine the optimal switchgrass supply chain for a potential biorefinery in Tennessee, specifically evaluating the potential tradeoffs between the objectives of minimizing plant-gate cost and GHG emissions from the switchgrass supply chain. The key findings of this study are as follows: both plant-gate feedstock cost and GHG emissions were sensitive to the type of land converted into switchgrass production, the …

Moving Toward Sustainable Production Of Charcoal In Sub-Saharan Africa: A Teaching Case Study, Justin Taylor Roop

Chemistry Publications and Other Works

In the developing world, wood fuels play a major role in supplying energy needs. In sub-Saharan Africa, much of this wood fuel is in the form of charcoal used for cooking. As much as 90% of the cooking performed in these countries use charcoal as the energy source. With this massive quantity being produced and sold, the charcoal sector presents a major area in which sustainable development can be implemented with a large positive impact. At present, deforestation, pollution, and inequitable distribution of profits threaten the long-term viability of this industry. This teaching case study presents the background of the …

Co2 Injection Into A Deep Saline Aquifer: Porosity Measurements, Numerical Modeling, And Costs Associated With Uncertainty Of Petrophysical Parameters, Michael John Gragg

Masters Theses

Anthropogenic levels of atmospheric greenhouse gases, particularly carbon dioxide (CO₂) have increased rapidly over the last several decades and coincide with rising temperatures globally. One possible solution is to capture CO₂ before it is released into the atmosphere by large point sources, such as fossil fuel power plants. Once captured, the CO₂ can be condensed and transported to a storage facility. Of the available options for storage of condensed CO₂, geologic sequestration in deep saline aquifers is considered the most viable option.

Porosity measurements were obtained for nearly 100 core samples of the Knox …