Environmental Sciences Commons^™

The Synthesis And Optimization Of Sulfide And Halide Solid Electrolytes For All Solid-State Batteries, Teerth Brahmbhatt

Doctoral Dissertations

Countries and organizations around the world have established ambitious targets to transition away from fossil fuel-based energy sources and devices. The transition is focused on cleaning up power generation by converting coal, natural gas, and oil-based power generation to renewables and nuclear energy. Decarbonizing other sectors of energy use, transportation for example, will require broader electrification. To drive this move away from fossil fuel powered transportation will require portable energy storage devices. Conventional lithium-ion batteries are a popular candidate to lead this shift. However, these batteries often rely on flammable liquid electrolytes and carbon anodes that suffer from low energy …

Application Of Titrations For Verification Of Small Molecule Interaction In Relation To Amidoximated Fibers For Uranium Extraction From Seawater, Kc Michael Mote

Masters Theses

Nuclear energy is a promising substitute for fossil fuels due to possessing low carbon emissions and providing scalable base-load power. However, one major drawback of using nuclear fuel as an energy source is that it needs a steady source of uranium. While the most economical method of obtaining uranium is through conventional terrestrial mining of the ore uranite, mining uranium ores is both harmful to the environment and limited by the terrestrial uranium supply, which is estimated at only 100 more years. However, more than 1000× more uranium is dissolved in seawater than is reasonably inferred and assured in terrestrial …

Future Energy: Opportunities & Challenges, Thomas W. Kerlin

Open Textbooks

Future Energy: Opportunities & Challenges was originally published in 2013 by the International Society of Automation. Rights for this work have been reverted to the authors by the original publisher. The author has chosen to license this work with a Creative Commons Attribution 4.0 International license (see https://creativecommons.org/licenses/by/4.0/).

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Future Energy: Opportunities & Challenges, Thomas W. Kerlin

Open Educational Resources and Course Materials

Future Energy: Opportunities & Challenges was originally published in 2013 by the International Society of Automation. Rights for this work have been reverted to the authors by the original publisher. The author has chosen to license this work with a Creative Commons Attribution 4.0 International license (see https://creativecommons.org/licenses/by/4.0/).

Click the blue Download link on this page to download the full book PDF. Individual chapters are also listed and available for download in the list below.

Table of Contents

Part I. GETTING STARTED

Chapter 1 – Introduction to the Energy Story

Chapter 2 – Fundamentals

Chapter 3 – Energy Production and …

Potential Contamination Risk In Tennessee Aquifers From Oil And Gas Drilling, Emma Reed

Chancellor’s Honors Program Projects

No abstract provided.

Lattice Boltzmann Methods For Wind Energy Analysis, Stephen Lloyd Wood

Doctoral Dissertations

An estimate of the United States wind potential conducted in 2011 found that the energy available at an altitude of 80 meters is approximately triple the wind energy available 50 meters above ground. In 2012, 43% of all new electricity generation installed in the U.S. (13.1 GW) came from wind power. The majority of this power, 79%, comes from large utility scale turbines that are being manufactured at unprecedented sizes. Existing wind plants operate with a capacity factor of only approximately 30%. Measurements have shown that the turbulent wake of a turbine persists for many rotor diameters, inducing increased vibration …

Mathematical Approaches To Sustainability Assessment And Protocol Development For The Bioenergy Sustainability Target Assessment Resource (Bio-Star), Nathan Louis Pollesch

Doctoral Dissertations

Bioenergy is renewable energy made of materials derived from biological, non-fossil sources. In addition to the benefits of utilizing an energy source that is renewable, bioenergy is being researched for its potential positive impact on climate change mitigation, job creation, and regional energy security. It has also been studied to investigate possible challenges related to indirect and direct land-use change and food security. Bioenergy sustainability assessment provides a method to identify, quantify, and interpret indicators, or metrics, of bioenergy sustainability in order to study trade-offs between environmental, social, and economic aspects of bioenergy production and use. Assessment is crucial to …

The Use Of Sodium Persulfate In Hydraulic Fracturing Fluids: A Degradation Study Based On Furfural, Katherine Elizabeth Manz

Masters Theses

Hydraulic fracturing has allowed natural gas to become a viable energy source via extraction of unconventional shale reserves, but this process requires an enormous amount of water. To ensure a productive fracture, a proprietary blend of chemical additives is added to the water. In this research, a hydraulic fracturing chemical additive – an enzyme breaking agent – is analyzed for organic components using gas chromatography mass spectrometry. The chemical changes that occur over the course of a fracture are also investigated using one model chemical found in the additive, furfural, in order to help assess the environmental risk that hydraulic …

Experimental Limestone Dissolution And Changes In Multiscale Structure Using Small- And Ultra Small- Angle Neutron Scattering, Chad Alan Novack

Masters Theses

Small angle neutron scattering (SANS), ultra-small angle neutron scattering (USANS), and backscatter electron (BSE) imaging, along with neutron computed tomography (NCT) were used in this study to experimentally quantify pore size, distribution, and connectivity of dissolved limestone geometries. Eight samples of Indiana limestone of two different initial permeabilities (2-4 mD and 70 mD ) [millidarcy] were reacted with HCl [hydrochloric acid] solutions at differing pH (2 and 4), and flow rates (0.1 and 10 cm³/min) [cubic centimeters per minute] to describe a broad range of parameters that affect limestone dissolution. NCT was first used to image the dissolution …

Characterizing Groundwater Ch4 And 222rn In Relation To Hydraulic Fracturing And Other Environmental Processes In Letcher County, Ky, St. Thomas Majeau Ledoux

Masters Theses

Hydraulic fracturing of shale deposits has greatly increased the productivity of the natural gas industry by allowing it to exploit previously inaccessible reservoirs. However, previous research has demonstrated that this practice can contaminate shallow aquifers with CH₄ [methane] from deeper formations. This study compares concentrations and isotope compositions of CH₄ sampled from domestic groundwater wells in Letcher County, Kentucky in order to characterize its occurrence and origins in relation to neighboring hydraulically fractured natural gas wells. Additionally, this study tests the reliability of ²²²Rn [radon] as an alternative tracer to CH₄ in identifying processes of gas …

Impacts Of Climate Change On The Evolution Of The Electrical Grid, Melissa Ree Allen

Doctoral Dissertations

Maintaining interdependent infrastructures exposed to a changing climate requires understanding 1) the local impact on power assets; 2) how the infrastructure will evolve as the demand for infrastructure changes location and volume and; 3) what vulnerabilities are introduced by these changing infrastructure topologies. This dissertation attempts to develop a methodology that will a) downscale the climate direct effect on the infrastructure; b) allow population to redistribute in response to increasing extreme events that will increase under climate impacts; and c) project new distributions of electricity demand in the mid-21^st century.

The research was structured in three parts. The first …

A Gis-Based Multi-Objective Optimization Of A Lignocellulosic Biomass Supply Chain: A Case Study In Tennessee, Zidong Wang

Masters Theses

To achieve an economically and environmentally sustainable lignocellulosic biomass (LCB)-based biofuel industry sector, the design and location of a sustainable LCB supply chain is important. In this study, a multi-objective optimization model integrated with high-resolution geographical data was developed to examine the optimal switchgrass supply chain for a potential biorefinery in Tennessee, specifically evaluating the potential tradeoffs between the objectives of minimizing plant-gate cost and GHG emissions from the switchgrass supply chain. The key findings of this study are as follows: both plant-gate feedstock cost and GHG emissions were sensitive to the type of land converted into switchgrass production, the …

Local Residents' Experience Of The Coal Ash Spill In Kingston, Tennessee: A Phenomenological Study, Amy Lynn Mathis

Doctoral Dissertations

On December 22, 2008, near Kingston, Tennessee, a Tennessee Valley Authority (TVA) retention pond holding approximately 1.7 million cubic yards of coal fly ash failed, spilling the ash into the nearby Emory River and inundating farms and homes in the Swan Pond community. As a result more than 100 people were permanently displaced from their homes and the clean-up effort is ongoing.

The purpose of this study was to explore the experience of living near Kingston, Tennessee, in the aftermath of the spill. Using existential phenomenology as the guiding research methodology, I interviewed 9 participants from the area and asked …

Co2 Injection Into A Deep Saline Aquifer: Porosity Measurements, Numerical Modeling, And Costs Associated With Uncertainty Of Petrophysical Parameters, Michael John Gragg

Masters Theses

Anthropogenic levels of atmospheric greenhouse gases, particularly carbon dioxide (CO₂) have increased rapidly over the last several decades and coincide with rising temperatures globally. One possible solution is to capture CO₂ before it is released into the atmosphere by large point sources, such as fossil fuel power plants. Once captured, the CO₂ can be condensed and transported to a storage facility. Of the available options for storage of condensed CO₂, geologic sequestration in deep saline aquifers is considered the most viable option.

Porosity measurements were obtained for nearly 100 core samples of the Knox …

Biofuels '101' Sp700-A, The University Of Tennessee Agricultural Extension Service

Biofuels

Biofuels continue to contribute to the attainment of the energyrelated goals of the United States, including increasing energy security and reducing the environmental degradation linked to transportation fuels. Demand for biofuel production will increase as new technologies are deployed and adopted by producers and consumers. The composition of feedstock for biofuel production, such as grain, will continue to grow. But when grain production has reached full capacity, alternative feedstocks will be needed to meet demand. The potential economic implications of biofuel production are wide-ranging and warrant further attention, especially in rural areas where the feedstocks originate.