Environmental Sciences Commons^™

Dispersion Of Artificial Tracers In Ventilated Caves, Claudio Pastore, Eric Weber, Frédéric Doumenc, Pierre-Yves Jeannin, Marc Lütscher

International Journal of Speleology

Artificial CO₂ was used as a tracer along ventilated karst conduits to infer airflow and investigate tracer dispersion. In the karst vadose zone, cave ventilation is an efficient mode of transport for heat, gases and aerosols and thus drives the spatial distribution of airborne particles. Modelling this airborne transport requires geometrical and physical parameters of the conduit system, including the cross-sectional areas, the airflow and average air speed, as well as the longitudinal dispersion coefficient which describes the spreading of a solute. Four gauging tests were carried out in one mine (artificial conduit) and two ventilated caves (natural conduits). …

Climate Monitoring In The Caumont Cave And Quarry System (Northern France) Reveal Near Oxygen Isotopic Equilibrium Conditions For Carbonate Deposition, Ingrid Bejarano-Arias, Carole Nehme, Sebastian Breitenbach, Hanno Meyer, Sevasti Modestou, Damase Mouralis

International Journal of Speleology

The study of modern cave deposits forming under near isotopic equilibrium conditions can potentially help disentangle the processes influencing the oxygen isotope system and suitability of stalagmites as archives of past hydrological or thermal changes. We used cave monitoring to evaluate the impact of kinetic isotope fractionation and assess the conditions under which modern cave carbonates form in the Caumont cave and quarry system, located in Normandy, northwest France. Over 20 months, we collected climatological data, dripwater, and modern carbonate samples at 2–4-week intervals at three different stations inside the Caumont cave and quarry system. We find highly stable (10.4 …

Land Use/Land Cover Uncertainty Analysis Using Hydrological Modeling In The Northern Watershed Of Lake Okeechobee, Andres Lora Santos

USF Tampa Graduate Theses and Dissertations

Over the past 150 years, Florida has undergone a major land-form transformation, transitioning from a natural to a primarily built environment. The state's population has grown exponentially, from less than 50,000 residents in the 1850s to approximately 22 million residents today. This population growth has led to significant changes in land use, including urbanization, mining, and agriculture. This trend is expected to continue, with projections indicating an increase in urbanization across the state. 2070 land use/land cover projections were used as input for the Watershed Assessment Model (WAM) to analyze the potential impact of these changes on flow, total nitrogen …

Quantifying A 21-Year Surface Water And Groundwater Interaction In A Ridge And Valley Lake Environment Using A Highly Constrained Modeling Approach, Richard T. Bowers Jr.

USF Tampa Graduate Theses and Dissertations

Karst lakes are ubiquitous in ridge terrain settings in limestone aquifer coastal plain environments. In west-central Florida, these lakes are frequently connected to the Upper Floridan aquifer and have unique aquifer recharge characteristics. They have been selectively studied because they commonly have no or very limited surface water discharge and limited drainage areas, have appreciable surface water and groundwater interaction and leak to the deep aquifer. An innovative modeling approach was developed to collectively understand and more precisely quantify this vertical leakage, both from a lake-specific and regional water budget standpoint, for a 21-year study period (2000-2020). A unique, calibrated …

Hydrodynamic Model For Independent Cold And Thermo-Mineral Twin Springs In A Stratified Continental Karst Aquifer, Camou, Arbailles Massif, Pyrénées, France, Philippe Audra, Jean-Yves Bigot, Dimitri Laurent, Nathalie Vanara, Didier Cailhol, Gérard Cazenave

International Journal of Speleology

The Camou springs (Arbailles Massif, French Western Pyrenees) display an unusual close association of a typically cold karstic spring that drains the Urgonian western limb of the Arbailles, and a thermo-mineral spring (33.5°C; salinity 17.7 g/L). The latter gains its mineralization at the contact of Triassic evaporites mainly through a deep loop in the Apanicé syncline. The fast upflow of this deep water occurs at the cross of large active lines (the North-Pyrenean thrust located at depth, and the Saison transverse fault). Cave diving in the nearby Maddalen Cave allowed reaching the phreatic passage at the origin of the cold …

Isotopic Study Of The Waters From The Sulphur Springs Catchment, Tampa, Florida, Esra Zengin

USF Tampa Graduate Theses and Dissertations

A stable isotope study was carried out using precipitation, spring water, groundwater well sample, and a seawater sample during the wet season in the Sulphur Springs watershed in Tampa, Florida. Studies that track long term isotopic variation over wet seasons are limited in the region. To fill this knowledge gap, this study aims to quantify the contributions of precipitation and diffuse sources to discharge in Sulphur Springs. A three-component mixing model was applied using δ18O and δ2H values to determine different source water contributions to spring water discharge. The three-component mixing model calculations suggest spring water consists mainly of diffuse …

Toxicity Of Fluorescent Tracers And Their Degradation Byproducts, Philippe Gombert, Hugues Biaudet, René De Sèze, Pascal Pandard, Jean Carré

International Journal of Speleology

Tracer tests are frequently used to delineate catchment area of water supply springs in karstic zones. In the karstic chalk of Normandy, the main tracers used are fluorescent: uranine, sulforhodamine B, naphtionate, and Tinopal®. In this area, a statistical analysis shows that less than half of the injected tracers joins the monitored restitution points and enters the drinking water system where they undergo chlorination. Most of the injected tracers is absorbed in the rock matrix or is thrown out of the aquifer via karstic springs: then it can join superficial waters where it is degraded due to the sun and …

Evaluation Of Low-Cost Low Impact Development Practices In Southwest Florida For The Control Of Urban Runoff, Laura Kathren Rankin

USF Tampa Graduate Theses and Dissertations

Stormwater management is required due to development and alteration of the natural environment. It is heavily regulated in Florida and at the national level. Over the last two decades, Low Impact Development (LID) has been promoted as a sustainable and environmentally friendly method of controlling urban runoff. Case studies, provided in Chapter 2, show that LIDs can restore watershed hydrology by balancing the water budget. The difference in runoff between pre-development and post-development appears to increase with soil perviousness. However, the potential for mitigating the impacts of urbanization through runoff reduction is also greater for pervious, sandy soils that dominate …

Evaluation Of First Order Error Induced By Conservative-Tracer Temperature Approximation For Mixing In Karstic Flow, Philippe Machetel, David A. Yuen

Sinkhole Conference 2015

Fluid dynamics in karst systems is complex due to the heterogeneity of hydraulic networks that combine the Porous Fractured Matrix (PFM) and the interconnected drains (CS). These complex dynamic systems often need to be treated as “black boxes” in which only input and output properties are known. In this work, we propose to assess the first-order error induced by considering the temperature as a conservative tracer for flows mixing in karst (fluvio-karst). The fluvio-karstic system is treated as an open thermodynamic system (OTS), which exchanges water and heat with its surrounding. We propose to use a cylindrical PFM drained by …

Accounting For Anomalous Hydraulic Responses During Constant-Rate Pumping Tests In The Prairie Du Chien-Jordan Aquifer System – Towards A More Accurate Assessment Of Leakage, Justin Blum

Sinkhole Conference 2015

The Prairie du Chien-Jordan Aquifer system is an important source of drinking water for residents of southeastern Minnesota. Assessment of the hydraulic properties of this aquifer continues to be of interest for wellhead protection and resource evaluation efforts. When performing constant-rate pumping tests on wells constructed in the karsted Prairie du Chien Aquifer, anomalous hydraulic responses resulting from cavernous flow are frequently observed. Hydraulic response in the adjacent Jordan Sandstone Aquifer is also commonly distorted because of bedding-plane fractures and well development techniques such as blasting and bailing. Resolution of these anomalous responses is important for accurate estimates of leakage …

Dye Tracing Through The Vadose Zone Above Wind Cave, Custer County, South Dakota, James Nepstad

Sinkhole Conference 2015

During the 1990s, in an attempt to better understand threats posed by surface developments overlying the cave, National Park Service staff at Wind Cave National Park in Custer County, South Dakota carried out a series of dye traces through portions of the vadose zone overlying the cave. Wind Cave is located within the 100m-thick Madison formation (limestone and dolomite), which in most locations is capped by varying thicknesses of the basal units of the Minnelusa formation (intermingled beds of sandstone, limestone, and shale). A variety of cave locations with dripping or pooled water were monitored for up to five years …

Finding Springs In The File Cabinet, Mason Johnson, Ashley Ignatius

Sinkhole Conference 2015

The Minnesota Pollution Control Agency (MPCA), in partnership with other agencies, is currently undertaking comprehensive sub-basin assessments statewide over a ten-year period. Southeast Minnesota has over 17,500 kilometers of perennial and intermittent streams, making the task of comprehensive sub-basin assessment challenging; the task is further complicated by karst geology. In the summer of 2014, a pilot project began between the MPCA and Minnesota Department of Natural Resources (DNR) to digitally preserve paper documents which capture qualitative and quantitative data about the hydrology, water chemistry, geomorphology, biology, land use and karst features of southeast Minnesota streams. The paper documents in file …

Legacy Data In The Minnesota Spring Inventory, Greg Brick

Sinkhole Conference 2015

Past spring inventories have covered certain parts of Minnesota reasonably well, notably, the springs of the Minneapolis-St. Paul metropolitan area and the southeastern Minnesota karst. But hitherto, there has not been a systematic effort to create a uniform statewide inventory. The first step, before hunting down new springs, was to compile existing data and the most fruitful source of hydrological legacy data for the Minnesota spring inventory was the DNR Fisheries files. Once entered into a GIS-capable database, these spring locations can help “seed the ground” so that when crews finally do take to the field to map more springs, …

Sinkhole Vulnerability Mapping: Results From A Pilot Study In North Central Florida, Clint Kromhout, Alan E. Baker

Sinkhole Conference 2015

At the end of June in 2012, Tropical Storm Debby dropped a record amount of rainfall across Florida which triggered hundreds, if not thousands, of sinkholes to form which resulted in tremendous damage to property. The Florida Division of Emergency Management contracted with the Florida Department of Environmental Protection’s Florida Geological Survey to produce a map depicting the state’s vulnerability to sinkhole formation. The three-year project began with a pilot study in three northern Florida counties: Columbia, Hamilton and Suwannee. Utilizing the statistical modeling method Weights of Evidence, results from the pilot study yielded a 93 percent success rate of …

Creation Of A Map Of Paleozoic Bedrock Springsheds In Southeast Minnesota, Jeffrey A. Green, E. Calvin Alexander Jr.

Sinkhole Conference 2015

Springs are groundwater discharge points that serve as vital coldwater sources for streams in southeast Minnesota. The springs generally emanate from Paleozoic carbonate and siliciclastic bedrock aquifers. Use of systematic dye tracing began in the 1970s and continues through the present as a standard method for investigating karst hydrology and to map springsheds,. The work was accelerated in 2007 because of increased funding from the State of Minnesota’s Environment and Natural Resources Trust Fund. A compilation springshed map of dye traces conducted over the last several decades has been assembled for the region. In southeast Minnesota, the springs are the …

Tracking Of Karst Contamination Using Alternative Monitoring Technologies: Hidden River Cave Kentucky, Caren Raedts, Christopher Smart

Sinkhole Conference 2015

Karst groundwater contamination presents great challenges for efficient monitoring because of rapid, discrete transport and the diversity of contaminants. Here a low cost approach is described and applied to Hidden River Cave, Kentucky, where a long history of contamination has been experienced. Local knowledge was acquired through informal interviews and coupled with observations of contaminant residues, faunal distributions and fluorescence spectra in the cave. The resulting patterns were interpreted using Google Earth and Street View to identify specific contaminant sources in the affected sub-catchment of the cave. Despite success in matching contaminant sources with the contamination history and pattern, the …

Karst Influence In The Creation Of A Pfc Megaplume, Virginia Yingling

Sinkhole Conference 2015

Perfluorochemicals (PFCs) are fully-fluorinated organic chemicals used to produce a wide range of industrial and commercial products. Their extreme persistence and mobility in the environment and nearly ubiquitous presence in humans and wildlife has raised serious concerns regarding their environmental and human health effects. In the 1940s to 1970s, PFC-bearing wastes were disposed of in three unlined landfills in Washington County, Minnesota. The resulting co-mingled PFC plumes created a “megaplume” that contaminated over 250 km2 of groundwater and four major drinking water aquifers; affecting eight municipal water supply systems and thousands of private wells. Site investigations revealed that karst features, …

Evaluation Of Veterinary Pharmaceuticals And Iodine For Use As A Groundwater Tracer In Hydrologic Investigation Of Contamination Related To Dairy Cattle Operations, Larry Boot Pierce, Honglin Shi

Sinkhole Conference 2015

Standard groundwater tracers such as Rhodamine WT, Fluorescein, Eosin and Tinopal CBX effectively provide a snapshot of hydrological conditions over a brief period of time and in a tightly controlled setting. However, in complex environmental situations with multiple potential sources, groundwater hydrologists are often seeking groundwater tracers that have extended longevity in the natural environment and the ability to directly pinpoint source locations. After reviewing operations of the nearby dairy it was determined that emerging contaminants, specifically two bovine veterinary pharmaceuticals (antibiotics), cephapirin sodium (CEPNa) and cephapirin benzathine (CEPB), and a sanitation agent, elemental Iodine (I) may have potential as …

Seeps And Springs At A Platteville “Observatory” On The River Bluffs, Bj Bonin, Greg Brick, Julia R. Steenberg

Sinkhole Conference 2015

Residential building construction along the Mississippi River bluffs in the 1970s created a unique enclosed outcrop of the Late Ordovician Platteville Formation at Lilydale, Minnesota. This outcrop was examined in early 2013 after a newly-formed spring flooded an elevator shaft the previous year, drawing attention to the foundation conditions. The Lexington Riverside property is a six story condominium complex constructed within the top of the bluff. A two-level underground parking garage was built into the bluff. Bedrock was mechanically excavated to accommodate the construction of the building, creating an unweathered rock surface. The space between the structure and the excavated …

Conduit Flow In The Cambrian Lone Rock Formation, Southeast Minnesota, U.S.A., John D. Barry, Jeffrey A. Green, Julia R. Steenberg

Sinkhole Conference 2015

The karst lands of southeast Minnesota contain more than one hundred trout streams that receive perennial discharge from Paleozoic bedrock springs. Several of the Paleozoic bedrock units that provide discharge are karst aquifers. Field investigations into the flow characteristics of these formations have been conducted using fluorescent dyes to map groundwater springsheds and characterize groundwater flow velocities for use in water resource protection. Recent field work has focused on the Cambrian Lone Rock Formation, a siliciclastic unit consisting of very fine-grained sandstone and siltstone with minor beds of shale and dolostone. The formation is mapped within tributary valleys of the …

Human Impacts On Water Quality In Coldwater Spring, Minneapolis, Minnesota, Sophie M. Kasahara, E. Calvin Alexander Jr., Scott C. Alexander

Sinkhole Conference 2015

Coldwater Spring in Minneapolis, Minnesota was the water supply for Fort Snelling from the 1840s to 1920. The spring site has been declared a sacred site by some federally recognized Native American tribes. The site is managed by the National Park Service. This project has monitored the water chemistry of Coldwater Spring to document human impacts on the spring’s water quality. Temperature, dissolved oxygen, conductivity, pH and anions were monitored weekly and cations and alkalinity monitored monthly at Coldwater Spring and the adjacent Wetland A from 15 February 2013 through 18 January 2015. Coldwater Spring’s water flows through fractures in …

Tracer Studies Conducted Nearly Two Decades Apart Elucidate Groundwater Movement Through A Karst Aquifer In The Frederick Valley Of Maryland, Keith A. White, Michael K. Cobb, Thomas Aley, Ethan Weikel

Sinkhole Conference 2015

A pair of groundwater tracer studies at a single karst test site were completed 18 years apart. The results of these studies have provided evidence of both relatively rapid advective transport via conduits and an extreme capacity for dye storage and retardation. The tracer results, coupled with other subsurface investigation data, are used to develop a conceptual model for groundwater movement through this karst aquifer in the Frederick Valley of Maryland, as well as identify implications for remediation. Three fluorescent tracer dyes used in the initial study were detected in several background monitoring locations established for the second study conducted …

Hydrogeological Dynamic Variability In The Lomme Karst System (Belgium) As Evidenced By Tracer Tests Results (Karag Project), Amaël Poulain, Gaëtan Rochez, Vincent Hallet

Sinkhole Conference 2015

Paleozoic carbonate aquifers represent major groundwater resources in Belgium. Karstification processes affect most of them and Belgium counts many hydrologically active karst networks. Given the intrinsic vulnerability of such geological objects, comprehensive studies are required in order to improve their protection and management. The KARAG project (Karst Aquifer ReseArch by Geophysic, 2013-2017) aims to identify the specific dynamic of karst aquifers by using geophysical and hydrogeological tools. This research is funded by the Belgium National Fund for Scientific Research (FNRS) and conducted by the University of Namur, University of Mons and the Royal Observatory of Belgium. The LKS – Lomme …

Karst Porosity Estimations From Archive Cave Surveys - Studies In The Buda Thermal Karst System (Hungary), Gáspár Albert, Magdolna Virág, Anita Erőss

International Journal of Speleology

The Buda Thermal Karst System is located under the densely populated hills of Budapest. One of its caves (Pál-völgy Cave System) is the longest cave of Hungary with 30.1 km. The research was done in this area as a methodological study to estimate karst porosity parameters of aquifers or hydrocarbon reservoirs. In this study two modeling methods are demonstrated. The volumetric modeling method was primarily aimed to determine the macro-scale (>0.5 m) conduit porosity (referred as macroporosity) of the study area as percentage of the incorporating limestone and marl. This method is based on archive survey data (maps and …

New Research In Cave Ledenica In Bukovi Vrh On Velebit Mt In Croatian Dinaric Karst, Mladen Garasic

The International Workshop on Ice Caves

No abstract provided.

Time, Money, And Melting Ice: Proposal For A Coopertive Study Of The World’S Cave Ice In A Race Against Climate Change, George Veni, Lewis Land, Aurel Perşoiu

The International Workshop on Ice Caves

Climate change is a global phenomenon that is melting and threatening to melt ice deposits in many of the world’s ice caves. The National Cave and Karst Research Institute of the USA is concerned that major and important paleoclimate and paleoenvironmental records stored in cave ice will soon be lost, and is proposing an international collaborative effort to overcome funding and logistical challenges to sample and analyze at least a representative collection of ice from several regions before further melting occurs.

Some New Potential Subterranean Glaciation Research Sites From Velebit Mt. (Croatia), Neven Bočić, Nenad Buzjak, Zoltan Kern

The International Workshop on Ice Caves

Despite the frequent reports about their shrinkage detailed survey of the major subterranean ice deposits is still lacking in Croatia. Here we present cave maps and detailed description of cave ice accumulation from five caves of the Velebit Mt. Morphological constraints allowed ice volume estimation for four of them. Ice volumes were estimated as ~1500 m³ at the Gavranova Pit in 1999, 100 m³ at Štirovača ice cave in 1987, 150 m³ at Japagina 3 in 2000, 1500 m³ at Kugina ice cave in 2004. These new records provide reference data for future studies to evaluate …

Impact Of Climate Change On Human And Ecological Use Of Karst Groundwater Resources: A Case Study From The Southwestern Usa, George Veni

National Cave and Karst Management Symposium 2013

Climate change models for the arid southwestern USA predict increasing temperatures and declines in precipitation. These changes will have multiple adverse impacts on water and ecological resources and pose diverse challenges on their management. The San Solomon Spring system of west Texas discharges from the western edge of the karstic Edward-Trinity Plateau Aquifer. It consists of six springs in Jeff Davis and Reeves counties, is one of the largest spring groups in the state, and provides water for agricultural use and habitat to two federally listed endangered species and three species proposed for listing. It serves in this paper as …

Preliminary Summary Of Water Resource Investigations During 2012 At Timpanogos Cave National Monument, Utah, Lee J. Florea, Chelsie R. Dugan, Camille Mckinney

National Cave and Karst Management Symposium 2013

This manuscript considers the hydrology and geochemistry of water resources within Timpanogos Cave National Monument in American Fork, Utah. In particular, data are presented for five cave pools within the Monument and the American Fork River that flows through the Monument. Two independent dye trace attempts in this study have not established a connection between the surface near the canyon rim at the south border of the Monument and the cave pools or the river. Ion chemistry of the pools reveals elevated sulfate concentrations. Analysis of sulfate and other reaction products suggests the possibility of combined carbonic and sulfuric acids …

Something Is Askew In Florida's Water: Arguing For A Better Descriptive Statistic For Positively Skewed Water-Quality Data, Amie October West

USF Tampa Graduate Theses and Dissertations

ABSTRACT

It may be of no surprise that water quality data is right-skewed, but what appears to be overlooked by some is that the arithmetic mean and standard deviation most often fail as measures of central tendency in skewed data. When using the arithmetic mean and arithmetic standard deviation with nutrient data, one standard deviation about the arithmetic mean can capture nearly all of the data and extend into negative values. Representing nutrient data this way can be misleading to viewers who are using the statistics, and making assumptions, to understand the characteristics of those waters. Through an in-depth statistical …