Environmental Sciences Commons^™

Quantifying Current Soil Brine Contamination Within The Smackover Oil Field In Arkansas Using Multispectral Digital Imagery, Victoria Williams

Electronic Theses and Dissertations

A remote sensing study was performed to quantify current soil brine contamination across the historic Smackover Oil Field in south-central Arkansas, United States. The oil field was established in 1922 and was not subject to the future waste regulations created by the Arkansas Oil and Gas Commission. Brine is a waste product of oil manufacturing which contains water with high salt levels. The storage and transport of brine in the oil field created landscape scarring across the study area.

Landsat 9 multispectral digital imagery was utilized to create supervised classification maps based on earthen pits and creek scarring across the …

Understanding The Impacts Of Anthropogenic Effects An Habitat Variability Interactions On Maine's Rocky Intertidal Ecosystem, Laura Braun

Electronic Theses and Dissertations

The rocky intertidal ecosystem is an important ecological and cultural aspect of the picturesque Maine coast, playing a vital role in not only Maine’s coastal ecosystem, but also to Maine’s economy. It’s distinct community structure along the sharp elevational gradient and the presence of daily stressors (wave action, heat, and desiccation), make the rocky intertidal ecosystem an important model ecosystem to monitor for effects from anthropogenic impacts. In this thesis, I describe attempts to monitor and understand the impacts of two of these anthropogenic impacts on this system: climate change and industrial harvesting of Ascophyllum nodosum along Maine’s coast. For …

Carbon Dioxide Emissions From Deadwood In Forests Of The Northeastern United States, Zoe Read

Electronic Theses and Dissertations

As the climate changes, understanding the sources and sinks of greenhouse gases such as carbon dioxide (CO₂) is increasingly important. However, several components of the carbon cycle within forests remain poorly understood. For example, knowledge gaps exist in our understanding of CO₂ emissions from coarse woody material (CWM; logs and stumps), including how emissions change over time, how they are influenced by environmental variables, and how they compare to soil and ecosystem-level CO₂ emissions.

To fill these knowledge gaps, we examined CO₂ emissions from CWM at three sites. We sampled 18 red spruce (Picea …

Assessing The Long-Term Effects Of Natural Disturbance-Based Silvicultural On The Avian Assemblage At The Acadian Forest Ecosystem Research Program, Carl Pohlman

Electronic Theses and Dissertations

Active forest management alters the resources available to forest-obligate species. Large-scale intensive management practices where timber production is the primary objective can lead to notable ecological changes in forest ecosystems. A key concept of ecological forestry is to design forest management activities to emulate natural disturbance regimes as a way to maintain the ecological integrity of forests. The Acadian Forest Ecosystem Research Program (AFERP) was undertaken as an experimental demonstration of management reflective of the region’s disturbance regime, which typically produces small canopy gaps. AFERP includes nine research areas assigned to three silvicultural treatments: unharvested control, small gap (expanding-group selection …

Anthropogenic Impacts To Essential Habitats In The Gulf Of Maine: A Case Study Of The American Lobster, Homarus Americanus, And Its Fishery, Andrew Goode

Electronic Theses and Dissertations

The Gulf of Maine has been fundamentally altered by anthropogenic forcings for decades and offers an ideal study system to monitor response to change. Through complex interactions between ocean warming, altered demographic bottlenecks, and reduced top-down controls, the American lobster (Homarus americanus Milne Edwards) capitalized on favorable conditions and proliferated within the Gulf of Maine. These changes catalyzed the expansion of the lobster fishery, elevated its status as North America’s most valuable marine resource, and shifted coastal communities towards a virtual lobster monoculture. The same processes that facilitated lobster to capitalize on favorable conditions may come with unintended consequences …

Forest Disturbance And Occupancy Patterns Of Carnivores: Results Of A Large-Scale Field Study In Maine, Usa, Bryn E. Evans

Electronic Theses and Dissertations

Understanding trends in the abundance and distribution of carnivores is important at global, regional and local scales due to their ecological role, their aesthetic and economic value, and the numerous threats to their populations. Carnivores in Maine range from the American black bear (Ursus americanus), to numerous native mesocarnivore species, such as American marten (Martes americana), fisher (Pekania pennanti), coyote (Canis latrans), red fox (Vulpes vulpes), bobcat (Lynx rufus), Canada lynx (Lynx canadensis) and to two small weasel species (Mustela erminea and Neogale frenata). …

Development Of Standard Operating Procedure With Modified Method To Quantify Benzene And Other Volatile Organic Compounds In Air Samples Using Gas Chromatography, Heather Hall

Electronic Theses and Dissertations

Stephen F. Austin State University (SFASU) Department of Environmental Science has recently invested in a gas chromatograph which can be used to analyze air samples for volatile organic compounds (VOCs) such as benzene, toluene, ethylbenzene, and xylenes (BTEX). The goal of this project was to develop a standard operating procedure (SOP) and modify the current method for the detection of VOCs associated with oil and gas drilling activity to accommodate the equipment and capabilities of SFASU Environmental Assessment Lab. This study aims to provide the framework for future research in air quality monitoring in the Eagle Ford Shale area. An …

Using An Inventory Of Unstable Slopes To Prioritize Probabilistic Rockfall Modeling And Acid Base Accounting In Great Smoky Mountains National Park, Thomas A. O'Shea

Electronic Theses and Dissertations

An inventory of unstable slopes along transportation corridors and performance modeling are important components of geotechnical asset management in Great Smoky Mountains National Park (GRSM). Hazards and risk were assessed for 285 unstable slopes along 151 miles of roadway. A multi-criteria model was created to select fourteen sites for two-dimensional probabilistic rockfall simulations and Acid Base Accounting (ABA) tests. Simulations indicate that rock material would likely enter the roadway at all fourteen sites. ABA test results indicate that influence of significant acid-producing potential is generally confined to slaty rocks of the Anakeesta Formation and graphitic schist of the Wehutty Formation. …

Accurate Quantitation Of Hexavalent Chromium For Reference Standard Certification And Quality Control Testing Using Speciated Isotope Dilution Mass Spectrometry, James E. Henderson

Electronic Theses and Dissertations

The ability to perform accurate, repeatable, and defensible elemental and molecular speciated analysis is immensely significant for measurements that support human health, environmental science, and industry. This is especially true since trivalent chromium [Cr(III)] is necessary for proper nutrition, while hexavalent chromium [Cr(VI)] is extremely toxic, genotoxic, and carcinogenic. The main challenges associated with speciated analysis are related to reactive species that are continuously transformed or converted to other species during sample processing. Accurate determination of Cr(III) and Cr(VI) species require a method that is capable of monitoring and correcting for interconversion, bias, and instrumental error. Traditional quantitative methods, such …

Tree Canopy Effects On Roof-Harvested Rainwater In East Texas, Kimberly Gamez

Electronic Theses and Dissertations

Nine experimental metal roofs with rainwater harvesting systems were constructed and water quality parameters were measured in 2016-2017 in order to evaluate the effects of arboreal overhang on roof-harvested rainwater quality collected in East Texas. Three treatments were evaluated: Rainwater collected from roofs without any overhanging tree vegetation, rainwater collected from roofs under predominantly Southern yellow pine tree cover, and rainwater collected from roofs under predominantly hardwood tree cover. Rainwater was collected from these roofs for one year. The effects of canopy cover on water quality parameters, comparison to drinking water standards, first-flush efficiency, and seasonal effects were evaluated.

Significant …

Aerial Mineral And Organic Particulate Deposition In East Texas, Sarah Caton, Sarah Caton

Electronic Theses and Dissertations

This study determined the monthly amount, particle size distribution, and chemical composition of particulate deposition in East Texas over a one-year period. It also recognized the seasonal patterns of this deposition as well as its primary origins as either mineral or organic particulate deposition.

The study recorded the monthly mass of deposition, particle size distribution, and the chemical makeup of deposition throughout a period of twelve months at seven sampling locations. SEM-EDS technology was used in conjunction with PCI programming to measure the sizes of depositional particles throughout this time period and identify their chemical composition.

The total yearly deposition …

The Persistence Of Acid Mine Drainage At An East Texas Coal Mine, Sarah Zagurski

Electronic Theses and Dissertations

The objective of this study was to estimate the time it will take for acid forming materials (pyrite) to be weathered to a state of equilibrium and thus cease to produce acid in ground and surface waters within Oak Hill Mine. This was accomplished using an ex-situ kinetic leaching study incorporating a humidity cell in a controlled laboratory setting. Leaching was conducted on soil cores obtained from the vadose zone at Oak Hill Mine and the humidity cell was used to accelerate oxidation of the pyrite within the cores.

An in-situ field study was also conducted that monitored groundwater conditions …

Airborne Hyperspectral Data Application In Stress Detection Of Blueberry Fields And Ash Trees, Catherine Chan

Electronic Theses and Dissertations

Water management and irrigation practices are persistent challenges for many agricultural systems. Changing seasonal and weather patterns impose a greater need for understanding crop deficiencies and excesses (e.g. water, sunlight, nutrients) for optimal growth while allocating proper resources for prompt response. The wild blueberry industry is at heightened susceptibility due to its unique growing conditions and uncultivated nature. Early detection of stress in agricultural fields can prompt management responses to mitigate detrimental conditions including drought and disease. Remote sensing has provided timely and reliable information covering large spatial extents, while novel applications in hyperspectral data and imaging spectroscopy have shown …

Applications Of Digital Remote Sensing To Quantify Glacier Change In Glacier And Mount Rainier National Parks, Brianna Clark

Electronic Theses and Dissertations

Digital remote sensing and geographic information systems were employed in performing area and volume calculations on glacial landscapes. Characteristics of glaciers from two geographic regions, the Intermountain Region (between the Rocky Mountain and Cascade Ranges) and the Pacific Northwest, were estimated for the years 1985, 2000, and 2015. Glacier National Park was studied for the Intermountain Region whereas Mount Rainier National Park was representative of the glaciers in the Pacific Northwest. Within the thirty year period of the study, the glaciers in Glacier National Park decreased in area by 27.5 percent while those on Mount Rainier only decreased by 5.7 …

Analyzing The Effects Of Of Seasonal Land Cover And Precipitation On The Sediment Delivery Ratio Of An Agriculture Dominated Watershed., Jonah Liebman

Electronic Theses and Dissertations

Soil erosion is of escalating importance as increasing population and climate change have put increasing pressures on agricultural food production. Vegetation and precipitation are two factors that control the amount of soil erosion extant within a region. Sediment delivery ratios (SDRs) assess the ratio of soil eroded from a watershed system that is permanently removed from the system through stream sediment discharge. Using 1) river discharge and sediment concentration data and 2) the Revised Universal Soil Loss Equation (RUSLE), this thesis analyzes fluctuations in monthly SDRs for an average hydroclimatological crop-harvest season for the Senachwine Creek watershed, IL. Through calculating …

Changes In Land Use Land Cover (Lulc), Surface Water Quality And Modelling Surface Discharge In Beaver Creek Watershed, Northeast Tennessee And Southwest Virginia, Tosin James

Electronic Theses and Dissertations

Beaver Creek is an impaired streams that is not supporting its designated use for recreation due to Escherichia coli (E.coli), and sediment. To address this problem, this thesis was divided into two studies.

The first study explored changes in Land Use Land Cover (LULC), and its impact on surface water quality. Changes in E.coli load between 1997-2001 and 2014-2018 were analyzed. Also, Landsat data of 2001, and 2018 were examined in Terrset 18.31. Mann-Whitney test only showed a significant reduction in E.coli for one site. Negative correlation was established between E.coli load, and Developed LULC, Forest LULC, and …

Storm Sampling To Assess Inclement Weather Impacts On Water Quality In A Karst Watershed: Sinking Creek, Watauga Watershed, East Tennessee, Porcha Mccurdy

Electronic Theses and Dissertations

Escherichia coli changes in Sinking Creek, an impaired water body in the Watauga watershed of northeast Tennessee, were assessed during storm events using water samples collected with ISCO automated samplers during eight storms at two locations. Turbidity and electrical conductivity (EC) data loggers were deployed in the creek, and dissolved oxygen (DO) was measured in situ to test the stream’s water quality and reaction to inclement weather. Cotton fabric was deployed at both locations and sent to an external lab to test for the presence of Optical Brighteners (OB), which are indicators of residential wastewater. E. coli and turbidity at …

A Study Of Chloride Levels In Pine Creek, Allegheny County, Pa, Selina Prettner

Electronic Theses and Dissertations

Pine Creek is a 22.8-mile long tributary to the Allegheny River draining over 67 square miles of northern Allegheny County, PA. The main stem runs along Route 8 and receives extensive runoff from road salt from deicing. A site near Etna, PA sampled biweekly in 2013 consistently showed elevated conductivity that correlated with increased chloride levels. Winter road deicing runoff produced acute chloride concentrations up to 678 mg/L. Chloride fluctuated in the summer and autumn months but did not exceed the USEPA Secondary Drinking Water Standard (250 mg/L) or the aquatic life criterion for chronic concentrations (230 mg/L). Sampling throughout …

Improved Estimates Of Tributary Nitrogen Load To Casco Bay, Maine, Whitley J. Gray

Electronic Theses and Dissertations

Over the past two decades, total nitrogen (TN) concentrations have increased in Casco Bay (CBEP 2015). The sources of the increased nitrogen are poorly understood but occur with simultaneous population growth and land use changes. The total riverine nitrogen load to Casco Bay was previously estimated by Liebman and Milstead (2012) using the United States Geologic Survey’s (USGS) SPAtially Referenced Regression On Watershed attributes (SPARROW) model. The SPARROW model uses watershed characteristics, regional monitoring data and nitrogen source data to estimate nitrogen loading but was not validated using measurements of nitrogen in the Casco Bay watershed. This study attempts to …

The Effects Of Constructed Wetlands On Metal Solubilization And Bioavailability In Passive Mine Remediation, Elizabeth Cochran

Electronic Theses and Dissertations

The legacy of coal mining in Appalachia has left many watersheds impacted by abandoned mine drainage. The drainage degrades streams, groundwater and habitats with acidity and toxic heavy metals. The Lowber Passive Remediation System has been in operation since 2004 to remediate high amounts of dissolved Fe, SO₄, Al, and Mn. The site consists of six settling ponds and an extensive wetlands at the finish. This study investigated the resolubilization of Fe and Mn in the wetlands and the role of bacteria in resolubilization. During three seasons, field measurements of water quality and lab analysis of Fe, Mn, …

Water Quality Assessment Of Deer Lakes County Park Before, During And After Unconventional Shale Gas Drilling, Daniel Robinson

Electronic Theses and Dissertations

Allegheny County, Pennsylvania, signed a lease to allow unconventional natural gas extraction from Marcellus Shale beneath Deer Lakes County Park in 2014. The park has three man-made lakes and four waterways that eventually flow into the Allegheny River. Drilling commenced in early 2016, and there are now five producing wells. The park has an extensive abandoned coal mine network and several abandoned oil and gas wells. Thus, an independent water quality study was undertaken beginning in July 2015. Samples from seven different sites in the park were used to establish a water quality baseline prior to the drilling. Monthly sampling …

Wetland Biogeochemical Responses To Predicted Climate Change Scenarios, Angela R. Shaffer

Electronic Theses and Dissertations

Wetlands are one of the world's largest known carbon sinks while comprising only a small amount of the Earth's surface. However, the amount of carbon sequestered by wetlands is shrinking as droughts and human disturbance increases. Carbon in wetlands is stored through the contrast of decomposition and sedimentation of organic matter and absorption of CO₂ from the atmosphere by soil microbes. Understanding how changing hydrological regimes and increased wildfires will affect wetland soil and microbial processes is important in the face of predicted climate change for future wetland conservation practices. Specifically, I seek to understand the response of southeastern …

Mercury In Big Cypress Bayou And Caddo Lake Watersheds In Marion And Harrison Counties Texas, Joseph Watkins

Electronic Theses and Dissertations

Caddo Lake has been included on the Texas Commission on Environmental Quality 303(d) list for impairment due to mercury (Hg) content since 1996. One of the primary tributaries, Big Cypress Bayou, flows across Eocene-aged rocks and sediments associated with the Wilcox Group; the Wilcox is of interest because it contains lignite coal, which has a direct link to mercury. Previous research has focused on dry deposition from fossil fuel combustion as the primary source of mercury but has not addressed the potential watershed contribution to mercury concentrations in Caddo Lake.

Big Cypress Bayou flows through Harrison and Marion counties in …

Groundwater Hydrogeolgy And Hydrochemistry Of Karst Springs In The Eastern Peninsula Of Fort Hood Military Installation, William Scribner Welles

Electronic Theses and Dissertations

The eastern peninsula of Fort Hood Military Installation is underlain by a complex karst spring network. These springs are a primary water source in a protected habitat for endangered songbirds, which has only recently begun to be fully investigated. These Fredericksburg Group springs express both epigenetic and hypogenetic karst signatures. The study area is part of a paleo reef trend, a hydraulically disconnected segment of the northern section of the Edwards Aquifer. This study utilized standard ion index values, repeated measures, and principal component analyses on the chemical profiles of six perennial springs to classify spring water sources and their …

Effectiveness Of Prescribed Fire On Meeting Fuel Load And Wildlife Habitat Management Objectives In East Texas National Forests, Trey Wall

Electronic Theses and Dissertations

Using standardized methodology outlined by the United States Forest Service and the National Forests and Grasslands in Texas’ Fire Monitoring Program for data collection, the efficacy of current Forest Service prescribed burn regimes were analyzed for 24 study sites in East Texas National Forests. Study sites were located within Sam Houston, Davy Crockett, and Angelina/Sabine National Forests. Efficacy was determined by comparing defined management objectives established by the Forest Service to the data collected at the study sites. The results conclude that most objectives, as outlined by the Forest Service, are not being met with the current practices. Re-visitation of …

Improving Sinkhole Mapping Using Lidar Data And Locating Sinkhole Hotspots In Johnson City, Tn, Kingsley Fasesin

Electronic Theses and Dissertations

Predicting infrastructure damage and economic impact of sinkholes requires high accuracy mapping distribution and development. The study mapped sinkholes and sinkhole hotpsots in Johnson City, TN using LiDAR-derived Digital Elevation Model (DEM) and a database of known sinkholes which were matched to LiDAR-derived depressions. For all matched depressions (n = 404), three metrics were calculated: circularity index, ratio of length to width of the Minimum Bounding Rectangle (MBR) and percent coverage of the MBR by the depression, and 3,634 new sinkholes were identified. Newly developed hotspots were identified in north Johnson City and other areas in the south near the …

Imidacloprid Persistence, Mobility, And Effect On Ecosystem Function, Joanna Hardin

Electronic Theses and Dissertations

Imidacloprid is a neonicotinoid pesticide used to protect against biting and sucking insects. Land managers rely on its systemic properties, however long-term studies investigating imidacloprid effects on ecosystem function are limited. This study investigated imidacloprid applications to Tsuga caroliniana and Tsuga canadensis over time and compared concentrations to measures of ecosystem function including soil respiration, microbial function, and invertebrate density. Results indicate that imidacloprid is persistent (p0.5). Microbial function and invertebrate density were not significantly different between control and treatment locations nor did imidacloprid concentrations correlate with ecosystem functional indicator activity (p>0.05). It is evident that imidacloprid does not …

Nitrogen Cycling During A Period Of Environmental Change, Kaizad Patel

Electronic Theses and Dissertations

Natural and anthropogenic disturbances have altered the N cycle on the regional to global scale. Although numerous studies have examined the effects of chronic atmospheric N deposition on ecosystem processes, less is known about intra-annual variability of these processes, or how these responses might be altered under conditions of changing climate. The work described in this dissertation focuses on the effects of a changing chemical and physical climate, particularly terrestrial N processes (a) during Maine’s changing winters, and (b) in response to chronic elevated N additions.

Subnivean winter soil processes were examined at the Dwight B. DeMerritt Forest (DBDF) and …

Environmental Assessment Of Road Brining And Injection Wells For Disposal Of Oil And Gas Liquid Waste, Marissa Madia

Electronic Theses and Dissertations

The dramatic increase in oil and gas drilling operations in Pennsylvania over the last decade has presented a challenge for their wastewater disposal (e.g., flowback, produced water). Currently, these fluids are treated in permitted brine treatment plants or exported out of state to deep injection well facilities. In Pennsylvania, road brining for dust control is permitted for conventional well brines, and permits for three injection wells for unconventional brines are pending. This study focused on water quality impacts due to road brining in Farmington Township (45 samples) and ground and surface water in Grant Township (41 samples) prior to the …

New Approaches To Mapping Forest Conditions And Landscape Change From Moderate Resolution Remote Sensing Data Across The Species-Rich And Structurally Diverse Atlantic Northern Forest Of Northeastern North America, Kasey R. Legaard

Electronic Theses and Dissertations

The sustainable management of forest landscapes requires an understanding of the functional relationships between management practices, changes in landscape conditions, and ecological response. This presents a substantial need of spatial information in support of both applied research and adaptive management. Satellite remote sensing has the potential to address much of this need, but forest conditions and patterns of change remain difficult to synthesize over large areas and long time periods. Compounding this problem is error in forest attribute maps and consequent uncertainty in subsequent analyses. The research described in this document is directed at these long-standing problems.

Chapter 1 demonstrates …