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Miscible Column Studies Of Unfractured And Saturated Cores Of Topopah Spring Tuff From Yucca Mountain, Nevada Using Hydrophobic Organic Pollutants, Kody V. Kramer
LSU Master's Theses
Miscible displacement column studies were conducted on unfractured cores of Topopah Spring Tuff to quantify transport characteristics of bromide&44; pentafluorobenzoic acid &40;PFBA&41;&44; trichloroethylene &40;TCE&41;&44; and naphthalene. Three 5 cm diameter by 2 cm long cores were flushed with pulses of simulated groundwater containing these tracers&44; followed by tracer&45;free solution. Effective porosities were gravimetrically measured as 11&37;&44; 10.6&37;&44; and 9.5&37;. The tracers achieved full breakthrough in an order correlating to their hydrophobicities. Bromide and PFBA sorbed least&44; achieving full breakthrough in fewer than 10 pore volumes. As water analogues&44; both exhibited no quantifiable sorption. Delay to full breakthrough was contributed to …