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Isotopes Of Carbon In A Karst Aquifer Of The Cumberland Platea Of Kentucky , Usa, Lee J. Florea Dec 2013

Isotopes Of Carbon In A Karst Aquifer Of The Cumberland Platea Of Kentucky , Usa, Lee J. Florea

Lee J Florea, PhD, P.G.

In this study, the concentration and isotopic composition of dissolved organic carbon (DOC) and dissolved inorganic carbon (DIC) are measured in the karst groundwater of the Otter Creek watershed of the Cumberland Plateau of Kentucky, USA. Comparisons among these data and with the geochemistry of carbonate and gypsum equilibrium reactions reveal that DOC concentration is inversely related to discharge, multiple reaction pathways provide DIC with isotopic enrichment that may be directly related to mineral saturation, and oxidation of reduced sulfur is possible for dissolution. DOC is derived from C3 vegetation with an average δ13CDOC of ‒27‰. DIC in groundwater is …


Preliminary Summary Of Water Resource Investigations During 2012 At Timpanogos Cave National Monument, Utah, Lee J. Florea, Chelsie R. Dugan, Camille Mckinney Nov 2013

Preliminary Summary Of Water Resource Investigations During 2012 At Timpanogos Cave National Monument, Utah, Lee J. Florea, Chelsie R. Dugan, Camille Mckinney

Lee J Florea, PhD, P.G.

This manuscript considers the hydrology and geochemistry of water resources within Timpanogos Cave National Monument in American Fork, Utah. In particular, data are presented for five cave pools within the Monument and the American Fork River that flows through the Monument. Two independent dye trace attempts in this study have not established a connection between the surface near the canyon rim at the south border of the Monument and the cave pools or the river. Ion chemistry of the pools reveals elevated sulfate concentrations. Analysis of sulfate and other reaction products suggests the possibility of combined carbonic and sulfuric acids …


Investigations Into The Potential For Hypogene Speleogenesis In The Cumberland Plateau Of Southeast Kentucky, U.S.A., Lee J. Florea Jul 2013

Investigations Into The Potential For Hypogene Speleogenesis In The Cumberland Plateau Of Southeast Kentucky, U.S.A., Lee J. Florea

Lee J Florea, PhD, P.G.

This manuscript offers preliminary geochemical evidence that investigates the potential for hypogene speleogenesis in the Cumberland Plateau of southeastern Kentucky, U.S.A. The region was traditionally considered a classic example of epigenic karst, but new insights have uncovered tantalizing observations that suggest alternatives to simple carbonic acid speleogenesis. Such first-order observations have included natural petroleum seeps at the surface and in caves, occasional cave morphologies consistent with action of hypogene fluids, and prolific gypsum within cave passages. To this point, geochemical data from caves and springs verify carbonic acid as the primary dissolutional agent; however, these same analyses cannot rule out …


Background Fluorescence In Groundwater From A Tropical Karst Island Aquifer, Michelle Hoffman Sep 2010

Background Fluorescence In Groundwater From A Tropical Karst Island Aquifer, Michelle Hoffman

Michelle Hoffman

Background levels of four fluorescent compounds were monitored biweekly at thirteen sampling sites on Guam, consisting of subtidal and intertidal springs, dissolution fractures, and internal upland contact spring discharge, over a 13-month period from 2006 to 2007. Samples were compared to local precipitation and to seawater samples from four nearby reef flats. The data revealed that the concentrations of optical brighteners were consistently two orders of magnitude greater than either sodium fluorescein or rhodamine WT, while Eosine Y was rarely detected. Background levels in seawater, by comparison, accounted for 25% or more of the fluorescent compounds detected at the thirteen …


Visualization Of Groundwater Flow Within Touching-Vug And Matrix Porosity In An Eogenetic Karst Aquifer, Lee J. Florea, Kevin J. Cunningham, Stephen Altobelli Jan 2008

Visualization Of Groundwater Flow Within Touching-Vug And Matrix Porosity In An Eogenetic Karst Aquifer, Lee J. Florea, Kevin J. Cunningham, Stephen Altobelli

Lee J Florea, PhD, P.G.

In this study, we use an innovative, non-invasive technology, nuclear magnetic resonance imaging (NMRI), to visualize the direction and magnitude of groundwater flow in field samples of late Pleistocene limestone of the Biscayne aquifer. Specific goals of the first set of NMRI experiments are to map the advective velocity of water flowing at two rates of specific discharge (0.00025 and 0.00013 m/s) through a 10-cm-diameter cylindrical, epoxy-resin model. The model interior accurately reproduces a well-connected maze of ichnologically influenced, centimeter-scale, touching-vug macroporosity common within preferred flow zones in parts of the Biscayne aquifer. A second set of NMRI experiments investigates …


Biogenic Porosity And Its Lattice Boltzmann Method Permeability In The Karst Biscayne Aquifer, Kevin Cunningham, Mike Sukop, Haibo Huang, Pedro Alvarez, Allen Curran, Michael Waker, Lee J. Florea, Robert Renken, Joann F. Dixon Jan 2008

Biogenic Porosity And Its Lattice Boltzmann Method Permeability In The Karst Biscayne Aquifer, Kevin Cunningham, Mike Sukop, Haibo Huang, Pedro Alvarez, Allen Curran, Michael Waker, Lee J. Florea, Robert Renken, Joann F. Dixon

Lee J Florea, PhD, P.G.

No abstract provided.


Solute Transport Through Laboratory-Scale Karstic Aquifers, Lee J. Florea, Carol M. Wicks Apr 2001

Solute Transport Through Laboratory-Scale Karstic Aquifers, Lee J. Florea, Carol M. Wicks

Lee J Florea, PhD, P.G.

Laboratory-scale models of branchwork and of network karstic aquifers were constructed to provide data needed for calibration of numerical models. The distribution and connectedness of the conduits and sinkholes were scaled similarly to those found in nature; however, the porosity of models (2 and 3%) and the recharge rate (80 cm/hr) could not be scaled appropriately. Pulses of 1-M NaCl were injected sequentially at ten locations on both models to determine transport parameters using QTRACER. For all experiments, the Reynolds numbers were <150, the Peclet numbers were >6, and the Froude numbers were ~0. The flow regime was laminar and subcritical and advective processes dominated …