Open Access. Powered by Scholars. Published by Universities.®

Earth Sciences Commons

Open Access. Powered by Scholars. Published by Universities.®

2019

Geochemistry

Discipline
Institution
Publication
Publication Type

Articles 1 - 28 of 28

Full-Text Articles in Earth Sciences

Geomorphology And Geochronology Of Sand Ramps Adjoining The Coral Pink Sand Dunes, Kane County, Utah, Kerri E. Spuller Dec 2019

Geomorphology And Geochronology Of Sand Ramps Adjoining The Coral Pink Sand Dunes, Kane County, Utah, Kerri E. Spuller

Boise State University Theses and Dissertations

Projected climate change is expected to have widespread impacts on arid regions of the world. Inland, continental dune fields are sensitive to changes in climate and the surrounding environment and are an important source for understanding interactions between Earth’s surface, atmosphere, and biosphere in drylands. Reconstructing past periods of aeolian activity from dune fields can provide insights into how landscapes have responded to previous changes in climate. However, the nature of aeolian systems to recycle older deposits leads to a preservation bias towards only the youngest deposits. Targeting geomorphic settings that are conducive to preserving older records is critical to …


Effects Of Reservoir Conditions And Trace Co-Contaminant Gases On Geological Carbon Sequestration, Ram Kumar Nov 2019

Effects Of Reservoir Conditions And Trace Co-Contaminant Gases On Geological Carbon Sequestration, Ram Kumar

USF Tampa Graduate Theses and Dissertations

Geological carbon sequestration in a saline formation is a promising technology for large-scale carbon dioxide (CO2) mitigation. Several factors such as temperature, pressure, salinity, hydraulic conductivity, and mineralogy of a formation affect the CO2 sequestration in saline formations. These factors can vary widely depending upon the type of formation or the degree of heterogeneity within a formation. In addition to these properties of the repositories, the CO2-rich flue gas streams captured from point sources often contains small amounts of impurities such as sulfur oxides (SOx) and nitrogen oxides (NOx), which may have serious implications on the chemistry of the repositories …


Exploring Planetary Surfaces With Remote Sensing, Donald R. Hood Nov 2019

Exploring Planetary Surfaces With Remote Sensing, Donald R. Hood

LSU Doctoral Dissertations

Aside from Earth, Mars is the most well-explored planetary body in our solar system. Much has been learned about its geologic past including a history of volcanism, ice ages, and potentially long-lasting liquid water. Much of this knowledge of Mars comes from remote observations of the surface and atmosphere from Mars-orbiting satellites. Such remote observations remain the only way to examine the entirety of Mars’ surface as rovers and landers can only examine small areas. The chapters of this work cover three projects that explore the surface of Mars through a variety of remote sensing methods.

In chapter 1, Gamma-ray …


Geochemistry And Tectonic Signifi Cance Of The Ophiolitic Rocks Of The Yarpuz-Kaypak (Amanoslar, Osmaniye) Area, Tamer Rizaoğlu, Utku Bağci, Osman Parlak Aug 2019

Geochemistry And Tectonic Signifi Cance Of The Ophiolitic Rocks Of The Yarpuz-Kaypak (Amanoslar, Osmaniye) Area, Tamer Rizaoğlu, Utku Bağci, Osman Parlak

Bulletin of the Mineral Research and Exploration

Yarpuz-Kaypak (Osmaniye) region, located in Amanos Mountains, contains harzburgitic tectonites and mafic cumulates. The tectonites are represented by serpantinized harzburgites, whereas the cumulates are characterized by gabbronorite and gabbro compositions. The crystallization order within the cumulates is clinopyroxene, orthopyroxene plagioclase and amphibole. The major element compositions of the tectonites and cumulate rocks are consistent with formation in an arc-related tectonic setting. Trace element concentrations of these rocks exhibit large ion litophile element enrichments. Both geochemical and petrographic evidence suggest that the tectonite and cumulate rocks from the Yarpuz-Kaypak (Osmaniye) region represent the remnants of an oceanic lithosphere that formed in …


Investigation And Classification Of Planetary Materials And Surfaces Using Novel Methods To Analyze Large Compositional Datasets: Quantitative X-Ray Compositional Mapping And Lunar Reconnaissance Orbiter Narrow Angle Camera Photometric Analysis, Timothy Michael Hahn Aug 2019

Investigation And Classification Of Planetary Materials And Surfaces Using Novel Methods To Analyze Large Compositional Datasets: Quantitative X-Ray Compositional Mapping And Lunar Reconnaissance Orbiter Narrow Angle Camera Photometric Analysis, Timothy Michael Hahn

Arts & Sciences Electronic Theses and Dissertations

Our understanding of planetary bodies and their surfaces originates from measurements made by spacecraft instruments and laboratory analysis of extraterrestrial materials. Integration of these datasets can significantly advance the fields of planetary geology and geochemistry. The goal of my dissertation research has been to develop novel methods for interrogating extraterrestrial samples and planetary regoliths, with an emphasis on integrating these complementary datasets. Additionally, my research has focused on utilizing ‘big data’ within the geoscience and planetary science communities, whether that data be geospatial or geochemical in nature. My dissertation research involves two separate, but related projects: (1) coupling Apollo 17 …


The Paleozoic Sedimentary Rocks Of The Ouachita Mountains And Their Genetic Relationship To The Mississippi Valley-Type Mineralization In The Southern Ozark Region: Insights From Radiogenic Pb Isotopes And Trace Elements Studies, Christophe Wakamya Simbo Aug 2019

The Paleozoic Sedimentary Rocks Of The Ouachita Mountains And Their Genetic Relationship To The Mississippi Valley-Type Mineralization In The Southern Ozark Region: Insights From Radiogenic Pb Isotopes And Trace Elements Studies, Christophe Wakamya Simbo

Graduate Theses and Dissertations

Cluster of Pb and/or Zn deposits of the well-known Tri-State and Northern Arkansas Mississippi Valley Type (MVT) districts located north of the Arkoma basin and the Ouachita fold-thrust belt in north America are genetically connected to the Pennsylvanian-Permian Ouachita orogeny which triggered a South-North topographic gradient flow of basinal brines, leaching metal rich sediments en route. The objective of the research is twofold. First, to ascertain whether the organic-rich shales and sandstones from the study area provided metals during the mineralization event, which was coeval with the Ouachita orogeny. Second, to assess the depositional environment of the potential source rocks, …


A Metasomatized Lithospheric Mantle Control On The Metallogenic Signature Of Post-Subduction Magmatism, David A. Holwell, Marco Fiorentini, Iain Mcdonald, Yongjun Lu, Andrea Giuliani, Daniel J. Smith, Manuel Keith, Marek Locmelis Aug 2019

A Metasomatized Lithospheric Mantle Control On The Metallogenic Signature Of Post-Subduction Magmatism, David A. Holwell, Marco Fiorentini, Iain Mcdonald, Yongjun Lu, Andrea Giuliani, Daniel J. Smith, Manuel Keith, Marek Locmelis

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Ore deposits are loci on Earth where energy and mass flux are greatly enhanced and focussed, acting as magnifying lenses into metal transport, fractionation and concentration mechanisms through the lithosphere. Here we show that the metallogenic architecture of the lithosphere is illuminated by the geochemical signatures of metasomatised mantle rocks and post-subduction magmatic-hydrothermal mineral systems. Our data reveal that anomalously gold and tellurium rich magmatic sulfides in mantle-derived magmas emplaced in the lower crust share a common metallogenic signature with upper crustal porphyry-epithermal ore systems. We propose that a trans-lithospheric continuum exists whereby post-subduction magmas transporting metal-rich sulfide cargoes play …


Evaluating Sources Of Hydrochemical Variability And Mixing In The Upper Gila River, New Mexico, Pavel Vakhlamov Jul 2019

Evaluating Sources Of Hydrochemical Variability And Mixing In The Upper Gila River, New Mexico, Pavel Vakhlamov

Earth and Planetary Sciences ETDs

This study of the upper reaches of the Gila River basin in southwestern New Mexico reveals both spatial and seasonal patterns in physical and hydrochemical parameters. Monsoonal precipitation, temporal variability in water chemistry of streams in the upper Gila watershed is significantly impacted by surface runoff due to variability in landscape cover features, as well as surface area of the catchment. However, during base flow regimes spring inputs are the dominant drivers of solute concentrations and chemical variability.

Geothermal sources play a major role in salinization of the southwestern stream systems. Prolonged water/rock interaction combined with high temperature, pressure result …


Natural Salinization Of The Jemez River, New Mexico: An Insight From Trace Element Geochemistry, Jon K. Golla Jul 2019

Natural Salinization Of The Jemez River, New Mexico: An Insight From Trace Element Geochemistry, Jon K. Golla

Earth and Planetary Sciences ETDs

The Jemez River, a tributary of the Rio Grande in north-central New Mexico, receives thermal water input from the geofluids of the Valles Caldera, an active, high-temperature, liquid-dominated geothermal system. We focus on a ∼50-km portion of the northern Jemez River. This research extends previous decadal work (Crossey et al., in prep., 2013) on major chemistry in the river by characterizing the response of 16 trace elements to geochemical contributions from geothermal waters (McCauley, Spence, Soda Dam, and Jemez Springs springs and San Ysidro mineral waters), an area with copious hydrothermal degassing (Hummingbird), and two major tributaries (Rio San Antonio …


A Survey Of Sierra Nevada Magmatism Using Great Valley Detrital Zircon Trace-Element Geochemistry: View From The Forearc, Kathleen D. Surpless, D. Clemens-Knott, A. P. Barth, M. Gevedon Jul 2019

A Survey Of Sierra Nevada Magmatism Using Great Valley Detrital Zircon Trace-Element Geochemistry: View From The Forearc, Kathleen D. Surpless, D. Clemens-Knott, A. P. Barth, M. Gevedon

Kathleen D. Surpless

The well-characterized Sierra Nevada magmatic arc offers an unparalleled opportunity to improve our understanding of continental arc magmatism, but present bedrock exposure provides an incomplete record that is dominated by Cretaceous plutons, making it challenging to decipher details of older magmatism and the dynamic interplay between plutonism and volcanism. Moreover, the forearc detrital record includes abundant zircon formed during apparent magmatic lulls, suggesting that understanding the long-term history of arc magmatism requires integrating plutonic, volcanic, and detrital records. We present trace-element geochemistry of detrital zircon grains from the Great Valley forearc basin to survey Sierra Nevadan arc magmatism through Mesozoic …


Impacts Of Glacial Meltwater On Geochemistry And Discharge Of Alpine Proglacial Streams In The Wind River Range, Wyoming, Usa, Natalie Shepherd Barkdull Jul 2019

Impacts Of Glacial Meltwater On Geochemistry And Discharge Of Alpine Proglacial Streams In The Wind River Range, Wyoming, Usa, Natalie Shepherd Barkdull

Theses and Dissertations

Shrinking alpine glaciers alter the geochemistry of sensitive mountain streams by exposing reactive freshly-weathered bedrock and releasing decades of atmospherically-deposited trace elements from glacier ice. Changes in the timing and quantity of glacial melt also affect discharge and temperature of alpine streams. To investigate the effects of glacier ice melt on the geochemistry and hydrology of proglacial streams in the arid Intermountain West, we sampled supraglacial meltwaters and proglacial streams in the Dinwoody Creek watershed in the Wind River Range, Wyoming during late summer 2015, when the contributions of glacier meltwater were highest. Supraglacial meltwater was enriched in 8 trace …


Extreme Oxygen Isotope Zoning In Garnet And Zircon From A Metachert Block In Melange Reveals Metasomatism At The Peak Of Subduction Metamorphism, F. Zeb Page, Emilia M. Cameron, Clara Margaret Flood, Jeffrey W. Dobbins, Michael J. Spicuzza, Kouki Kitajima, Ariel Strickland, Takayuki Ushikubo, Christopher G. Mattinson, John W. Valley Jul 2019

Extreme Oxygen Isotope Zoning In Garnet And Zircon From A Metachert Block In Melange Reveals Metasomatism At The Peak Of Subduction Metamorphism, F. Zeb Page, Emilia M. Cameron, Clara Margaret Flood, Jeffrey W. Dobbins, Michael J. Spicuzza, Kouki Kitajima, Ariel Strickland, Takayuki Ushikubo, Christopher G. Mattinson, John W. Valley

Faculty & Staff Scholarship

A tectonic block of garnet quartzite in the amphibolite-facies melange of the Catalina Schist (Santa Catalina Island, California, USA) records the metasomatic pre-treatment of high-delta O-18 sediments as they enter the subduction zone. The block is primarily quartz, but contains two generations of garnet that record extreme oxygen isotope disequilibrium and inverse fractionations between garnet cores and matrix quartz. Rare millimeter-scale garnet crystals record prograde cation zoning patterns, whereas more abundant similar to 200-mu m-diameter crystals have the same composition as rims on the larger garnets. Garnets of both generations have high-delta O-18 cores (20.8 parts per thousand-26.3 parts per …


Geochemical Analysis Of The Chinchín Formation In Southern Ecuador, Katherine Ludwig May 2019

Geochemical Analysis Of The Chinchín Formation In Southern Ecuador, Katherine Ludwig

Celebration of Learning

The subduction of the Nazca Plate under the South American Plate has led to the uplift of the majority of the Andes Mountains, but in Ecuador, the Nazca Plate subducts underneath the North Andes Plate, which then collides with the South American Plate. This tectonic setting has formed two parallel mountain chains as well as a complex series of basins between them. However, the formations that make up these basins are poorly understood. This study focuses on the Chinchín Formation, an ~3.5 km thick, volcanic formation that serves as the bedrock of the Quingeo Basin in southern Ecuador. This study …


Structural Control Of Thermal Fluid Circulation And Geochemistry In A Flat-Slab Subduction Zone, Peru, Brandt E. Scott May 2019

Structural Control Of Thermal Fluid Circulation And Geochemistry In A Flat-Slab Subduction Zone, Peru, Brandt E. Scott

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Hot spring geochemistry from the Peruvian Andes provide insight on how faults, or fractures in the Earth's crust, are capable of influencing fluid circulation. Faults can either promote or inhibit fluid flow and the goal of this study is test the role of a major fault, such as the Cordillera Blanca detachment, as a channel for transporting deep fluids to the surface. Hot springs are abundant in the Cordillera Blanca and Huayhuash ranges in Peru, and several springs issue along the Cordillera Blanca detachment, making this region an ideal setting for our study. To test the role of the Cordillera …


Petrogenesis Of The El Rechuelos Rhyolite, Jemez Mountains Volcanic Field, New Mexico, Usa, Kelsy Jo Konkright May 2019

Petrogenesis Of The El Rechuelos Rhyolite, Jemez Mountains Volcanic Field, New Mexico, Usa, Kelsy Jo Konkright

UNLV Theses, Dissertations, Professional Papers, and Capstones

The El Rechuelos Rhyolite represents volcanic activity preceding the multiple caldera collapse events of the Jemez Mountains volcanic field (JMVF) in northern New Mexico. This study focuses on seven rhyolitic units clustered north of the Valles caldera. These units have been studied in order to interpret their relationships to one another and the eruptive history of the JMVF. Additionally, this study adds to the research on the relationships between effusive and explosive rhyolitic volcanism, and understanding how caldera-forming eruptions develop from silicic systems.

Limited previous research includes K/Ar dates and a few inconsistent 40Ar/39Ar dates, in addition to whole rock …


Geochemical Characteristics Of Sabalan Volcanic Rocks In Northwestern Iran, Reza Fahim Guilany, Ali Darvishzadeh, Seyed Jamal Sheikhzakariaee, Mansour Vosoughi Abedini Apr 2019

Geochemical Characteristics Of Sabalan Volcanic Rocks In Northwestern Iran, Reza Fahim Guilany, Ali Darvishzadeh, Seyed Jamal Sheikhzakariaee, Mansour Vosoughi Abedini

Bulletin of the Mineral Research and Exploration

Sabalan is a voluminous stratovolcano situated in the northwestern part of Alborz-Azerbaijan zone, 25km from Meshkinshahr. It is separated by tectonic faults from Sarab plain and Meshkinshahr. The composition of Sabalan volcanic rocks ranges from andesite, trachyandesite to dacite. The rocks have hypocrystalline porphyritic texture with a glassy matrix and microlite . Plagioclase, amphibole, pyroxene, biotite, and oxides are the main phenocryst phase of the rocks. Some plagioclases show disequilibrium textures (sieve texture and oscillatory zoning). The sieve texture and oscillatory zoning in the plagioclases may be indicative of magma mixing processes in the genesis of the Sabalan volcanic rocks. …


Hydro-Chemical And Isotopic Investigation Of The İspendere Mineral And Thermal Water Springs, Malatya, Turkey, Murat Çeliker, Ömer Faruk Dursun, Mahmut Fırat Apr 2019

Hydro-Chemical And Isotopic Investigation Of The İspendere Mineral And Thermal Water Springs, Malatya, Turkey, Murat Çeliker, Ömer Faruk Dursun, Mahmut Fırat

Bulletin of the Mineral Research and Exploration

The objective of this study is to determine the source, chemical characteristics and isotopic components of the İspendere mineral and thermal waters, Malatya, Turkey. There are many mineral and thermal water springs in the area with flow rates ranging between 0.01 – 0.4 l/s. Geochemical and isotope chemistry studies were carried out at three different thermal springs in the region as well as three different cold water springs during May-October 2011. The temperature of mineral and thermal waters were measured as between 21.1°C – 23.6°C in May 2011 and as 20.8°C in October 2011. The region was determined as a …


Petrology Of The Earliest Cascade Volcanic Units In Washington: The Northcraft, Tukwila, And Rattlesnake Mountain Formations And Implications For The Evolution Of The Cascade Arc, Louisa Cryan, Jeffrey H. Tepper Jan 2019

Petrology Of The Earliest Cascade Volcanic Units In Washington: The Northcraft, Tukwila, And Rattlesnake Mountain Formations And Implications For The Evolution Of The Cascade Arc, Louisa Cryan, Jeffrey H. Tepper

Summer Research

Cascade arc magmatism began ~45 million years ago, following the reconfiguration of the Farallon-North American subduction zone. This project seeks to classify the path of magmatism throughout the history of the Cascade arc, as well as categorize the earliest expressions of the Cascade arc. Three volcanic units, the Northcraft Formation (NF), Tukwila Formation (TF), and Rattlesnake Mountain Formation (RM) will serve as examples of the earliest Cascades-related lavas. Their categorization by field setting, geochemical characteristics, isotopic data, and age will create a better understanding of how Cascades magmatism began and developed over time.

Analysis has shown these units to contain …


Investigating Cascade Magmatism Through Dating And Chemical Analysis Of The Hatchet Mountain And Pe Ell Formations, Sw Wa, Robyn Organ, Jeffery Tepper, Wesely Von Dassow, Tabor Reedy Jan 2019

Investigating Cascade Magmatism Through Dating And Chemical Analysis Of The Hatchet Mountain And Pe Ell Formations, Sw Wa, Robyn Organ, Jeffery Tepper, Wesely Von Dassow, Tabor Reedy

Summer Research

Modern Cascade arc magmatism began ~45 Ma, shortly after accretion of the Siletzia terrane culminated at ~50 Ma. The earliest expressions of this magmatism are several petrologically-diverse volcanic units in SW Washington including: (1) the Goble Volcanics (GV) / Hatchet Mountain Formation (HM), (2) the Pe Ell Formation (PE), and (3) scattered exposures of unnamed basalts (UB). These rocks, all dominantly subaerial lavas, occur west of the modern arc where they are interbedded with marine and deltaic sedimentary units, suggesting eruption in a forearc or volcanic front setting. Goals of this study are: (1) to characterize the elemental and Sr-Nd …


Petrology Of The Eocene Goble Volcanics, Southwest Washington: An Early Phase Of The Cascade Arc, Clara Phipps, Jeffrey H. Tepper Jan 2019

Petrology Of The Eocene Goble Volcanics, Southwest Washington: An Early Phase Of The Cascade Arc, Clara Phipps, Jeffrey H. Tepper

Summer Research

The Eocene Goble Volcanics (GV), comprised of >1000 km2 of subaerial lavas and tuffs, are one of the most voluminous igneous formations in SW WA. Whole rock K-Ar ages of 45 to 32 Ma (Beck and Burr, 1979) suggest these rocks are an early expression of the Cascade arc, but their location is anomalous, lying between oceanic Crescent Fm basalts of the Siltezia terrane to the west and younger arc rocks to the east. The goals of this research are to determine the chemical and Sr-Nd isotopic traits of the GV and better establish the tectonic setting in which …


Mineralogy And Geochemistry Of Feed Coals And Combustion Residues Of The Kangal Power Plant (Sivas, Turkey), Ali̇ İhsan Karayi̇ği̇t, Riza Görkem Oskay, Rod A. Gayer Jan 2019

Mineralogy And Geochemistry Of Feed Coals And Combustion Residues Of The Kangal Power Plant (Sivas, Turkey), Ali̇ İhsan Karayi̇ği̇t, Riza Görkem Oskay, Rod A. Gayer

Turkish Journal of Earth Sciences

This study focuses on mineralogical and geochemical compositions of feed coal (FC) and combustion residues, namely fly ash (FA) and bottom ash (BA) samples, obtained from the Kangal coal-fired power plant in central Turkey. The X-ray powder diffraction data indicate that carbonate and clay minerals are dominant phases in the FC samples. In the FA samples, quartz, hematite, anhydrite, lime, and feldspar are generally dominant and abundant phases, whereas calcite, ettringite, and portlandite are generally more abundant in the BA samples. The elements Mo, Cs, and U are significantly enriched in the studied FC, FA, and BA samples. The statistical …


Upper Cretaceous Volcaniclastic Complexes And Calcareous Plankton Biostratigraphy Inthe Western Pontides, Nw Turkey, Katharina Boehm, Michael Wagreich, Erik Wolfgring, Okan Tüysüz, Susanne Gier, İsmai̇l Ömer Yilmaz Jan 2019

Upper Cretaceous Volcaniclastic Complexes And Calcareous Plankton Biostratigraphy Inthe Western Pontides, Nw Turkey, Katharina Boehm, Michael Wagreich, Erik Wolfgring, Okan Tüysüz, Susanne Gier, İsmai̇l Ömer Yilmaz

Turkish Journal of Earth Sciences

This study describes and interprets Upper Cretaceous volcaniclastics interbedded with hemipelagic to pelagic limestones, marls, and turbidites from the Western Pontides, northwestern Turkey. The Dereköy Formation, the Unaz Formation (red pelagic limestone unit), and the Cambu Formation can be distinguished, overlain by the turbiditic Akveren Formation. Biostratigraphic ages from the predominantly volcaniclastic Dereköy Formation indicate Turonian (Dicarinella concavata planktonic foraminifera zone, CC13/UC8-9 nannofossil zones) to middle/late Santonian ages up to CC17/UC13. The Unaz Formation, deposited during the late Santonian (UC13, Dicarinella asymetrica Zone), is overlain by the volcaniclastic Cambu Formation of latest Santonian (CC17b/UC13) to early/middle Campanian (CC20/UC15a) age. However, …


A Survey Of Sierra Nevada Magmatism Using Great Valley Detrital Zircon Trace-Element Geochemistry: View From The Forearc, Kathleen D. Surpless, D. Clemens-Knott, A. P. Barth, M. Gevedon Jan 2019

A Survey Of Sierra Nevada Magmatism Using Great Valley Detrital Zircon Trace-Element Geochemistry: View From The Forearc, Kathleen D. Surpless, D. Clemens-Knott, A. P. Barth, M. Gevedon

Geosciences Faculty Research

The well-characterized Sierra Nevada magmatic arc offers an unparalleled opportunity to improve our understanding of continental arc magmatism, but present bedrock exposure provides an incomplete record that is dominated by Cretaceous plutons, making it challenging to decipher details of older magmatism and the dynamic interplay between plutonism and volcanism. Moreover, the forearc detrital record includes abundant zircon formed during apparent magmatic lulls, suggesting that understanding the long-term history of arc magmatism requires integrating plutonic, volcanic, and detrital records. We present trace-element geochemistry of detrital zircon grains from the Great Valley forearc basin to survey Sierra Nevadan arc magmatism through Mesozoic …


Precipitation And Transformation Of Iron-Sulfide Nanoparticles In Low-Temperature Aqueous Environment: Effects Of Reactant Iron And Sulfide Sources, Ezequiel A. Moreno Flores Jan 2019

Precipitation And Transformation Of Iron-Sulfide Nanoparticles In Low-Temperature Aqueous Environment: Effects Of Reactant Iron And Sulfide Sources, Ezequiel A. Moreno Flores

Open Access Theses & Dissertations

Iron sulfide nanoparticles assume an important role within a wide range of geological settings as indicators of redox environmental conditions and elemental cycling mechanisms. Initial precipitates of iron sulfide are exclusively nanoscale sized in low temperature aqueous conditions and have been reported to go through diverse morphological and phase transformations, possibly leading to the ultimate deposits of pyrite in geologic records of various times. A systematic understanding of how the early-stage nanoparticles of iron sulfide may develop into more crystalline iron sulfide forms is still lacking however. The major goal for this study was to illuminate the effects of the …


Variability In Groundwater Flow And Chemistry In The Houzhai Karst Basin, Guizhou Province, China, Joshua M. Barna Jan 2019

Variability In Groundwater Flow And Chemistry In The Houzhai Karst Basin, Guizhou Province, China, Joshua M. Barna

Theses and Dissertations--Earth and Environmental Sciences

Understanding how karst aquifers store and transmit water and contaminants is an ongoing problem in hydrogeology. Flowpath and recharge heterogeneity contribute to the complexity of these systems. This thesis explores karst-conduit connectivity and water chemistry variability in the Houzhai catchment in Guizhou province, China. Artificial tracer tests were conducted during both the monsoon and dry seasons to understand temporal variability in connectivity and water velocity between karst features. Multiple flowpaths through the catchment are activated during the monsoon season and partially abandoned during the dry season. Additionally, gradient reversals during monsoonal high-flow events and as a result of pumping can …


The Early Eocene Ekmekçi Granodiorite Porphyry In The Karacabey Region(Sakarya Zone, Nw Turkey), Gürsel Sunal, Mehmet Korhan Erturaç, Gülteki̇n Topuz, Aral Okay, Thomas Zack Jan 2019

The Early Eocene Ekmekçi Granodiorite Porphyry In The Karacabey Region(Sakarya Zone, Nw Turkey), Gürsel Sunal, Mehmet Korhan Erturaç, Gülteki̇n Topuz, Aral Okay, Thomas Zack

Turkish Journal of Earth Sciences

The Ekmekçi granodiorite porphyry is a unit in the E-W trending, postcollisional Eocene magmatic rocks of northern Anatolia. It occurs as a relatively small stock, but represents a link between plutonic and volcanic rocks. This Early Eocene granodiorite porphyry intruded into the Upper Triassic rocks of the Karakaya complex in the Sakarya Zone. In this study we present geochemical and zircon U-Pb LA-ICP-MS age data to contribute to understanding the Early Tertiary postcollisional tectonic setting of NW Anatolia. The granodiorite porphyry includes plagioclase, quartz, hornblende, K-feldspar, biotite, and minor zircon, apatite, sphene, and opaque minerals. The stock displays medium-K calc-alkaline …


Petrography, Geochemistry, And Provenance Of Jurassic Sandstones From Thesakarya Zone, Nw Turkey, Firat Şengün, Osman Ersi̇n Koralay Jan 2019

Petrography, Geochemistry, And Provenance Of Jurassic Sandstones From Thesakarya Zone, Nw Turkey, Firat Şengün, Osman Ersi̇n Koralay

Turkish Journal of Earth Sciences

The Jurassic sandstones exposed in the western part of the Sakarya Zone are yellowish to brown, moderate to well sorted, medium to coarse-grained, grain-supported, and cemented by calcareous and minor silica. Sandstones are mainly classified as litharenite, subarkose, and arkose according to the relative proportions of quartz, feldspar and rock fragments, and major element ratios. On the SiO2 variation diagram, Na2O and K2O show slight positive correlations, which could reflect abundance of sodic plagioclase and K-feldspar with quartz within high Si-content sandstones. Sandstones generally exhibit slight LREE enrichment with respect to HREEs. The REE plots are characteristic for sedimentary rocks …


The Medicine Hat Block And The Assembly Of Laurentia: New Interpretations From Single-Grain Zircon Analyses, Blake Oswell Ladouceur Jan 2019

The Medicine Hat Block And The Assembly Of Laurentia: New Interpretations From Single-Grain Zircon Analyses, Blake Oswell Ladouceur

Electronic Theses and Dissertations

The Medicine Hat Block (MHB) is one of the core cratonic elements that amalgamated in the Paleoproterozoic to form Laurentia. However the role of the MHB in the formation of Laurentia is poorly constrained due to virtually all of the MHB being concealed by Proterozoic and younger supracrustal sequences limiting availability of data. The primary sources of samples from the MHB are 1) xenoliths of variable metamorphic grade including gneisses amphibolites and meta-plutonic rocks collected from Eocene volcanic rock; and 2) similar lithologies recovered from boreholes that penetrate to the MHB basement. Previous work on samples from the MHB yielded …