Earth Sciences Commons^™

A Preliminary Study Of Sulfide Mineral Formation In Methane-Rich, Marine Sediments Associated With Anaerobic Methane Oxidation, Cascadia Continental Margin, Offshore Oregon, David Deigert, Walter S. Borowski

EKU Faculty and Staff Scholarship

Within gas hydrate settings, sulfide mineralization in marine sediments is likely controlled by two microbially-mediated, sulfate-depleting processes: anaerobic methane oxidation (AMO) and sulfate reduction. If large amounts of methane are delivered to the sulfate-methane interface (SMI), predominantly by diffusion, larger amounts of solid sulfide sulfur should occur there as dissolved sulfide combines with iron, forming an authigenic precipitate. We measure the amount of diagenetic sulfide sulfur at three locations in the Hydrate Ridge vicinity by extracting the bulk sedimentary sulfide-phase minerals (S^o, FeS, and FeS₂) through chromium reduction, precipitating sulfide sulfur as silver sulfide, and gravimetrically …

A Geologic Record Of Competing Sulfate-Depletion Processes Within Continental-Rise Sediments Overlying Methane Gas Hydrates Of The Blake Ridge Region (Continental Rise, Offshore Southeastern United States), Walter S. Borowski, Kathryn G. Takacs, Matthew K. Thompson

EKU Faculty and Staff Scholarship

Geochemical signals locked within sediments and sedimentary rocks record geochemical processes through geologic time. Sulfide minerals (elemental sulfur, iron monosulfides, and pyrite) are formed within marine sediments as dissolved sulfide is produced by various geochemical processes, which include sulfate reduction and anaerobic methane oxidation (AMO). The concentration and sulfur isotopic composition (d³⁴S) of sulfide minerals gives clues about the relative importance of these competing geochemical processes, and consequently about sedimentation rates and upward methane transport.

Marine sediments of the Blake Ridge(offshore South Carolina and Georgia) contain sulfide minerals that point to AMO as an important diagenetic process both …

A Preliminary Comparison Of The Sulfur Geochemistry Between Two Gas Hydrate Terranes, Michael D. Spicer, Walter S. Borowski

EKU Faculty and Staff Scholarship

We compare the authigenic sulfide mineral geochemistry of two, different gas hydrate terranes: the accretionary wedge of the Cascadia continental margin (offshore Oregon) and the passive margin of the Blake Ridge region (offshore southeastern US). We expect diagenetic processes effecting sulfide mineral formation (elemental sulfur, iron monosulfides, and pyrite) within these sediments to respond to differing geologic conditions at each setting. In both settings, methane diffuses upward from gas hydrates to the methane-sulfate interface (SMI), where it is consumed by reaction with sulfate during anaerobic methane oxidation (AMO). This microbially-mediated, diagenetic process produces an interstitial environment conducive to authigenic sulfide …