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Full-Text Articles in Earth Sciences

Secondary Minerals From Extrapedogenic Per Latus Acidic Weathering Environments At Geomorphic Edges, Eastern Nebraska, Usa, Robert Matthew Joeckel, K.D. Wally, B.J. Ang Clement, P.R. Hanson, J.S. Dillon, S.K. Wilson Jan 2011

Secondary Minerals From Extrapedogenic Per Latus Acidic Weathering Environments At Geomorphic Edges, Eastern Nebraska, Usa, Robert Matthew Joeckel, K.D. Wally, B.J. Ang Clement, P.R. Hanson, J.S. Dillon, S.K. Wilson

Conservation and Survey Division

Acidic weathering of the sulfidic Upper Cretaceous Carlile and Pierre Shales in Nebraska has led to the precipitation of the Al sulfate–hydroxide minerals aluminite, alunite, “basaluminite”/felsöbányaite (e.g.,), the aluminum hydroxides gibbsite and bayerite, and the rare Al phosphate hydroxide vashegyite. Kaolinite has also been produced as a result of this acidic weathering. These minerals do not appear as neoformed constituents in any extant soils in the region, and their existence underscores the ability of pyrite oxidation to produce major changes in mineralogy on a Holocene to Recent time scale. Jarosite, hydronium jarosite, gypsum, halotrichite, and melanterite also appear as secondary …


Foundation Problems And Pyrite Oxidation In The Chattanooga Shale, Estill County, Kentucky, Warren H. Anderson Jan 2008

Foundation Problems And Pyrite Oxidation In The Chattanooga Shale, Estill County, Kentucky, Warren H. Anderson

Report of Investigations--KGS

Pyrite oxidation in the Chattanooga Shale has caused serious foundation problems in numerous buildings and structures in Estill County, Ky. Pyrite oxidizes and various secondary sulfates form when excavated shale or shale fill are used in foundations. These secondary sulfates are water- and humidity-sensitive and can form when only minor amounts of water are present in foundation materials. These sulfates form by crystal growth and expand by volume change, which causes subsequent soil expansion and heaving of any foundation materials when the materials are confined. Several structures have undergone expensive remediation to repair damaged sidewalks, floors, walls, and foundations. Zones …