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International Journal of Speleology

Sulfuric acid speleogenesis

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Full-Text Articles in Earth Sciences

Sulfuric Acid Speleogenesis And Surface Landform Evolution Along The Vienna Basin Transfer Fault: Plavecký Karst, Slovakia, Pavel Bella, Helena Hercman, Šimon Kdýr, Petr Mikysek, Petr Pruner, Juraj Littva, Jozef Minár, Michal Gradzinski, Wojciech Wróblewski, Marek Velšmid, Pavel Bosak Jul 2022

Sulfuric Acid Speleogenesis And Surface Landform Evolution Along The Vienna Basin Transfer Fault: Plavecký Karst, Slovakia, Pavel Bella, Helena Hercman, Šimon Kdýr, Petr Mikysek, Petr Pruner, Juraj Littva, Jozef Minár, Michal Gradzinski, Wojciech Wróblewski, Marek Velšmid, Pavel Bosak

International Journal of Speleology

Hypogene caves in the Plavecký hradný vrch Hill (Western Slovakia, Central Europe) were formed by waters ascending along faults in fractured Triassic carbonates related to the horst-graben structure at the contact of the Malé Karpaty Mountains and the NE part of the Vienna Basin. The Plavecká jaskyňa and Pec caves mostly contain horizontal passages and chambers with flat corrosion bedrock floors, fissure discharge feeders, wall water-table notches, replacement pockets, as well as a few other speleogens associated with sulfuric acid speleogenesis. The low-temperature sulfuric acid development phases of the Plavecká Jaskyňa are also indicated by the presence of sulfate minerals …


Barite Replacement Boxwork In The Frasassi Caves (Italy), Sandro Galdenzi Sep 2019

Barite Replacement Boxwork In The Frasassi Caves (Italy), Sandro Galdenzi

International Journal of Speleology

The Frasassi caves, located in the Sentino River Gorge in Ancona Province (Marche, Italy), contains boxwork in a small zone in the inner part of the cave system where it is closely associated with subaqueous corrosion produced by sulfuric acid speleogenesis. The boxwork consists of barite that replaces calcite spar-filled veins and limestone porosity and projects from the corroded cave walls. The replacement involved only the calcite that protrudes from the rock surfaces, indicating that the process took place in the cave environment, and therefore the boxwork is not simply a product of differential corrosion. I hypothesize that the boxwork …


Multi-Phased Hypogene Speleogenesis In A Marginal Horst Structure Of The Malé Karpaty Mountains, Slovakia, Pavel Bella, Pavel Bosák, Petr Mikysek, Juraj Littva, Helena Hercman, Jacek Pawlak Aug 2019

Multi-Phased Hypogene Speleogenesis In A Marginal Horst Structure Of The Malé Karpaty Mountains, Slovakia, Pavel Bella, Pavel Bosák, Petr Mikysek, Juraj Littva, Helena Hercman, Jacek Pawlak

International Journal of Speleology

The Plavecká jaskyňa Cave on the western fault edge of the Malé Karpaty Mountains (western Slovakia) is a result of multi-phased hypogene speleogenesis. It formed in fractured Triassic carbonates by waters ascending along the Vienna Basin Transform Fault between Malé Karpaty Mountains and Záhorská nížina Lowland (the north-eastern part of the Vienna Basin) and/or the N–S-trending faults that intersect it in the cave vicinity. Morphologically, the cave is featured by (1) phreatic chimneys, cupolas, ceiling pockets, enlarged fissures with spongework cavities, upward wall channels and upward oriented large scallops, (2) epiphreatic flat corrosion bedrock floors, feeding fissures and wall water-table …


Sulfur (34S/32S) Isotope Composition Of Gypsum And Implications For Deep Cave Formation On The Nullarbor Plain, Australia, Matej Lipar, Mateja Ferk, Sonja Lojen, Milo Barham Sep 2018

Sulfur (34S/32S) Isotope Composition Of Gypsum And Implications For Deep Cave Formation On The Nullarbor Plain, Australia, Matej Lipar, Mateja Ferk, Sonja Lojen, Milo Barham

International Journal of Speleology

Large deep caves with little relation to surface topography are distinctive karst features on the Nullarbor Plain of Australia. The presence of gypsum deposits and chemoautotrophic bacteria within the caves have been suggested as evidence for cave formation and (or) enlargement via sulfuric acid speleogenesis. To test this hypothesis, the stable sulfur isotope compositions (δ34S) of both cave gypsum and surface gypsum were measured. Analyses yielded relatively high, positive δ34S values from both cave gypsum and surface gypsum, arguing against gypsum genesis via microbial chemoautotrophy, and more broadly, sulfuric acid speleogenesis. Instead, the gypsum is interpreted …


U-Pb Dating Of Speleogenetic Dolomite: A New Sulfuric Acid Speleogenesis Chronometer, Victor J. Polyak, Paula P. Provencio, Yemane Asmerom Feb 2016

U-Pb Dating Of Speleogenetic Dolomite: A New Sulfuric Acid Speleogenesis Chronometer, Victor J. Polyak, Paula P. Provencio, Yemane Asmerom

International Journal of Speleology

The 1100-meter Big Room elevation level of Carlsbad Cavern, New Mexico USA, formed 4 Ma by hypogenic sulfuric acid speleogenesis (SAS). The age of the Big Room level of 4.0 ± 0.2 Ma was previously determined by dating alunite, a byproduct of speleogenesis, using the 40Ar/39Ar method. Duplication of these results is possible by radiometric dating of other byproducts interpreted to be speleogenetic (a byproduct of speleogenesis) such as calcite and dolomite in certain settings. XRD and TEM analyses of sample 94044, a piece of crust collected within the Big Room level of SAS just below Left …


Hypogenic Origin Of Provalata Cave, Republic Of Macedonia: A Distinct Case Of Successive Thermal Carbonic And Sulfuric Acid Speleogenesis, Marjan Temovski, Philippe Audra, Andrej Mihevc, Jorge E. Spangenberg, Victor Polyak, William Mcintosh, Jean-Yves Bigot Sep 2013

Hypogenic Origin Of Provalata Cave, Republic Of Macedonia: A Distinct Case Of Successive Thermal Carbonic And Sulfuric Acid Speleogenesis, Marjan Temovski, Philippe Audra, Andrej Mihevc, Jorge E. Spangenberg, Victor Polyak, William Mcintosh, Jean-Yves Bigot

International Journal of Speleology

Provalata Cave (Republic of Macedonia) is a small but remarkable hypogenic cave, developed in Cambrian marbles by successive thermal carbonic and sulfuric acid speleogenesis. The cave has a thick partly corroded calcite crust, abundant gypsum deposits, with cupolas, ceiling and wall channels, feeders and replacement pockets as some of the most characteristic morphological features. Distribution of morphology and deposits suggest a hypogenic origin in two distinct speleogenetic phases: the first by thermal CO2 rich waters, the second by sulfuric acid dissolution, which were separated by complete infilling of cave passages with pyroclastic-derived clays. In the first phase of speleogenesis, …