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Full-Text Articles in Earth Sciences

Subaqueous Carbonate Speleothems As Paleotemperature Archives – Clumped Isotope Thermometry And Stable Isotope Compositions Of Inclusion-Hosted Water, Attila Demeny, Ágnes Berentés, László Rinyu, Ivett Kovács, Gergely Surányi, Magdolna Virág Feb 2024

Subaqueous Carbonate Speleothems As Paleotemperature Archives – Clumped Isotope Thermometry And Stable Isotope Compositions Of Inclusion-Hosted Water, Attila Demeny, Ágnes Berentés, László Rinyu, Ivett Kovács, Gergely Surányi, Magdolna Virág

International Journal of Speleology

Clumped isotope measurements of carbonates and stable isotope analyses of water trapped in fluid inclusions are both promising techniques to determine carbonate formation temperatures. Cave-hosted carbonate deposits (speleothems) are excellent targets for such studies, but kinetic fractionations and diagenetic influences frequently deteriorate the temperature data obtained from these methods. However, subaqueous carbonate deposits may provide reliable data, as kinetic fractionations are less significant in underwater environments. In this study, subaqueous speleothems, whose formation temperatures were directly measured in the water, were investigated. Additionally, temperatures calculated from the oxygen isotope fractionations between calcite and fluid inclusion-hosted water were compared with clumped …


Reverse Pseudo-Gours: A New Sub-Type Of Folia Observed In The Nerja Cave (Se Spain), Cristina Liñán Baena, Concepción Jiménez De Cisneros, Yolanda Del Rosal, Paolo Forti Dec 2023

Reverse Pseudo-Gours: A New Sub-Type Of Folia Observed In The Nerja Cave (Se Spain), Cristina Liñán Baena, Concepción Jiménez De Cisneros, Yolanda Del Rosal, Paolo Forti

International Journal of Speleology

A new sub-type of folia named “reverse pseudo-gour” has been observed and described in the Nerja Cave, southern Spain. It consists of fairly vertical, thin barriers (about 5 mm high and 2 mm thick) that develop on the underside of a sub-horizontal surface (shelfstone) and grow in the opposite direction to normal gours (rimstone dams), generating sinuous shapes. Their mineral composition is essentially calcium carbonate, although globular aggregates composed of clay and phosphate minerals have also been identified. The genesis and evolution of these reverse pseudo-gours occur just at the air-water interface and are controlled by (1) the sub-horizontality of …


Cryogenic Ridges: A New Speleothem Type, Bogdan P. Onac, Daniel M. Cleary, Oana A. Dumitru, Victor J. Polyak, Ioan Povara, Jonathan G. Wynn, Yemane Asmerom Jan 2023

Cryogenic Ridges: A New Speleothem Type, Bogdan P. Onac, Daniel M. Cleary, Oana A. Dumitru, Victor J. Polyak, Ioan Povara, Jonathan G. Wynn, Yemane Asmerom

International Journal of Speleology

Cryogenic cave carbonates have been described from several formerly or presently glaciated karst caves. In most of these occurrences, they precipitated as loose grains or aggregates with various morphologies and sizes. Here, we report on a new speleothem type (cryogenic ridges) identified in Sohodoalele Mici Cave (SW Romania) within a large chamber near the entrance shaft. This study was motivated by the presence of a network of calcite ridges over the stalactites’ surface and by the observation that during winter, these speleothems are covered by a thin ice layer. The higher δ18O (−3.5 to –1‰) and …


Low Impact Sampling Of Speleothems – Reconciling Scientific Study With Cave Conservation, Claire L.V. Macgregor, John C. Hellstrom, Jon D. Woodhead, Russell N. Drysdale, Rolan S. Eberhard Nov 2021

Low Impact Sampling Of Speleothems – Reconciling Scientific Study With Cave Conservation, Claire L.V. Macgregor, John C. Hellstrom, Jon D. Woodhead, Russell N. Drysdale, Rolan S. Eberhard

International Journal of Speleology

Speleothems are increasingly valued as important paleoclimate archives and yet the removal of samples from caves can come at a cost to natural heritage, impacting delicate environments with limited mechanisms for repair. Conservation of cave environments is a key responsibility for scientists and, with this in mind, we are working to develop and implement techniques that allow us to extract valuable scientific data, with minimal impact. In this study, we demonstrate the utility of low-impact reconnaissance dating surveys on caves in southern Tasmania and southwest Western Australia as a precursor to the removal of stalagmites for paleoclimate reconstruction. Small flakes …


Continuous Color Model As A Tool To Improve Speleothem Age Model Development, Celia Campa-Bousoño, Ángel García-Pérez, Ana Moreno, Miguel Iglesias, Hai Cheng, R Lawrence Edwards, Heather Stoll Oct 2021

Continuous Color Model As A Tool To Improve Speleothem Age Model Development, Celia Campa-Bousoño, Ángel García-Pérez, Ana Moreno, Miguel Iglesias, Hai Cheng, R Lawrence Edwards, Heather Stoll

International Journal of Speleology

Because they can archive a variety of geochemical proxies and be precisely and accurately dated with the U-Th decay series chronometer, stalagmites are widely used for paleoclimate reconstructions. However, limitations in the use of this chronometer arise because U-Th dating is analytically time consuming, expensive, and requires a relatively large sample size. These limitations restrict the number of absolute dates usually obtained, which can result in significant uncertainties in the age model and inhibit the ability to archive high resolution records of environmental variability, particularly in those stalagmites where there are variations in growth rate not constrained by U-Th dates. …


Geochemistry Of Phosphatic Nodules As A Tool For Understanding Depositional And Taphonomical Settings In A Palaeolithic Cave Site (San Teodoro, Sicily), Gerlando Vita, Vittorio Garilli, Mirko Andrea Vizzini, Renato Giarrusso, Angelo Mulone, Massimiliana Pinto Vraca, Valeria La Parola, Pierluigi Rosina, Laura Bonfiglio, Luca Sineo Sep 2021

Geochemistry Of Phosphatic Nodules As A Tool For Understanding Depositional And Taphonomical Settings In A Palaeolithic Cave Site (San Teodoro, Sicily), Gerlando Vita, Vittorio Garilli, Mirko Andrea Vizzini, Renato Giarrusso, Angelo Mulone, Massimiliana Pinto Vraca, Valeria La Parola, Pierluigi Rosina, Laura Bonfiglio, Luca Sineo

International Journal of Speleology

Interpreting depositional settings of cave sites is generally problematic, especially in absence of paleontological/archaeological evidence. This is the case of some deposits at San Teodoro Cave (Sicily), a key site for the Mediterranean Palaeolithic. In a stratigraphic level interrupted by a carbonatic concretion, phosphatic nodules are present only in the part enclosed between the concretion and the cave wall. The discovery of these nodules combined with the punctual lack of fossils had initially suggested an erosion phenomenon and subsequent formation of nodules at a vadose level. Here we show the usefulness of an integrated, geochemical-paleoecological approach in defining stratigraphy and …


The Impact Of Burning On The Structure And Mineral Composition Of Bat Guano, Joyce Lundberg, Donald A. Mcfarlane May 2021

The Impact Of Burning On The Structure And Mineral Composition Of Bat Guano, Joyce Lundberg, Donald A. Mcfarlane

International Journal of Speleology

Here we addressed the question of whether burning of guano produces a characteristic suite of morphological changes and/or unique mineralogical products. The changes observed in our experimental burning of guano (both fresh and decayed) included colour change (blackening), grain size and morphological change (grain size generally reduced, morphology rendered generally less distinct), alteration of minerals by dehydration (e.g., gypsum to anhydrite, brushite to whitlockite), and production of new minerals or compounds (e.g., augelite, bayerite, giniite, graphite, oldhamite, strontium apatite, tridymite). The key morphological feature we found that may be diagnostic of burning was severe damage to crystals from rapid dehydration …


On The Genesis Of Aluminum-Rich Speleothems In A Granite Cave Of Nw Spain, Jorge Sanjurjo-Sanchez, Carlos Arce Chamorro, Juan Ramón Vidal Romaní, Marcos Vaqueiro-Rodríguez, Victor Barrientos, Joeri Kaal Feb 2021

On The Genesis Of Aluminum-Rich Speleothems In A Granite Cave Of Nw Spain, Jorge Sanjurjo-Sanchez, Carlos Arce Chamorro, Juan Ramón Vidal Romaní, Marcos Vaqueiro-Rodríguez, Victor Barrientos, Joeri Kaal

International Journal of Speleology

Granite massifs often contain caves, with dimensions ranging from a few meters up to 1,000 m, also referred to as pseudokarst. The speleothems in such caves are mostly composed of either Si-rich (commonly opal-A) or Al-rich authigenic mineraloids. Whereas the formation and geochemical composition of opal-A biospeleothems have been studied and are fairly well understood, knowledge on the Al-rich analogues is scarce. This work reports for the first time a study on the composition, accretion process, age and growth rate of an Al-rich speleothem type flowstone from the A Trapa Cave System (Galicia, NW Spain), developed in a granite cave. …


Active Growth Of Non-Hydrothermal Subaqueous And Subaerial Barite (Baso4) Speleothems In Lechuguilla Cave (New Mexico, Usa), Max Wisshak, Hazel A. Barton, Katey E. Bender, Harvey R. Duchene Jan 2020

Active Growth Of Non-Hydrothermal Subaqueous And Subaerial Barite (Baso4) Speleothems In Lechuguilla Cave (New Mexico, Usa), Max Wisshak, Hazel A. Barton, Katey E. Bender, Harvey R. Duchene

International Journal of Speleology

Barite (BaSO4) speleothems have been reported from caves around the globe and interpreted to have chiefly formed in phreatic, hypogene, hydrothermal settings. Here we report two contrasting types of barite speleothems (bluish tabular crystals in a shallow pool and actively dripping greenish stalactites), which today form at lower temperatures in the non-hydrothermal and vadose environment of Lechuguilla Cave, New Mexico, USA. Scanning electron microscopy analysis, along with energy- and wavelength-dispersive X-ray spectroscopy (EDS, WDS), as well as X-ray diffraction (XRD), characterize the habit and chemical composition as barite. Fractionation of the minor element calcium is related to growth …


Genesis Of Iron And Manganese Sediments In Zoloushka Cave (Ukraine/Moldova) As Revealed By Δ13C Organic Carbon, Piotr Kotula, Viacheslav Andreychouk, Jacek Pawlyta, Leszek Marynowski, Izabela Jendrzejewska Sep 2019

Genesis Of Iron And Manganese Sediments In Zoloushka Cave (Ukraine/Moldova) As Revealed By Δ13C Organic Carbon, Piotr Kotula, Viacheslav Andreychouk, Jacek Pawlyta, Leszek Marynowski, Izabela Jendrzejewska

International Journal of Speleology

Zoloushka Cave is one of the largest maze gypsum caves in the world. Mining of the gypsum bedrock and lowering of the water level due to the pumping of groundwater led to exposure of the cave passages to vadose conditions and changed the hydrochemistry of the karst water. As a result, large quantities of Fe and Mn hydroxides were deposited in the passages. It was found that at least two groups of various organisms were involved in depositing ferrous and manganese sediments. In order to establish the mechanism of deposition, we conducted chemical analyses of the sediments and isotopic analyses …


Morphological And Mineralogical Evidence For Ancient Bat Presence In Cova Des Pas De Vallgornera (Llucmajor, Mallorca, Western Mediterranean), Antoni Merino, Joan J. Fornós, Antoni Mulet, Joaquín Ginés May 2019

Morphological And Mineralogical Evidence For Ancient Bat Presence In Cova Des Pas De Vallgornera (Llucmajor, Mallorca, Western Mediterranean), Antoni Merino, Joan J. Fornós, Antoni Mulet, Joaquín Ginés

International Journal of Speleology

Cova des Pas de Vallgornera is a unique karst cave located at the Llucmajor coastal platform that stands out not only because of its length, more than 78 km, but also for its particular morphological suite, richness and variety of speleothems and mineral infillings. Although the mineralogy of speleothems and minerals related to hypogene morphologies has been studied and described, the existence of minerals derived from guano deposits was still poorly investigated. The cave hosted bat colonies until the collapse of its natural entrances, circa 2.4 My ago, since then until its discovery in 1968, the cave remained sealed. These …


Cave Dripwater Isotopic Signals Related To The Altitudinal Gradient Of Mount-Lebanon: Implication For Speleothem Studies, Carole Nehme, Sophie Verheyden, Fadi H. Nader, Jocelyne Adjizian-Gerard, Dominique Genty, Kevin De Bont, Benedicte Minster, Ghada Salem, David Verstraten, Philippe Clayes Mar 2019

Cave Dripwater Isotopic Signals Related To The Altitudinal Gradient Of Mount-Lebanon: Implication For Speleothem Studies, Carole Nehme, Sophie Verheyden, Fadi H. Nader, Jocelyne Adjizian-Gerard, Dominique Genty, Kevin De Bont, Benedicte Minster, Ghada Salem, David Verstraten, Philippe Clayes

International Journal of Speleology

An important step in paleoclimate reconstructions based on vadose cave carbonate deposits or speleothems is to evaluate the sensitivity of the cave environment and speleothems to regional climate. Accordingly, we studied four caves, located at different altitudes along the western flank of Mount-Lebanon (Eastern Mediterranean). The objectives of this study are to identify the present-day variability in temperature, pCO2, and water isotopic composition and to assess the possible influence of the altitudinal gradient on cave drip waters and cave streams. We present here an overview of the spatial variability of rainwater based on local and regional data, and …


Isolution 1.0: An Isotope Evolution Model Describing The Stable Oxygen (Δ18O) And Carbon (Δ13C) Isotope Values Of Speleothems, Michael Deininger, Denis Scholz Jan 2019

Isolution 1.0: An Isotope Evolution Model Describing The Stable Oxygen (Δ18O) And Carbon (Δ13C) Isotope Values Of Speleothems, Michael Deininger, Denis Scholz

International Journal of Speleology

Stable oxygen and carbon isotope ratios (δ13C and δ18O) are the most applied climate and environmental proxies in speleothems allowing to infer past changes in cave drip water δ13C and δ18O related to climate and environmental variations from above the cave. However, disequilibrium isotope fractionation processes can modify δ13C and δ18O values in speleothems, which is in most cases difficult to estimate due to inter-dependencies on various cave specific parameter. To better understand the effect of these disequilibrium isotope fractionation processes proxy system models were developed in recent …


Evolution Of Noble Gas And Water Isotopes Along The Regional Groundwater Flow Path Of The Konya Closed Basin, Turkey, N. Nur Ozyurt, C. Serdar Bayari Nov 2018

Evolution Of Noble Gas And Water Isotopes Along The Regional Groundwater Flow Path Of The Konya Closed Basin, Turkey, N. Nur Ozyurt, C. Serdar Bayari

International Journal of Speleology

Noble gas and water isotope compositions of regional groundwater were investigated along two transects in the Konya Closed Basin (KCB) of central Turkey. According to the 3He/4He versus Ne/He plot of samples, crust (up to 86%) and mantle (up to 26%) appear to be the primary and secondary sources of dissolved He in groundwater, respectively. After the beginning of both transects where the flow domain is confined, both 3He and 4He accumulate steadily in groundwater. Thereafter, the intermediate recharge from the surface in the unconfined part of regional flow system disrupts the steady accumulation trend …


Interpreting The Origin And Evolution Of ‘Karst’ Features From A Siliceous Hydrothermal Terrane: A Case Study From The Upper Geyser Basin In Yellowstone National Park, Usa, Kevin W. Blackwood, Lainee A. Sanders, Stacy I. Gantt-Blackwood Nov 2018

Interpreting The Origin And Evolution Of ‘Karst’ Features From A Siliceous Hydrothermal Terrane: A Case Study From The Upper Geyser Basin In Yellowstone National Park, Usa, Kevin W. Blackwood, Lainee A. Sanders, Stacy I. Gantt-Blackwood

International Journal of Speleology

The Upper Geyser Basin in Yellowstone National Park occurs over a siliceous hydrothermal terrane containing numerous hot springs and geysers. The pool and vent-conduit geometries of these hydrothermal features share a resemblance to conventional karst features known from other rock types, suggesting karst processes could be responsible for their origin and/or evolution. Hypogene speleogenesis is a cave-forming process in which the formation of caves is decoupled from and occurs independently of surface recharge. The geologic setting for hypogene speleogenesis typically occurs at the distal end of regional groundwater systems wherein the hydrogeology is manifested by ascending fluids and/or by geochemical …


On Biospeleothems From A Venezuelan Tepui Cave: U-Th Dating, Growth Rates, And Morphology, Joyce Lundberg, Charles Brewer-Carías, Donald A. Mcfarlane Oct 2018

On Biospeleothems From A Venezuelan Tepui Cave: U-Th Dating, Growth Rates, And Morphology, Joyce Lundberg, Charles Brewer-Carías, Donald A. Mcfarlane

International Journal of Speleology

Seven silica biospeleothems from Cueva Charles Brewer, Chimantá Plateau, Venezuela have been successfully U-Th dated despite very low U and high detrital Th concentrations. Growth rates are low, between ~100 to ~800 µm/ka, and are greater closer to water level. Dates in unaltered material are in good stratigraphic order, but secondary silicification may compromise the U-Th system, yielding unreliable sequences of ages. Detritally-enriched layers correlate with global climate cycles of the Late Quaternary, in particular the cooler, drier phases of MIS 5d, 5a, and 4. SEM studies indicate that the peloidal material is made up of silica nano-particles assembled to …


Extremely High Diversity Of Sulfate Minerals In Caves Of The Irazú Volcano (Costa Rica) Related To Crater Lake And Fumarolic Activity, Andrés Ulloa, Fernando Gázquez, Aurelio Sanz-Arranz, Jesús Medina, Fernando Rull, José María Calaforra, Guillermo E. Alvarado, María Martínez, Geoffroy Avard, J. Maarten De Moor, Jo De Waele Jun 2018

Extremely High Diversity Of Sulfate Minerals In Caves Of The Irazú Volcano (Costa Rica) Related To Crater Lake And Fumarolic Activity, Andrés Ulloa, Fernando Gázquez, Aurelio Sanz-Arranz, Jesús Medina, Fernando Rull, José María Calaforra, Guillermo E. Alvarado, María Martínez, Geoffroy Avard, J. Maarten De Moor, Jo De Waele

International Journal of Speleology

The caves of the Irazú volcano (Costa Rica), became accessible after the partial collapse of the NW sector of the Irazú volcano in 1994, offering the opportunity to investigate active minerogenetic processes in volcanic cave environments. We performed a detailed mineralogical and geochemical study of speleothems in the caves Cueva los Minerales and Cueva Los Mucolitos, both located in the northwest foothills of the main crater. Mineralogical analyses included X-ray diffraction (XRD) and Raman spectroscopy, while geochemical characterization used Energy Dispersive X-ray spectroscopy (EDX) coupled to Scanning Electron Microscopy (SEM). In addition, measurements of environmental parameters in the caves, …


Drip Water Measurements From Carlsbad Cavern: Implications Towards Paleoclimate Records Yielded From Evaporative-Zone Stalagmites, Victor J. Polyak, Jessica B.T. Rasmussen, Yemane Asmerom Jun 2018

Drip Water Measurements From Carlsbad Cavern: Implications Towards Paleoclimate Records Yielded From Evaporative-Zone Stalagmites, Victor J. Polyak, Jessica B.T. Rasmussen, Yemane Asmerom

International Journal of Speleology

Stalagmites can host numerous potential climate proxies (stable and radiogenic isotopes, trace elements, annual and non-annual banding, grayscale, growth hiatuses, mineral assemblage). Reproducibility and/or integration of proxy results between one or more stalagmites will become increasingly important, and ideally, climate records generated by multiple stalagmites from the same cave or cave room are expected to be near-identical. The reality is that stalagmites from the same cave room can yield differing results to some degree, especially in cave environment zones that are evaporative. Our drip water study in an evaporative shallow-depth cave environment in Carlsbad Cavern shows that adjacent drip sites …


Unusual Internal Structure Of Cm-Sized Coldwater Calcite: Weichselian Spars In Former Pools Of The Zinnbergschacht Cave (Franconian Alb/Se Germany), Detlev K. Richter, Rolf D. Neuser, Martin Harder, Hardy Schabdach, Denis Scholz Apr 2018

Unusual Internal Structure Of Cm-Sized Coldwater Calcite: Weichselian Spars In Former Pools Of The Zinnbergschacht Cave (Franconian Alb/Se Germany), Detlev K. Richter, Rolf D. Neuser, Martin Harder, Hardy Schabdach, Denis Scholz

International Journal of Speleology

The investigation of the internal structure of calcite crystals is a new focus in speleothem science, especially in the range of crystallization temperatures close to 0°C. Recently found calcite spars from Zinnbergschacht Cave of the Franconian Alb (SE Germany) are ideal for multi-method investigation. The elongated calcites (up to 6 cm in length) with three to six lateral faces and basal triangular faces at the ends are observed in collapse-zones in the cave. 230Th/U-ages of 38.9 ka suggest formation during the periglacial Weichselian, between the Scandinavian and Alpine Glaciations. The δ18O and δ13C values of …


Phosphate Speleothems In Caves Developed In Iron Ores And Laterites Of The Carajás Mineral Province (Brazil) And A New Occurrence Of Spheniscidite, Alan R.L. Albuquerque, Rômulo S. Angélica, Daniele F. Gonçalves, Simone P.A. Paz Dec 2017

Phosphate Speleothems In Caves Developed In Iron Ores And Laterites Of The Carajás Mineral Province (Brazil) And A New Occurrence Of Spheniscidite, Alan R.L. Albuquerque, Rômulo S. Angélica, Daniele F. Gonçalves, Simone P.A. Paz

International Journal of Speleology

The Carajás Mineral Province has one of the largest concentrations of caves in Brazil, and its iron ore is among the country’s main exports. As a result of iron ore intense extraction, new environmental policies have been implemented. In an attempt to balance economic activity and environmental conservation, an inventory and a relevance-based classification of caves were implemented in 2008 as criteria for environmental licensing of mining ventures. This implementation motivated the present study of phosphate speleothems in Carajás’ caves developed in ferriferous rocks. The objectives of this study are to describe the phosphate minerals and their formation processes based …


Cave Monitoring In The Béke And Baradla Caves (Northeastern Hungary): Implications For The Conditions For The Formation Cave Carbonates, György Czuppon, Attila Demény, Szabolcs Leél-Őssy, Mihály Óvari, Mihály Molnár, József Stieber, Klaudia Kiss, Krisztina Kármán, Gergely Surányi, László Haszpra Nov 2017

Cave Monitoring In The Béke And Baradla Caves (Northeastern Hungary): Implications For The Conditions For The Formation Cave Carbonates, György Czuppon, Attila Demény, Szabolcs Leél-Őssy, Mihály Óvari, Mihály Molnár, József Stieber, Klaudia Kiss, Krisztina Kármán, Gergely Surányi, László Haszpra

International Journal of Speleology

In order to use speleothems in the reconstruction of past climate and environmental changes it is necessary to understand the environmental and hydrological processes that determine the physico-chemical conditions of carbonate precipitation and hence speleothem formation. Therefore, in this study an extended monitoring program was conducted in the Béke and Baradla caves located in the Aggtelek region (Northeastern Hungary). The studied caves are rich in speleothem and flowstone occurrences with great potential for paleoclimatology studies. The monitoring activity included measurements of atmospheric and cave temperatures, CO2 concentration in cave air, as well as chemical and isotopic compositions of water …


Geothermal Flux And Phreatic Speleogenesis In Gypsum, Halite, And Quartzite Rocks, Giovanni Badino Nov 2017

Geothermal Flux And Phreatic Speleogenesis In Gypsum, Halite, And Quartzite Rocks, Giovanni Badino

International Journal of Speleology

The first layers of rock underground are in thermal contact with the external atmosphere mainly through infiltrating meteoric water. This relatively cool zone absorbs rising geothermal energy, which heats the water. If the aquifer consists of gypsum, halite or quartzite, the water at those depths is usually salt-saturated, so the increase in temperature renders the water aggressive again. This in turn leads to rock dissolution and formation of phreatic conduits. This way, the geothermal flow creates caves that do not necessarily reach the surface. This paper analyzes the speed of the excavation, which, in different types of rocks, depends only …


Timing Of Speleogenesis Of Las Karmidas Cave (Mexico): First Description Of Pseudokarst Developed In Ignimbrite, María Del Pilar Aliaga-Campuzano, Rafael López-Martínez, Pablo Dávila-Harris, Ramón Espinasa-Pereña, Adriana Espino Del Castillo, J.P. Bernal Apr 2017

Timing Of Speleogenesis Of Las Karmidas Cave (Mexico): First Description Of Pseudokarst Developed In Ignimbrite, María Del Pilar Aliaga-Campuzano, Rafael López-Martínez, Pablo Dávila-Harris, Ramón Espinasa-Pereña, Adriana Espino Del Castillo, J.P. Bernal

International Journal of Speleology

Las Karmidas Cave (Puebla State, Mexico) is an unusual type of pseudokarstic cavity generated by piping and erosive processes within the contact of a diamicton and an overlying Quaternary ignimbrite. Morphological evidence suggests that the cave was developed in two stages: a phreatic stage and a vadose stage. The latter was characterized by the formation of carbonate speleothems. The absolute upper-age limit for the cave (168 +7.1/-7.5 ka) was established by U-Th dating of zircons grains extracted from the overlying ignimbrite, whilst a minimum age for the transition from a phreatic to vadose regime (95.6 ± 2.1 ka) was constrained …


Secondary Minerals From Salt Caves In The Atacama Desert (Chile): A Hyperarid And Hypersaline Environment With Potential Analogies To The Martian Subsurface, Jo De Waele, Cristina Carbone, Laura Sanna, Marco Vattano, Ermanno Galli, Francesco Sauro, Paolo Forti Jan 2017

Secondary Minerals From Salt Caves In The Atacama Desert (Chile): A Hyperarid And Hypersaline Environment With Potential Analogies To The Martian Subsurface, Jo De Waele, Cristina Carbone, Laura Sanna, Marco Vattano, Ermanno Galli, Francesco Sauro, Paolo Forti

International Journal of Speleology

Over the past 15 years several expeditions by French, American and especially Italian cavers have unveiled over 50 caves in the Cordillera de la Sal (Atacama Desert, Northern Chile). Many of these caves contain a variety of speleothems and minerals, some of which have rarely been observed within karst systems. Most of the secondary deposits in these caves are composed of halite, but also other halide, carbonate, sulphate, nitrate, phosphate, and silicate minerals have been found. Among the sixteen cave mineral species recognized, atacamite, darapskite, blödite, leonite, anhydrite, and especially antarcticite are worth mentioning. In one of the samples an …


Petrographical And Geochemical Changes In Bosnian Stalagmites And Their Palaeo-Environmental Significance, Veronica Chiarini, Isabelle Couchoud, Russell Drysdale, Petra Bajo, Simone Milanolo, Silvia Frisia, Alan Greig, John Hellstrom, Jo De Waele Jan 2017

Petrographical And Geochemical Changes In Bosnian Stalagmites And Their Palaeo-Environmental Significance, Veronica Chiarini, Isabelle Couchoud, Russell Drysdale, Petra Bajo, Simone Milanolo, Silvia Frisia, Alan Greig, John Hellstrom, Jo De Waele

International Journal of Speleology

Detailed petrographic observations have been coupled with trace element and δ13C - δ18O analyses in order to investigate their dynamics in two Holocene Bosnian speleothems. The potential of this multiproxy approach in providing a means to extract palaeo-environmental information from stalagmites whose stable isotope signals are noisy and without obvious trends has been tested. The studied stalagmites are mostly characterized by columnar microcrystalline fabric. At the sub-millimetre scale of lamination, different microcrystalline columnar sub-types (open and closed) have been detected and classified on the basis of the observed porosity and the crystallite size. The presence of …


High-Resolution Signatures Of Oxygenation And Microbiological Activity In Speleothem Fluid Inclusions, Nigel Blamey, Penelope J. Boston, Laura Rosales-Lagarde Aug 2016

High-Resolution Signatures Of Oxygenation And Microbiological Activity In Speleothem Fluid Inclusions, Nigel Blamey, Penelope J. Boston, Laura Rosales-Lagarde

International Journal of Speleology

Speleothems frequently host “fossil” fluids that were trapped in small inclusions during growth. Such fluids may provide valuable clues to past microbial, geochemical, and climatic processes during their formation. However, one difficulty is to understand which gases represent background atmosphere and fluids within a given cave system at a particular time, and which may be the product of post-trapping residual microbial activity or abiotic chemical reactions? Do we have any hope of sorting out these differences? The success depends on a quantitative understanding of the gas composition trapped in the inclusions and an understanding of the interactions of cave mineralogy, …


U-Pb Dating Of Speleogenetic Dolomite: A New Sulfuric Acid Speleogenesis Chronometer, Victor J. Polyak, Paula P. Provencio, Yemane Asmerom Feb 2016

U-Pb Dating Of Speleogenetic Dolomite: A New Sulfuric Acid Speleogenesis Chronometer, Victor J. Polyak, Paula P. Provencio, Yemane Asmerom

International Journal of Speleology

The 1100-meter Big Room elevation level of Carlsbad Cavern, New Mexico USA, formed 4 Ma by hypogenic sulfuric acid speleogenesis (SAS). The age of the Big Room level of 4.0 ± 0.2 Ma was previously determined by dating alunite, a byproduct of speleogenesis, using the 40Ar/39Ar method. Duplication of these results is possible by radiometric dating of other byproducts interpreted to be speleogenetic (a byproduct of speleogenesis) such as calcite and dolomite in certain settings. XRD and TEM analyses of sample 94044, a piece of crust collected within the Big Room level of SAS just below Left …


Quantitative Hermeneutics: Counting Forestructures On A Path From W.M. Davis To The Concept Of Multiple-Permeability Karst Aquifers, H. L. Vacher, Lee J. Florea Jun 2015

Quantitative Hermeneutics: Counting Forestructures On A Path From W.M. Davis To The Concept Of Multiple-Permeability Karst Aquifers, H. L. Vacher, Lee J. Florea

International Journal of Speleology

Hermeneutics is the theory of interpretation. One of its major components is recognizing prejudgments, or forestructures, that we bring to our objects of study. In this paper, we construct a historical narrative of the evolution of thinking about the role of caves in relation to groundwater flow in limestone, and we tabulate forestructures as they appear in the story. This account consists of three overlapping time periods: the before and after of an incident that repelled hydrogeologists and students of karst from each other in the middle of the 20th century; a period, up to around the turn of …


The Relationship Between Carbon Dioxide Concentration And Visitor Numbers In The Homothermic Zone Of The Balcarka Cave (Moravian Karst) During A Period Of Limited Ventilation, Marek Lang, Jiří Faimon, Camille Ek Mar 2015

The Relationship Between Carbon Dioxide Concentration And Visitor Numbers In The Homothermic Zone Of The Balcarka Cave (Moravian Karst) During A Period Of Limited Ventilation, Marek Lang, Jiří Faimon, Camille Ek

International Journal of Speleology

The evolution of CO2 levels with and without human presence was studied in a selected site (Gallery Chamber) of the homothermic zone of the Balcarka Cave (Moravian Karst, Czech Republic) during the fall, a period of limited ventilation. There were recognized various factors controlling the cave CO2 levels under different conditions in the exterior and interior. When visitors were absent, CO2 levels were controlled by the advective CO2 fluxes linked to cave airflows and reaching up to ~1.5x10-3 mol s-1. These fluxes exceed by orders of magnitude the exchanged diffusive fluxes (up to …


Groundwater Lowering And Stream Incision Rates In The Central Appalachian Mountains Of West Virginia, Usa, Gregory S. Springer, Holly A. Poston, Ben Hardt, Harold D. Rowe Dec 2014

Groundwater Lowering And Stream Incision Rates In The Central Appalachian Mountains Of West Virginia, Usa, Gregory S. Springer, Holly A. Poston, Ben Hardt, Harold D. Rowe

International Journal of Speleology

Surface channel incision rates are of broad geomorphological interest because they set the boundary conditions for landscape change by affecting changes in local relief and hillslope angles. We report groundwater table lowering rates associated with subsurface Buckeye Creek and the surface channel of Spring Creek in southeastern West Virginia, USA. The mountainous watersheds have drainage areas of 14 km2 and 171 km2, respectively. The lowering rates are derived from U/Th-dating of stalagmites and the paleomagnetostratigraphy of clastic sediments in Buckeye Creek Cave. The oldest stalagmites have a minimum age of 0.54 Ma and we use a minimum …