Earth Sciences Commons^™

Halogen And Non-Traditional Isotope Geochemistry Of Planetary And Terrestrial Materials, Anthony Gargano, Zachary Sharp, Justin Simon, Charles Shearer, Adrian Brearley, James Day

Earth and Planetary Sciences ETDs

This dissertation presents the advances in non-traditional isotope geochemistry of planetary and terrestrial materials encompassing chlorine, sulfur, and zinc isotopes, as well as halogen geochemistry. A wide breadth of materials was studied throughout the completion of this work including iron meteorites, achondrites, chondrites, Apollo lunar samples, as well ancient marine chert, and carbonate sediments. Much of the focus involved the development of a method capable of simultaneously measuring the halogen contents and chlorine isotope compositions of geological materials. Here, I present these data sets to broadly characterize the process of devolatilization of planetary materials, and specifically the problem of ‘halogen-poisoning’ …

Melt Inclusions And Their Application - New Perspective On The Subsurface Architecture Of Cerro Negro Volcano, Nicaragua, John M. Hamilton

Earth and Planetary Sciences ETDs

Volatiles are the drivers of volcanic eruptions and monitoring and measurement in quiescent times are the key in determining when unrest within a volcanic system is beginning leading to possible cataclysms. Previous studies have focused on direct measurements from volcanic plumes or fumaroles, however, this study proposes the use of melt inclusions from tephra to determine volatile contents from the 1992 eruption of Cerro Negro Volcano, Nicaragua. The analysis of melt inclusions adds a new technique to the volatile analytical toolbox and can help to determine volatile contents from past eruptions and their subsequent evolution within a volcanic system.

Though …

Microtextural Studies Of Feldspar In Ordinary Chondrites, Jonathan A. Lewis

Earth and Planetary Sciences ETDs

Ordinary chondrites contain an important record of events that took place during the earliest period of solar system evolution. These include primary processes, such as chondrule formation, and secondary processes, those that affected asteroids after accretion and modified primary components. Secondary processes include aqueous alteration, thermal metamorphism, and shock effects from impact events. Secondary minerals can provide insight into the chemical and physical conditions that affected their parent asteroids. Feldspar is known to be a secondary mineral that crystallized during thermal metamorphism. The goal of this work is to use the formation and evolution of feldspar to elucidate the conditions …

Geochemistry Of Volatiles Released By Incipient Continental Rifting And Subduction Processes, Hyunwoo Lee

Earth and Planetary Sciences ETDs

Volatiles (N2, CO2, and He) are released by volcanism and hydrothermal activity during continental rifting and subduction processes. Analyses of volatile components have been conducted to obtain gas contents (CO2, SO2, H2S, N2, Ar, He, and so on), stable isotope compositions (δ13C, δ15N, and so on), and noble gas isotopes (3He/4He, 40Ar/36Ar, and so on). This dissertation includes four chapters to report new nitrogen isotope fractionation factors of bubbling gases during gas-water transfer at various water temperatures (Chapter 1), first measurements of massive amounts of CO2 released by incipient continental rifting in the Magadi and Natron Basin, East African Rift …