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Full-Text Articles in Earth Sciences

Tb134: A Laboratory Study To Assess Methods For Predicting Ph Change Of Ash Amended Forest Soils, Yvonne Unger, Ivan Fernandez Mar 2015

Tb134: A Laboratory Study To Assess Methods For Predicting Ph Change Of Ash Amended Forest Soils, Yvonne Unger, Ivan Fernandez

Ivan J. Fernandez

The objective of this study was to compare several commonly used lime requirement tests and soil capacity factors for their ability to predict pH change following wood-ash amendment. The ability to predict pH change is important because it is one of the criteria used to prescribe rates of ash amendment to forest soils.


Improved Identification Of Sulfidic Soil Materials By A Modified Incubation Method, Leigh Sullivan, Nicholas Ward, Richard Bush, Edward Burton Oct 2013

Improved Identification Of Sulfidic Soil Materials By A Modified Incubation Method, Leigh Sullivan, Nicholas Ward, Richard Bush, Edward Burton

Dr Nicholas J Ward

This study examines the acidification behaviour and rate of sulfidic-sulfur oxidation in the incubation method that is currently used in soil taxonomies to identify sulfidic materials, for some clayey textured soil materials. ‘Sulfidic’ in these taxonomies identifies that a soil material is capable of becoming extremely acidic (i.e. pH < 4) as a result of oxidation of sulfide minerals contained in that soil material. As well as examining incubation slabs of acid sulfate soil materials with the standard 10 mm thickness, the utility of thinner (i.e. 2 mm thick) incubation slabs of these soil materials for identification of sulfidic soil materials …


Determination Of The Cec In Srs Soils And The Capability Of Epa Model 9081 For Cec Of Acidic Soils, Alexandra Simpson May 2013

Determination Of The Cec In Srs Soils And The Capability Of Epa Model 9081 For Cec Of Acidic Soils, Alexandra Simpson

Alexandra M Simpson

No abstract provided.


Determination Of The Cec In Srs Soils And The Capability Of Epa Model 9081 For Cec Of Acidic Soils, Alexandra Simpson May 2013

Determination Of The Cec In Srs Soils And The Capability Of Epa Model 9081 For Cec Of Acidic Soils, Alexandra Simpson

Alexandra M Simpson

No abstract provided.


Arsenic Mobilization And Iron Transformations During Sulfidization Of As(V)-Bearing Jarosite, Scott Johnston, Edward Burton, Annabelle Keene, Britta Planer-Friedrich, Andreas Voegelin, Mark Blackford, Greg Lumpkin Apr 2013

Arsenic Mobilization And Iron Transformations During Sulfidization Of As(V)-Bearing Jarosite, Scott Johnston, Edward Burton, Annabelle Keene, Britta Planer-Friedrich, Andreas Voegelin, Mark Blackford, Greg Lumpkin

Associate Professor Edward D Burton

Jarosite (KFe3(SO4) 2(OH)6) is an important host-phase for As in acid mine drainage (AMD) environments and coastal acid sulfate soils (CASS). In AMD and CASS wetlands, jarosite may encounter S(−II) produced by sulfate reducing bacteria. Here, we examine abiotic sulfidization of As(V)-bearing K-jarosite at pH 4.0, 5.0, 6.5 and 8.0. We quantify the mobilization and speciation of As and identify corresponding Fe mineral transformations. Sulfide-promoted dissolution of jarosite caused release of co-precipitated As and the majority of mobilized As was re-partitioned to a readily exchangeable surface complex (AsEx). In general, maximum As mobilization occurred in the highly sulfidized end-members of …


Remediation Of Coastal Acid Sulfate Soils By Tidal Inundation: Effectiveness And Geochemical Implications, Scott Johnston, Annabelle Keene, Richard Bush, Edward Burton, Leigh Sullivan Sep 2010

Remediation Of Coastal Acid Sulfate Soils By Tidal Inundation: Effectiveness And Geochemical Implications, Scott Johnston, Annabelle Keene, Richard Bush, Edward Burton, Leigh Sullivan

Associate Professor Edward D Burton

The effects of restoring marine tidal inundation to a severely degraded acid sulfate soil landscape were investigated. Five years of regular tidal inundation led to substantial improvements in a range of key parameters used to assess soil and water quality. The pH of estuarine creeks improved dramatically following reintroduction of tidal inundation. Time series water quality and climatic data indicate a substantial decrease in the magnitude of creek acidification per given quantity of antecedent rainfall. The soil pH also increased by 2–3 units and titratable actual acidity (TAA) decreased by ~40–50 μmol H+ g-1 within former sulfuric horizons. Tidal inundation …


Fe And S K-Edge Xas Determination Of Iron-Sulfur Species Present In A Range Of Acid Sulfate Soils: Effects Of Particle Size And Concentration On Quantitative Xanes Determinations, Kate Morgan, Edward Burton, Perran Cook, Mark Raven, Robert Fitzpatrick, Richard Bush, Leigh Sullivan, Rosalie Hocking Aug 2010

Fe And S K-Edge Xas Determination Of Iron-Sulfur Species Present In A Range Of Acid Sulfate Soils: Effects Of Particle Size And Concentration On Quantitative Xanes Determinations, Kate Morgan, Edward Burton, Perran Cook, Mark Raven, Robert Fitzpatrick, Richard Bush, Leigh Sullivan, Rosalie Hocking

Associate Professor Edward D Burton

Acid sulfate soils (ASS) are soils and soft sediments in which sulfuric acid may be produced from iron sulfides or have been produced leaving iron oxyhydroxysulfates in amounts that have a long lasting effect on soil characteristics. If soil material is exposed to rotting vegetation or other reducing material, the Fe-oxyhydroxysulfates can be bacterially reduced to sulfides including disulfides (pyrite and marcasite), and Monosulfidic Black Ooze (MBO) a poorly characterised material known to be a mixture of iron sulfides (especially mackinawite) and organic matter. The chemistry of these environments is strongly affected by Fe and S cycling processes and herein …


Implications Of Distributed Crustal Deformation For Exhumation In A Portion Of A Transpressional Plate Boundary, Western Transverse Ranges, Southern California, Andrew Meigs, Dong Yule, Ann Blythe, Doug Burbank Jan 2003

Implications Of Distributed Crustal Deformation For Exhumation In A Portion Of A Transpressional Plate Boundary, Western Transverse Ranges, Southern California, Andrew Meigs, Dong Yule, Ann Blythe, Doug Burbank

Ann Blythe

Spatial and temporal patterns of exhumation are inextricably linked to patterns of crustal deformation because crustal deformation drives rock uplift. A new interpretation of a segment of the Pacific-North America transpressional plate boundary in southern California is analyzed in the context of crustal shortening, rock uplift, and exhumation. Deformation is partitioned between two structural anticlinoria formed above thrust faults that root into a mid-crustal décollement. The southern anticlinorium began growing after 5 Ma and is characterized by almost no topographic expression, rock uplift of ∼3 km, and exhumation of <1.2 km. Deposition in the Los Angeles basin on the south generally kept pace with growth of this anticlinorium. In contrast, the northern anticlinorium is younger, has a significant topographic expression, rock uplift of 2.5–4.0 km, and exhumation of ∼1.5–2 km. On-going surface uplift above the northern anticlinorium is suggested by the mismatch between the magnitude of rock uplift relative to the exhumation. These data emphasize that the distribution of deformation between faults in the upper and middle crust, crustal root formation in the lower crust, and flexural subsidence are primary controls of patterns of exhumation, which together dictate net surface uplift in active orogenic belts.