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International Journal of Speleology

2015

Halloysite

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A New Microenvironment For The Formation Of Clay Minerals: The Example Of Authigenic Halloysite-7Å And Gibbsite In A Stalactite From Agios Georgios Cave, Kilkis, North Greece, Elena Ifandi, Basilios Tsikouras, Dimitrios Papoulis, Konstantin Hatzipanagiotou, Aspasia Antonelou Sep 2015

A New Microenvironment For The Formation Of Clay Minerals: The Example Of Authigenic Halloysite-7Å And Gibbsite In A Stalactite From Agios Georgios Cave, Kilkis, North Greece, Elena Ifandi, Basilios Tsikouras, Dimitrios Papoulis, Konstantin Hatzipanagiotou, Aspasia Antonelou

International Journal of Speleology

An unusual authigenic origin for halloysite and gibbsite is reported in a stalactite from Agios Georgios Cave, Kilkis. This speleothem includes mostly pure calcite whereas minor areas of Mg-rich calcite and scarce dolomite are present in four growth phases. Abundant pores are created due to imperfect coalescence of the calcite crystals. Several of them contain detrital muscovite, which was presumably transferred from the dripping water, during the formation of speleothem and has been variably altered to halloysite. Several pores in the stalactite contain different mineral assemblages that we interpret as in situ: halloysite-7Å, halloysite + silica, gibbsite + silica and …