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Mineral Physics

International Journal of Speleology

2011

Stable isotopes

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Revisiting Three Minerals From Cioclovina Cave (Romania), Bogdan P. Onac, Herta S. Effenberger, Nathan C. Collins, Joe B. Kearns, Radu C. Breban Jan 2011

Revisiting Three Minerals From Cioclovina Cave (Romania), Bogdan P. Onac, Herta S. Effenberger, Nathan C. Collins, Joe B. Kearns, Radu C. Breban

International Journal of Speleology

Cioclovina Cave in Romania’s Southern Carpathians is a world-renowned cave site for its paleontological, anthropological, and mineralogical (type locality of ardealite) findings. To date, over 25 mineral species have been documented, some unusual for a cave environment. This paper presents details on the occurrence of collinsite [Ca2(Mg,Fe2+)(PO4)2·2H2O], atacamite [Cu22+Cl(OH)3], and kröhnkite [Na2Cu2+(SO4)2·2H2O] based on single-crystal X-ray diffraction, electron microprobe, stable isotope analyses, and scanning electron microscope imaging. This is the first reported occurrence of kröhnkite …