Earth Sciences Commons^™

Influence Of Physical Variability Of Highly Weathered Sedimentary Rock On Nitrate In Area 3 Of The Enigma Field Research Site At Y-12, Erin Kelly

Masters Theses

Uranium processing and waste storage in unlined waste ponds leached contaminants into the groundwater at Y-12, Oak Ridge, Tennessee, from the 1950s to 1980s. Groundwater wells near the S-3 ponds have had the highest nitrate concentrations of groundwater anywhere in the world (>10,000 mg/L). For reference, the maximum contaminant level for nitrate in drinking water set by the U.S. Environmental Protection Agency is 10 mg/L. Since 2012, the ENIGMA (Ecosystems and Networks Integrated with Genes and Molecular Assemblies) group has been characterizing, monitoring, and conducting field experiments to understand the interactions between contaminants, microbes, and the subsurface. The goals …

The Importance Of Lithologic Variability And Stratigraphic Architecture In The Development Of Eogenetic Karst Systems, Nicholas J. Soto-Kerans

USF Tampa Graduate Theses and Dissertations

Integrative characterizations of karst systems on low-lying eogenetic carbonate platforms are rare and often limited to areas of direct observation where caves can be entered and explored. Because hydraulic properties of eogenetic limestones have been implicitly assumed to be homogeneous, classical models of carbonate island karst development stressed the importance of geochemical interfaces in controlling cave and vug development. These studies have explained the largest cavern systems as results of either 1) mixing dissolution at platform margins or 2) microbially-mediated dissolution processes at water tables.

New data from core descriptions and wireline logs obtained in 18 boreholes drilled in the …

Testing The Impact Of A Freshwater Wetland Restoration On Water Table Elevation And Soil Moisture Using A Parametric Groundwater Modeling Approach, Erika T. Ito

Masters Theses

Wetlands are now recognized for the many social, environmental, ecological, and economic benefits they provide. They improve water quality, support biodiversity, abate floods and storms, and provide local recreational areas. Historically, many wetlands have been drained or altered for residential, commercial, or agricultural use. Effective wetland restoration projects reestablish ecosystem services and mitigate legacy effects of land use change to create self-sustaining systems. However, a persisting lack of scientifically-vetted methodological and evaluation guidelines in the field of restoration ecology has caused many restoration efforts to fail to restore natural wetland hydrologic conditions. By definition, wetlands must be saturated, permanently or …

Investigating Epikarst Recharge Dynamics Under Agricultural Landuse Using Hydrometeorological And Isotopic Tracers, Austin Shane Deering

Masters Theses & Specialist Projects

Epikarst systems have complex recharge – discharge processes in telogenetic karst systems, including highly variable storage, flowpaths, and mixing dynamics. This research aimed to characterize the epikarst zone using hydrogen and oxygen isotopic tracers of these processes within south-central Kentucky’s Crumps Cave system located in the Pennyroyal Sinkhole Plain. Data and statistical analyses were applied to highresolution rainfall (RF), lysimeter (10 cm, 20 cm, 30 cm depths), and an epikarst Waterfall 1 (WF1) isotope data collected on a weekly basis between 2011-2018. These data were coupled with WF1 discharge measurements and weather station data collected at Crumps Cave Preserve during …

Numerical Modeling Of Controlling Factors For Formation Of Unconformity-Related Uranium Deposits In Sedimentary Basins, Jiayue Shen

Electronic Theses and Dissertations

Unconformity-related uranium (URU) deposits are the most profitable uranium deposits in the world. Among those deposits, the Athabasca Basin hosts the world’s largest high-grade uranium deposits. A series of numerical experiments regarding the effect of uranium source location, fault location, and fault dip angle on the formation of URU deposits have been conducted by using software TOUHREACT.

Simulation results suggest that although both sandstone-sourced and basement-sourced models can generate economical deposits, basement-sourced models are more likely to form larger deposits since uranium-carrying fluid only needs to move a shorter distance to reach the structural trap for further ore forming reaction. …

Coastal Groundwater Catchments Of The Gulf Of Alaska, Aeon Russo

Masters Theses

High latitude mountain environments are experiencing disproportionately adverse effects in a currently changing climate. The Gulf of Alaska (GoA) region is an exemplar of this. Dramatic shifts are occurring in the region’s freshwater reservoirs as glaciers retreat more with each passing year. Research in the region places much focus on observing and predicting climate driven shifts in glacier mass balance, surface discharge, and associated nutrient fluxes to the ocean. On the other hand, coastal groundwater discharge (CGD) is given very little attention. Global and near-global estimates of CGD indicate variable results spanning an order of magnitude. Focusing on regionally specific …

Geologic Characterization Of The Nonconformity Interface Using Outcrop And Drillcore Analogs: Implications For Injection-Induced Seismicity, Kayla Smith

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Starting around 2009, a greater number of earthquakes than anticipated have occurred in the midcontinent region of the United States. These earthquakes have been linked to increased rates and volumes of wastewater injection at several km’s depth into the Earth’s crust near a contact between crystalline metamorphic or igneous rock and overlying sedimentary rock, known as a nonconformity. While much is known about why these new earthquakes occur, comparatively little is known about the physical and chemical rock properties because the nonconformity contact is primarily buried under km’s of sedimentary rock in the midcontinent region. These rock properties are important …