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Environmental Sciences

Theses/Dissertations

2015

Geochemistry

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Full-Text Articles in Earth Sciences

The Champlain Sea/Lake Champlain Transition Recorded In The Northeast Arm Of Lake Champlain, Usa-Canada, Ashliegh Theresa Belrose Jan 2015

The Champlain Sea/Lake Champlain Transition Recorded In The Northeast Arm Of Lake Champlain, Usa-Canada, Ashliegh Theresa Belrose

Graduate College Dissertations and Theses

Sediment accumulated on a lakebed archives information about past climate and changes in the regional environment. Previous studies (Burgess, 2007; Koff, 2011; Palmer, 2012) in the Northeast Arm of Lake Champlain, specifically Missisquoi Bay and Saint Albans Bay, showed a period (~9,400 - 8,600 yBP) of elevated organic matter deposition in both bays, indicating a productive event that pre-dated any possible anthropogenic influence. However, the record was abruptly cut off and any documentation representing the span of time leading up to this event was not found. The elevated organic matter levels were explained as being the result of a warm, …


Accelerated Degradation Of Chlorinated Solvents By Copper-Modified Nanoscale Zero Valent Iron (Cu-Nzvi) Stabilized With Carboxymethyl Cellulose, Andrew Franze Jan 2015

Accelerated Degradation Of Chlorinated Solvents By Copper-Modified Nanoscale Zero Valent Iron (Cu-Nzvi) Stabilized With Carboxymethyl Cellulose, Andrew Franze

Browse all Theses and Dissertations

Nanoscale zero valent iron (nZVI) is a remediation technology that can be used to treat chlorinated hydrocarbons (CHCs) in contaminated aquifers. Nanoparticles remain mobile in water and can be transported with groundwater flow to contaminated zones. However, due to magnetic and van der Waals forces, unstabilized nZVI agglomerates. Carboxymethylcellulose (CMC) was used as a polyelectrolyte stabilizer in this study. nZVI serves as an electron donor and can dechlorinate CHCs. nZVI reactivity with CHCs can be enhanced by addition of a secondary metal catalyst. This study evaluates the potential of copper amended nZVI (Cu-nZVI) to degrade select CHCs. The objective of …