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Hydrothermal Chemistry Of The M(I,Ii)/Paha/Anion System, Kari Ann Darling
Hydrothermal Chemistry Of The M(I,Ii)/Paha/Anion System, Kari Ann Darling
Chemistry - Dissertations
This research encompasses the detailed investigation of the design and synthesis of metal organic framework (MOF) materials involving the M(I,II)/ polyazaheterocycle/anion system in order to expand our understanding of the principles which render the chemistry more controllable and predictable. In addition, this research investigates the development of properties in these classes of compounds. Furthermore, it has been demonstrated that hydrothermal reaction conditions of stoichiometry, pH, and temperature can influence the identity of the products.
The structural versatility of the M(I,II)/polyazaheterocycle/anion system for M = Cu(I,II), Co(II), Ni (II), Zn (II), and Cd(II) and where the anion is F-, …