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Selected Synthetic Studies Of Nlo Pi-Bridges And Thermally Stable Monomers, Stacey Marie Fauley
Selected Synthetic Studies Of Nlo Pi-Bridges And Thermally Stable Monomers, Stacey Marie Fauley
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The molecular weights of two series of PEEK polymers were determined using gel permeation chromatography (GPC). The first series contains oxyalkylene linkages. The other series contains oxyethylene linkages. The synthesis of several thermally stable monomers has been investigated. These monomers include 9,9-dihexylfluorene-2,7-dicarboxaldehyde, 2,7-bis(bromomethyl)-9,9- dibutylfluorene and 2,7-bis(hydroxymethyl)-9,9-diethylfluorene. These monomers can be used to form polymers that will contain short conjugated segments separated by nonconjugated segments. The synthesis of 50 g of each of the following monomers was accomplished: bis(3-methylphenyl) phenylphosphine oxide, bis(4-methylphenyl)phenylphosphine oxide, bis(3- carboxyphenyl)phenylphosphine oxide and bis(4-carboxyphenyl)phenylphosphine oxide. These monomers will be used in a polymerization to form polybenzoxazoles. The …
The Synthesis Of Bromoethoxy And Vinylbenzyloxy Substituted Nlo Chromophores, Michael Joseph Matuszewski
The Synthesis Of Bromoethoxy And Vinylbenzyloxy Substituted Nlo Chromophores, Michael Joseph Matuszewski
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Multiphoton-absorption processes have recently attracted growing interest because of the potential impact on a wide spectrum of applications, ranging from data storage to photodynamic therapy. From the materials standpoint, particular interest is centered in designing chromophores that exhibit a large two-photon cross-section. The current research is focused on establishing synthetic routes that lead to the formation of derivatives of N,N-diphenyl-(7-benzothiazol-2-yl)-9,9-diethyl-9H-fluoren-2-ylamine which contain meta functionalization. A bromoethoxy functionalized chromophore, N-phenyl-N-(3-(2-bromoethoxy)phenyl)-7-(benzothiazol-2-yl)-9,9-diethyl-9H-fluoren- 2-ylamine , was synthesized and used as a polymer pendent while a vinylbenzyloxy chromophore, N-phenyl-N-(3-(4-vinylbenzyloxy)phenyl)-7- (benzothiazol-2-yl)-9,9-diethyl-9H-fluoren-2-ylamine, was synthesized as a hydrosilation substrate. A compound containing three chromophores, 1,3,5-tris(3-(N-phenyl- 4-(7-(benzothiazol-2-yl)-9,9-diethyl-9H-fluoren-2- ylanilino)phenoxymethyl)benzene, has …