Chemistry Commons^™

Microwave-Induced Bismuth Nitrate-Impregnated Claymediated Novel Dinitration Of 9,10- Dihydrophenanthrene: A Precursor For New Heterocycles, Ram Naresh Yadav, Leonardo Salazar, Amrendra Kumar Singh, Bimal K. Banik

Chemistry Faculty Publications and Presentations

A facile method for the dinitration of 9, 10-dihydrophenanthrene using domestic microwave-induced bismuth nitrate-impregnated clay is developed.

Expeditious Green Synthesis Of Versatile Organic Compounds By Diverse Methods, Bimal K. Banik

Chemistry Faculty Publications and Presentations

Synthesis of organic compounds requires organic solvents and reagents to promote them. Very often, toxic solvents are used for this purpose. Many organic reactions require molar proportion of reactants and reagents to accomplish the goal. Some reactions require longer reaction times and produce products without control of stereochemistry. Therefore, development of facile and effective organic reactions under environmentally friendly conditions is necessary. In this perspective, several reactions are discussed that are performed by microwave-induced reactions, catalytic procedures, in the absence of any solvents, one-pot method and in water. Important reactions are chosen to investigate the feasibility of conducting these reactions …

Microwave-Induced Bismuth Triiodide-Catalyzed Facile Synthesis Of Octahydroxanthenes, Ashlee Chavez, Jessica Cruz, Alexdra Munoz, Ram Naresh Yadav, Debasish Bandyopadhyay, Bimal K. Banik

Chemistry Faculty Publications and Presentations

Microwave-induced reaction of 1,3-cyclohexanedione with numerous aldehydes using bismuth iodide is performed successfully toward the synthesis of important octahydroxanthenes. A most probable mechanism is suggested to explain the formation of products.

Microwave-Assisted Polystyrene Sulfonatecatalyzed Synthesis Of Novel Pyrroles, Rosario Astrid Vargas Cardenas, Blanca Olinda Quintanilla Leal, Ashwini Reddy, Debasish Bandyopadhyay, Bimal K. Banik

Chemistry Faculty Publications and Presentations

Background: Pyrroles are widely distributed in nature and important biologically active molecules. The reaction of amines with 2,5-dimethoxytetrahydrofuran is a promising pathway for the synthesis of pharmacologically active pyrroles under microwave irradiation.

Results: Microwave-induced polystyrenesulfonate-catalyzed synthesis of pyrroles from amines and 2,5- diemthoxytetrahydrofuran has been accomplished with excellent yield. This method produces pyrroles with polyaromatic amines.

Conclusion: The present procedure for the synthesis of N-aromatic substituted pyrroles will find useful application in the area of pharmacologically active molecules.

A Microwave-Assisted Bismuth Nitrate-Catalyzed Unique Route Toward 1,4-Dihydropyridines, Debasish Bandyopadhyay, Stephanie Maldonado, Bimal K. Banik

Chemistry Faculty Publications and Presentations

The classical Hantzsch reaction is one of the simplest and most economical methods for the synthesis of biologically important and pharmacologically useful 1,4-dihydropyridine derivatives. Bismuth nitrate pentahydrate under microwave irradiation is proven to act as a very efficient catalyst for a one-pot, three-component synthesis of 1,4-dihydropyridines in excellent yields from diverse amines/ammonium acetate, aldehydes and 1,3-dicarbonyl compounds within 1-3 min under solvent-free conditions. The present environmentally benign procedure for the synthesis of 1,4-dihydropyridines is suitable for library synthesis and it will find application in the synthesis of potent biologically active molecules. The excellent yield and extreme rapidity of the method …

Bismuth Nitrate-Induced Microwave-Assisted Expeditious Synthesis Of Vanillin From Curcumin, Debasish Bandyopadhyay, Bimal K. Banik

Chemistry Faculty Publications and Presentations

Background: Curcumin and vanillin are the two useful compounds in food and medicine. Bismuth nitrate pentahydrate is an economical and ecofriendly reagent.

Method: Bismuth nitrate pentahydrate impregnated montmorillonite KSF clay and curcumin were subjected to microwave irradiation.

Results: Microwave-induced bismuth nitrate-promoted synthesis of vanillin from curcumin has been accomplished in good yield under solvent-free condition. Twenty-five different reaction conditions have been studied to optimize the process.

Conclusion: The present procedure for the synthesis of vanillin may find useful application in the area of industrial process development.

Microwave-Induced Bismuth Nitrate-Mediated Selective Hydrolysis Of Amide, Debasish Bandyopadhyay, Rene Solano Fonseca, Bimal K. Banik

Chemistry Faculty Publications and Presentations

Microwave-induced selective hydrolysis of amide to the corresponding amine has been achieved with bismuth nitrate and montmorillonite KSF clay.

Microwave-Induced Indium-Catalyzed Synthesis Of Pyrrole Fused With Indoline In Water, Dina Abrego, Debasish Bandyopadhyay, Bimal K. Banik

Chemistry Faculty Publications and Presentations

An expeditious microwave-induced indium metal-catalyzed synthesis of pyrrole fused with indoline in water is developed by reacting isatin and 4-hydroxyproline.

Microwave-Induced N-Bromosuccinimide-Mediated Novel Synthesis Of Pyrroles Via Paal-Knorr Reaction, Rosemarie Andoh-Baidoo, Roberto Danso, Sanghamitra Mukherjee, Debasish Bandyopadhyay, Bimal K. Banik

Chemistry Faculty Publications and Presentations

An expeditious rapid synthesis of N-substituted pyrroles using microwave-induced Nbromosuccinimide- mediated solventless reaction of 2,5-hexanedione and primary amine has been accomplished.

Microwave-Induced Bismuth Nitrate-Catalyzed Electrophilic Substitution Of Indole With Keto Ester Under Slovent-Free Conditions, Sonya Rivera, Laura Iglesias, Debasish Bandyopadhyay, Bimal K. Banik

Chemistry Faculty Publications and Presentations

Microwave-induced preparation of bis(indollyl)methane derivative has been developed through a bismuth nitrate-catalyzed reaction of indole with diethylketomalonate under solventfree conditions.

An Effective Microwave-Induced Iodine-Catalyzed Method For The Synthesis Of Quinoxalines Via Condensation Of 12-Diamines With 12-Dicarbonyl Compounds, Debasish Bandyopadhyay, Sanghamitra Mukherjee, Robert R. Rodriguez, Bimal K. Banik

Chemistry Faculty Publications and Presentations

A microwave-induced iodine-catalyzed simple, rapid and convenient synthesis of different types of quinoxalines via condensation of 1,2-diamines with 1,2-dicarbonyl compounds has been accomplished with an excellent yield.