Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 1 of 1
Full-Text Articles in Chemistry
Excitation-Dependent Photoluminescence Of Bazro3:Eu3+ Crystals, Santosh K. Gupta, Hisham Abdou, Carlo U. Segre, Yuanbing Mao
Excitation-Dependent Photoluminescence Of Bazro3:Eu3+ Crystals, Santosh K. Gupta, Hisham Abdou, Carlo U. Segre, Yuanbing Mao
Chemistry Faculty Publications and Presentations
The elucidation of local structure, excitation-dependent spectroscopy, and defect engineering in lanthanide ion-doped phosphors was a focal point of research. In this work, we have studied Eu3+-doped BaZrO3 (BZOE) submicron crystals that were synthesized by a molten salt method. The BZOE crystals show orange–red emission tunability under the host and dopant excitations at 279 nm and 395 nm, respectively, and the difference is determined in terms of the asymmetry ratio, Stark splitting, and intensity of the uncommon 5D0 → 7F0 transition. These distinct spectral features remain unaltered under different excitations for the BZOE …