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Full-Text Articles in Chemistry
The Role Of Particle Surface Functionality And Microstructure Development In Isothermal And Non-Isothermal Crystallization Behavior Of Polyamide 6/Cellulose Nanocrystals Nanocomposites, Shahram Rahimi, Joshua U. Otaigbe
The Role Of Particle Surface Functionality And Microstructure Development In Isothermal And Non-Isothermal Crystallization Behavior Of Polyamide 6/Cellulose Nanocrystals Nanocomposites, Shahram Rahimi, Joshua U. Otaigbe
Faculty Publications
Polyamide 6 (PA6)/cellulose nanocrystal (CNC) and aminopropyl triethoxy silane (APS) - modified CNC nanocomposites were prepared by in situ anionic ring opening polymerization and subsequent melt extrusion. The morphological observation of these hybrid systems revealed that the non-modified nanocrystals developed a network-like fibrillar structure while the APS-modified CNCs were finely dispersed mostly as individual whiskers. The isothermal and non-isothermal crystallization kinetics was extensively studied with emphasis on the effects of CNC surface functionality and the subsequent microstructure development on crystallization behavior of these novel nanocomposite systems. The non-modified CNC particles with corresponding fibrillar microstructure were found significantly hinder the crystallization …