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2002

Physics Faculty Research & Creative Works

Articles 1 - 8 of 8

Full-Text Articles in Chemistry

Magnetic And Neutron Diffraction Studies On Prmnsb₂, Satish K. Malik, Zili Chu, Amish G. Joshi, Jinbo Yang, William B. Yelon, Qingsheng Cai, William Joseph James, Kishore Kamaraju May 2002

Magnetic And Neutron Diffraction Studies On Prmnsb₂, Satish K. Malik, Zili Chu, Amish G. Joshi, Jinbo Yang, William B. Yelon, Qingsheng Cai, William Joseph James, Kishore Kamaraju

Physics Faculty Research & Creative Works

Magnetic and neutron diffraction studies have been carried out on PrMnSb2. Magnetization data in the temperature range of 5-400 K show two magnetic transitions: one at ∼175 K attributed to the antiferromagnetic ordering of the Mn moments, and the other at ∼35 K possibly due to the antiferromagnetic ordering of the Pr moments. The magnetization-field isotherms at various temperatures are consistent with the above. Neutron diffraction data obtained at various temperatures can be fitted with a nearly antiferromagnetically coupled Mn moment of ∼3μB at 70 K. At 10 K, moments both on Mn (∼3.5μB) and …

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Structure And Magnetic Properties Of The Mnbi Low Temperature Phase, Jinbo Yang, William B. Yelon, William Joseph James, Qingsheng Cai, Samit Roy, Naushad Ali May 2002

Structure And Magnetic Properties Of The Mnbi Low Temperature Phase, Jinbo Yang, William B. Yelon, William Joseph James, Qingsheng Cai, Samit Roy, Naushad Ali

Physics Faculty Research & Creative Works

High purity MnBi low temperature phase has been prepared and analyzed using magnetic measurements and neutron diffraction. The low-temperature phase of the MnBi alloy has a coercivity μ0iHc of 2.0 T at 400 K, and exhibits a positive temperature coefficient from 0 to at least 400 K. The neutron data refinement indicated that the Mn atom changes its spin direction from c axis above room temperature to nearly perpendicular to the c axis at 50 K. A canted magnetic structure has been observed below 200 K. The anisotropy field increases with increasing temperature which gives rise to …

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Observation Of Novel Disordered Rhombohedral R₂Fe₁₇ (R=Rare Earth) Based Compounds, William B. Yelon, William Joseph James, Jinbo Yang, Kishore Kamaraju, Qingsheng Cai, Zili Chu, Satish K. Malik May 2002

Observation Of Novel Disordered Rhombohedral R₂Fe₁₇ (R=Rare Earth) Based Compounds, William B. Yelon, William Joseph James, Jinbo Yang, Kishore Kamaraju, Qingsheng Cai, Zili Chu, Satish K. Malik

Physics Faculty Research & Creative Works

A recent study of (SmGd)Fe 14Si3 showed an anomalous x-ray diffraction pattern [P. C. Ezekwenna, G. K. Marasinghe, J.-H. Nam, W. J. James, W. B. Yelon, M. Ellouze, and Ph. I'Héritier, J. Appl. Phys. 87, 6716 (2000)]. Although all observed peaks could be indexed to the rhombohedral 2:17 phase (R-3m) many lines were strongly reduced in intensity. Subsequently, the same phenomenon was seen in neutron diffraction patterns from Nd2-xDysFe17-ySiy alloys and conventional refinement using the rhombohedral phase left significant residuals. Fourier mapping revealed additional density along the c-axis chains of Fe dumbbells …

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Possible Ordering Of Ru And Cu In The Charge-Reservoir Of Magneto-Superconductor Rusr₂Gdcu₂O₈ (Ru-1212): Magnetic, Transport, And Tem Microstructural Studies, V. P. S. Awana, S. Ichihara, J. Nakamura, M. Karppinen, H. Yamauchi, Jinbo Yang, William B. Yelon, William Joseph James, Satish K. Malik May 2002

Possible Ordering Of Ru And Cu In The Charge-Reservoir Of Magneto-Superconductor Rusr₂Gdcu₂O₈ (Ru-1212): Magnetic, Transport, And Tem Microstructural Studies, V. P. S. Awana, S. Ichihara, J. Nakamura, M. Karppinen, H. Yamauchi, Jinbo Yang, William B. Yelon, William Joseph James, Satish K. Malik

Physics Faculty Research & Creative Works

Magnetization vs temperature behavior of RuSr2GdCu2O8-δ (Ru-1212) measured in an field of 5 Oe, shows a clear branching of zero-field-cooled (ZFC) and field-cooled (FC) curves around 140 K, a cusp at 135 K, and a diamagnetic transition around 20 K (in the ZFC branch). The cusp at 135 K is due to the antiferromagnetic ordering of the Ru moments. The magnetization-field isotherms, below 50 K, show a nonlinear contribution from a ferromagnetic component. The resistance vs temperature behavior of the compound, in applied fields of 0, 3, and 7 T, confirms that the sample is …

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Magnetic And Mössbauer Studies On Oxygen Deficient Perovskite, La₀.₆Sr₀.₄Feo3-Δ, Jinbo Yang, William B. Yelon, William Joseph James, X.-D. Zhou, Yixiang Xie, Harlan U. Anderson, Zili Chu May 2002

Magnetic And Mössbauer Studies On Oxygen Deficient Perovskite, La₀.₆Sr₀.₄Feo3-Δ, Jinbo Yang, William B. Yelon, William Joseph James, X.-D. Zhou, Yixiang Xie, Harlan U. Anderson, Zili Chu

Physics Faculty Research & Creative Works

Samples of La0.6Sr0.4Fe3-δ with varying oxygen vacancy contents were prepared by heating them in different gas flows. Magnetization measurement showed that samples with low oxygen vacancies have a magnetic ordering temperature in the range of 300-325 K while those with 9%-12% oxygen vacancies have a magnetic ordering temperature of 800 K and higher. Mössbauer spectra at 300 K exhibit paramagnetic or weak magnetic characteristics for the N2, O2, and air-quenched samples, whereas an average hyperfine field of 52 T is found for the CO/CO2 reduced samples. The heat treatment in …

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Magnetic Properties Of Iron-Rich Mixed Rare-Earth Sm₂-ₓtbₓfe17-YSiY Compounds, Kishore Kamaraju, Jinbo Yang, William B. Yelon, Oran Allan Pringle, William Joseph James, Ph. I'Héritier May 2002

Magnetic Properties Of Iron-Rich Mixed Rare-Earth Sm₂-ₓtbₓfe17-YSiY Compounds, Kishore Kamaraju, Jinbo Yang, William B. Yelon, Oran Allan Pringle, William Joseph James, Ph. I'Héritier

Physics Faculty Research & Creative Works

A series of Sm2-xTbxFe17-ySiy solid solutions with x = 0, 1, and 1.5 and y = 1, 2, and 3 were prepared by induction melting stoichiometric amounts of high purity elements. The x-ray diffraction data confirm that the postannealed samples are 2:17 intermetallics of the R3 space group. The lattice parameters and the unit cell volumes were calculated using a modified Rietveld program. The fitted intensities showed behavior related to a disordered rhombohedral structure as inferred from neutron data. It was observed that for a particular y, the unit cell volume decreased almost …

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Electrical And Magnetotransport Properties Of Canted Antiferromagnet Dy₅Si₂Ge₂, R. Nirmala, V. Sankaranarayanan, K. Sethupathi, Zili Chu, William B. Yelon, V. Prasad, A. V. Morozkin, Satish K. Malik, S. V. Subramanyam Jan 2002

Electrical And Magnetotransport Properties Of Canted Antiferromagnet Dy₅Si₂Ge₂, R. Nirmala, V. Sankaranarayanan, K. Sethupathi, Zili Chu, William B. Yelon, V. Prasad, A. V. Morozkin, Satish K. Malik, S. V. Subramanyam

Physics Faculty Research & Creative Works

Summary form only given. Since the giant magnetocaloric effect is encountered in a ferromagnetic Gd5Si2Ge2 alloy near room temperature it is considered as a suitable material for magnetic refrigerator applications. Also a commensurate structural transition occurs at the magnetic transition temperature and there is a good correlation between the crystal structure and magnetic properties. Such observations have triggered numerous experimental studies on similar rare earth alloys and compounds. We have synthesized its Dy- analogue, namely, Dy5Si2Ge2 and have characterized it by means of room temperature X-ray diffraction, ac magnetic susceptibility (15 K - 300 K), electrical resistivity (at zero field …

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Effect Of Oxygen Vacancies On The Magnetic Structure Of The La₀.₆Sr₀.₄Feo3-Δ Perovskite: A Neutron Diffraction Study, Zili Chu, William B. Yelon, Jinbo Yang, William Joseph James, Harlan U. Anderson, Yixiang Xie, Satish K. Malik Jan 2002

Effect Of Oxygen Vacancies On The Magnetic Structure Of The La₀.₆Sr₀.₄Feo3-Δ Perovskite: A Neutron Diffraction Study, Zili Chu, William B. Yelon, Jinbo Yang, William Joseph James, Harlan U. Anderson, Yixiang Xie, Satish K. Malik

Physics Faculty Research & Creative Works

Magnetic interactions in perovskite compounds of the type La1-xSrxMO3-δ (M=3d transition such as Mn and Fe) are presumed to arise through a super exchange between 3d electrons of the magnetic ions via oxygen orbitals. The magnetic structure of La0.6Sr0.4FeO3-δ has been studied with neutron diffraction. Oxygen vacancies were created by annealing samples under various gases including N2, air and mixtures of CO/CO2. All La0.6Sr0.4FeO3-δ compounds maintain the rhombohedral structure (space group R3̄c). The air- or oxygen-annealed samples have almost no oxygen …

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