Chemistry Commons^™

Application Of The Quasi-Lattice Theory To The Heats Of Mixing Of Some Alcohol-Hydrocarbon Systems, Mar Lynn James

Theses and Dissertations

Values for the heats of mixing were obtained calorimetrically for the systems C2H5OH-C6H12, CH3OH-C6H6 and C2H5OH-C6H6 at 25° over the complete range of composition. Analytical equations which summarize these values are: Benzene (1) - Methanol (2) System ΔHxM = x1x2[628.4 + 365.7(x1-x2) + 521.9(x1-x2)3 + 819.8(x1-x2)4 ] Benzene (1) - Ethanol (2) System ΔHxM = x1x2[748.8 + 534.1(x1-x2) + 265.7(x1-x2)2 + 408.7(x1-x2)3 + 434.1(x1-x2)4 ] Cyclohexane (1) - Ethanol (2) System ΔHxM = x1x2[615.0 + 132.4(x1-x2) + 195.9(x1-x2)2 + 251.5(x1-x2)3 + 521.7(x1-x2)4 ] where xi is the mole fraction of component i. The experimental data were satisfactorily interpreted by a …

3rd Annual Rocky Mountain Spectroscopy Conference Abstracts Of Papers

Rocky Mountain Conference on Magnetic Resonance

Abstracts of papers presented at the 3rd annual meeting of the Rocky Mountain Spectroscopy Conference, sponsored by the Rocky Mountain Section of the Society for Applied Spectroscopy. Held in Denver, Colorado, August 8-9, 1960.

3rd Annual Rocky Mountain Spectroscopy Conference Program

Rocky Mountain Conference on Magnetic Resonance

Program from the 3rd annual meeting of the Rocky Mountain Spectroscopy Conference, sponsored by the Rocky Mountain Section of the Society for Applied Spectroscopy. Held in Denver, Colorado, August 8-9, 1960.

A Study Of The Curcumin Method For Boron Determination, James Edward Hardcastle

Master's Theses

The purpose of the research project, of which this thesis is a partial report, was two fold: first, to develop a method for determining small quantities of boron, and second, to develop a rapid field test for the determination of atmospheric boron. A literature survey revealed that the curcumin method is the most sensitive colorimetric method presently available for boron determination. Also, the curcumin paper test should be readily adapted to the determination of atmospheric boron.

An Investigation Of Solvent Extraction Techniques In The Determination Of Formation Constants Of Complex Species In Aqueous Silver Chloride Solution, David Martin Bodily

Theses and Dissertations

Solvent extraction techniques have been used to determine formation constants for molecular silver chloride and dichloro silver (I) ion in unsaturated aqueous solutions. Nitrobenzene was used to extract the molecular silver chloride from the aqueous silver chloride solution. The total concentration of silver in each phase was determined by radioassay techniques and related by an expression involving the equilibrium constants. The reciprocal of the distribution ratio times the activity of the chloride ion was plotted versus the activity of the chloride ion and portions of the curve were analyzed by the method of least squares to obtain values for the …

The Dilute Solution Chemistry Of Antimony, Kent H. Jones

Chemistry and Chemical Biology ETDs

Investigation of the chemistry of the elements by conventional methods is generally limited to concentrations on the order of 10^-5 M or higher. The discovery of radio-activity opened new fields in chemistry among which is the obtaining of information concerning chemical behavior of elements at very low concentrations. For many years after the initial discovery of radioactivity in 1896 by Becquerel, the study of low-concentration chemistry was limited to about ten naturally occurring radioactive elements. A renewed interest in this field was generated after 1934 when it was discovered by Curie and Joliot that radioactive elements could be artificially …

Potentiometric Titrations Of Metal Ions With Edta, Donald Theodore Carlson

Honors Theses

Ethylenediaminetetracetic acid, known commonly as EDTA and commercially as Versene, Trilon B, Sequestrene, and Complexone II, III, and IV; was first produced in 1936 by the I.G. Farbenindustrie. EDTA reacts chemically as a ligand. That is, it forms a complex by occupying two or more coordination prositions of the atom it reacts with. The resulting complex is called a chelate, which stems from the Greek word for clas. EDTA acts as a sequestering agent by forming stable, water-soluble chelates with metal ions.

The Determination Of The Cross-Sectional Area Of A Stearic Acid Molecule, Michael Stacey Dryer

Honors Theses

The fundamental relationship determining the area per molecule is: A = SM/ (g/c x v x N) A = area per molecule. S = area occupied by the monolayer. M = molecular weight. g = grams of stearic acid in volume c. c = volume of solution. v = aliquot of c delivered to the surface. N = Avogadro’s Number. Each of the terms in the above equation will be discussed in detail below.

Further Studies On Zirconia Gels, James Emmons Anderson

Honors Theses

When solutions of zirconium oxychloride and sodium acetate are mixed at room temperature (25°c.), a grey-white hydrogel of zirconia is formed. This gel structure gradually weakens on standing, and finally becomes a water-clear sol. Heating this sol to 6o°c. will form a similar gel, stable at this temperature, which will reliquefy on cooling to 25°c. The gelation-reliquefaction cycle can apparently be carried out indefinitely. Such behavior is in direct contrast to normal gelation. The so-called “irreversible gels”, such as those of silicic acid, show stability at all temperatures; while other “reversible gels”, such as common gelatin, set at lower temperatures …

Liquid-Vapor Equilibria In The System: Isopropyl Alcohol-Dibromomethane, John Henry Nickles

Honors Theses

The purpose of this research project was to determine more closely the liquid vapor equilibrium curve and the boiling point and composition of the azeotrope formed in the system isopropyl alcohol - dibromomethane. This system is reported in Horsley's book from Lecat as forming an azeotrope at a bioling point less than 81.0 degrees Celsius. Both components have boiling points of less than 100 degrees Celsius and their refractive indices are well separated, thus making investigation with fairly simple, but accurate apparatus possible.

The Alkylation Of Phenol, William Raymond Stine

Honors Theses

Attention was focused on the formation of the various isomers of butyl phenol.

Investigations For A Rapid Qualitative Method For The Detection Of Organic Herbicides, Robert Albert Jung

Honors Theses

The present study is undertaken in an attempt to find a rapid qualitative or semi-quantitative method for the detection of organic herbicides in water.

Part A: Studies Of Organic Solvent Enhancements In Flame Photometry; Part B: Studies Of The Extraction And Flame Emission Of Magnesium, Jack Hudgens Knox

Doctoral Dissertations

Summary

The present investigation has been concerned with the study of several parameters which influence the flame photometric emission of elements in an effort to elucidate the nature of the intensifications observed with organic solvents. Parameters such as flames temperature, OH band intensity, ionization, sample flow rate, and the emission intensities of different elements in different solvents have been studied.

Interaction Of Riboflavin With Molybdenum, Jacques Tocatlian

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Molybdenum may function as a catalyst in promoting and controlling some of the complex chemical reactions that go on in living systems. The lack of understanding which exists about these reactions is due to their obvious complexity and to the extremely minute quantities of molybdenum involved. Traces of molybdenum have been shown to have spectacular results on the growth of plants when added to certain soils. This metal is also required for the growth of azobacter, the nitrogen-fixing bacteria (1).

Molybdenum has been shown to be present in four enzymes: nitrate reductase (2), hydrogenase (3), xanthine oxidase (4) and aldehyde …

Voltammetry With A Mercury Pool Cathode, David Peter Stricos

Honors Theses

Voltarnmetry with a mercury pool cathode has been examined using both slow and rapid scanning techniques. A conventional polarograph was used to interpret the slow scans, and a cathode ray polarograph for the rapid scans. A description of the necessary apparatus is given as well as the experimental details involved.

Three different supporting media were studied: 0.01 molar potassium nitrate, 0.1 molar potassium acid phthalate, and 0.1 molar ammonia-0.1 molar ammonium chloride. Well defined peaks were observed for lead, cadmium, and zinc in potassium nitrate. Indium also gave a peak, but it was not characteristic of a three-electron reduction. Furthermore, …

An Investigation Of The Formation Constant Of Molecular Silver Chloride Using Ion Exchange Techniques.|Nii.|Pan Investigation Of The Rate Of Precipitation Of Silver Sulfide By Thioacetamide, James W. Pyper

Theses and Dissertations

The first part of this work reports on the investigation of the formation constant of molecular silver chloride using ion exchange techniques. In order to determine the formation constant, it was necessary to develop a method of rinsing the sorbed molecular silver chloride from the resin. It was found that desorption with nitrobenzene would remove the sorbed molecular species. However, the formation constant was not calculated since the nitrobenzene used contained hydrogen ion and chloride ion which removed silver ion as well as the molecular species. In the study of the formation of silver sulfide by the reaction between the …

Metal-Metal Ion Exchange Of Mercury And Some Amalgams, Richard Charles Legendre

Doctoral Dissertations

Proposed Problem

The objective of this research was to investigate the behavior of metal ions in aqueous solution in their exchange with atoms of the same metal, but where the metallic phase would be in the liquid state.

Research along these lines but involving solid metallic phases has demonstrated that the exchangeability of an ion with a solid metal probably depends on the ability of the metal to re-form its surfaces when in contact with these solutions. A preceding section has reported on the sensitivity of exchange to any of the various processes that can affect the nature of the …

Determination Of Arsenic In Fish By Neutron Activation Analysis, William Walter Ullmann

Honors Theses

The use of arsenicals to control aquatic vegetation has become widespread. A study was conducted to determine possible uptake of arsenic by fish in treated waters. Present methods for the analysis of arsenic (1,2) are reliable when applied to water and bottom samples which contain relatively small concentrations of organic matter. In the presence of larger concentrations, arsenic is lost during digestion. Recoveries of from 40-60 per cent were obtained when the method for the analysis of arsenic in food (2) was applied to fish flesh.

A Study Of The Kinetics Of The Oxidation Of Uranium(Iv) By Cerium(Iv), Floyd Beatty Baker

Chemistry and Chemical Biology ETDs

The kinetics of a number of oxidation-reduction reactions and exchange reactions involving cations of the transition and inner transition elements have been extensively reviewed by T. W. Newton and S. W. Rabideau. These workers represent the formation of the activated complex by an equation which includes only the principal species in solution as reactants.

Gas Chromatography Of Hydrogen-Deuterium Mixtures, Paul Payson Hunt

Doctoral Dissertations

Introduction: In recent years the gas chromatographic method has found widespread applications, chiefly for analytical purposes. This method is principally employed for the separation, identification, and quantitative determination of volatile compounds. It is potentially of great value for the quantitative determination of mixtures of the hydrogen isotopes. The development of a rapid, convenient, and inexpensive method for the analysis of the hydrogen isotopes would be a valuable addition to many laboratories, especially those where a mass spectrograph is unavailable. This problem was undertaken in an attempt to develop further the chromatographic method for the separation and quantitative determination of hydrogen …

List Of Registered Fertilisers : 1959-60, H G. Cariss

Journal of the Department of Agriculture, Western Australia, Series 4

TN accordance with the provisions of the Fertilisers Act, 1928-1955, it is required that—with the exception of bulk sales to a manufacturer and those made in accordance with a buyer's written prescription—all fertilisers sold are required to be registered annually, the registration year being from November 1 to October 31 following.

The list of fertilisers registered for the year commencing November 1, 1959, is set out herewith in tabular form.

The Chelation Of Cu(Ii) With 1, 3-Bis(Tris(Hydroxymethyl)Methylamino)-2-Propanol And 1, 3-Bis (2-Hydroxyethylamino)-2-Propanol, David Andrew Jackson Jr.

Master's Theses

The chelating agent 1, 3-bis(2-hydroxyethylamino)-2-propanol dihydro­chloride was prepared and preliminary examinations of the Cu(ll) and Fe(lll) complexes were carried out spectrophotometrically. This dihydrochloride as well as 1, 3 bis(tris(hydroxymethyl)methylamino)-2-propanol dihydrochloride. were converted from the chloride salts to their corresponding ammonium bases. The conversion was carried out by passing an aqueous solution of each chloride salt through an ion exchange column containing Amberlite XE-78 resin.

Solutions of these bases were standardized for use in potentiometric titration&. Each ammonium base was titrated with standard perchloric acid at 20°C, 30°C, and 40°C. The dissociation constants. were calculated using these data. Aqueous solutions of …

Preparation Of Elemental Boron And Measurement Of Its Emittance At Incandescent Temperatures, Claude P. Talley

Master's Theses

The normal spectral emittance at 0. 65 microns of elemental boron specimens was measured at incandescent temperatures by the hollow-tube method, This was made possible by depositing boron onto thin-walled hollow tubes of graphite and molybdenum. An approximate value of the total hemispherical emittance for boron was also obtained. The deposition of boron was accomplished by chemical vapor plating with boron tribromide and hydrogen. The boron produced was characterized in several ways.

The Development Of Nickel Electrodeposits On Copper Monocrystals As Studied With The Electron Microscope, Lucille Burnett Garmon

Master's Theses

Important theoretical and experimental developments in the field of electrocrystallization on single crystals are briefly reviewed and new data presented. The deposition of nickel from a Watts-type bath onto electrolytically polished mono crystals of copper is the system chosen for study. Various aspects of the structural changes in the deposit with increasing thickness are considered. The electron microscope is the main tool employed and the deposit is studied by detaching it from the basis metal as well as by the use of surface replicas. Short backgrounds in crystallography and electron microscopy are included.

A Chromatographic Study Of The Polyphenols In Cured Tobacco, Marvin Dennis Edmonds

Master's Theses

The object of this project was to isolate, separate, and identify the polyphenols in tobacco. Following this, the aim was to develop a method for the quantitative determination of the major polyphenols in tobacco.

Existing methods for the determination of polyphenols in tobacco involve lengthy procedures which are concerned with one or two of the polyphenols rather than the· complete class of compounds. The methods consist of exhaustive extraction procedures, lengthy chromatographic procedures and numerous methods of identification.

Extensive research on the determination of polyphenols by chromatography has been carried out in the field of tobacco and in other fields. …

3-Amino-2,5-Dihydroxy-5-Sulfo-Benzoic Acid, Hideo Tomomatsu

University of the Pacific Theses and Dissertations

It seems possible that efforts to discover essential chemical differences which might exist between normal and malignant cells will eventually reveal the secret of cancer and thereby lead to new approaches to safer and more selective chemotherapy.

One objective of this study is to find that part of this molecule that causes it to concentrate in the tumor and thence make a smaller size compound which has similar concentration characteristics to tumor as tetracycline. For this purpose, an attempt was made in this study to synthesize the right side ring of Chlorotetracycline, the structure of which is shown below. [see …

The Dielectric Strength Of Some Anti-Corrosive Paints, John Harvey Gustafson

Masters Theses

"Metals undergo chemical reaction with nonmetallic elements of their surroundings to produce compounds which are either oxides or salts. These corrosion products, as they are called, may accelerate, impede, or have no influence on the course of further corrosion. It is unfortunate that iron, the metal of greatest use to man, receives very little protection from its corrosion products. There are no easy or inexpensive means of prevention of this corrosion and at best the reactions can only be controlled. One method of control is the use of anti-corrosive paints. Their protection is produced by placing an inert, continuous, and …

Feeding Pickled Wheat To Pigs, Department Of Agriculture, Western Australia

Journal of the Department of Agriculture, Western Australia, Series 4

INQUIRIES are frequently received from farmers asking whether it is safe to feed pickled wheat to pigs, and if so, the quantities which would be suggested.

Until very recently there was no experimental information on the safety or possible dangers of these wheat pickling agents, but feeding trials completed last year at the Animal Health and Nutrition Laboratory, Nedlands, have provided some of the answers to these questions.

Weed Research. 7. Weed Control Around The Yard, Geoffrey A. Pearce

Journal of the Department of Agriculture, Western Australia, Series 4

MANY farmers and city householders have weed problems around houses and sheds which can be readily overcome by treatment with appropriate herbicides.

The risk from fire through weeds and unslightly growth can easily be removed and an area free of any plant growth can be maintained with little effort for a considerable period.

Oxygen Permeability Of Free Paint Films, Janice I. Kellerman

Masters Theses

"As early as the mid 1800’s investigations were performed on the gas passage through rubber, but it is only comparatively recently that plastic polymeric materials have come into prominence. One interesting aspect of much experimentation begun was that of permeability, and it was soon evident that, in general, polymeric materials have extremely low permeability of gases. This is, in essence, the basis for use of plastics as packaging materials, balloons, and in many other designs and fabrications where it is desirous and/or necessary to exclude air.

There are several variables which must be taken into consideration in the evaluation of …