Open Access. Powered by Scholars. Published by Universities.®

Chemistry Commons

Open Access. Powered by Scholars. Published by Universities.®

Articles 1 - 4 of 4

Full-Text Articles in Chemistry

Polyol Induced Extraction (Pie) Of Water From Organic Solvents, Mithilesh Deshpande Aug 2014

Polyol Induced Extraction (Pie) Of Water From Organic Solvents, Mithilesh Deshpande

Seton Hall University Dissertations and Theses (ETDs)

Acetonitrile (ACN) is used in huge quantities for Reversed Phase High Performance Liquid Chromatography (RP-HPLC) experiments. For most of the part, these results in waste that is only contaminated with large amounts of water, buffer and trace organic impurities. It would seem worthwhile to purify the ACN from water using a mass separating agent (MSA). In a quest for an MSA, our investigation reveals polyols as a new class of MSAs. It is observed that when a polyol such as glycerol, sorbitol, erythritol, xylitol, Isomalt® or maltitol is added to a mixture of ACN-water, the ACN separates out of the …


3d Flowerlike Micro/Nanocomposite Ceria To Remove Arsenic And Chromium In Drinking Water, Taera Kim Jun 2014

3d Flowerlike Micro/Nanocomposite Ceria To Remove Arsenic And Chromium In Drinking Water, Taera Kim

Honors Theses

Ceria has received great attention for the removal of water contaminants due to its high oxygen storage capacity, marked oxygen ion conductivity, and tunable catalytic activity. Zhong et al. suggested that ceria (cerium oxide) microspheres with nanoscale 3D flowerlike morphology represent a promising inorganic synthetic material to remove water contaminants such as As(V) and Cr(VI) from drinking water. The 3D flowerlike micro/nanocomposite ceria offer key advantages over other nanoparticle based remediation systems as they can be easily removed via conventional microfiltration. The goals of this thesis project were to test the reproducibility of the synthesis of the 3D flowerlike ceria, …


Improving The Microbial Source Tracking Toolbox : Evaluating The Use Of Selective Enrichments And Artificial Sweeteners In A Multi-Tiered Approach, Stacey A. Helming Jan 2014

Improving The Microbial Source Tracking Toolbox : Evaluating The Use Of Selective Enrichments And Artificial Sweeteners In A Multi-Tiered Approach, Stacey A. Helming

Legacy Theses & Dissertations (2009 - 2024)

Microbial contamination of surface waters is a public health concern world-wide, with non-point source fecal input contributing to millions of cases of waterborne illness annually. Numerous techniques have been proposed to monitor for non-point source fecal contamination, but few studies have explored the correlation of multiple chemical and microbial fecal source tracking markers in ambient waters. Therefore, the purpose of these studies was to evaluate the use of multiple "ideal" markers of fecal contamination and improve upon any analytical techniques required to identify species-specific fecal contamination in surface waters. The use of selective enrichments to improve the sensitivity of end-point …


First-Principles Study Of The Electric Field Effect On The Water-Adsorbed Rutile Titanium Dioxide Surface, Abraham L. Hmiel Jan 2014

First-Principles Study Of The Electric Field Effect On The Water-Adsorbed Rutile Titanium Dioxide Surface, Abraham L. Hmiel

Legacy Theses & Dissertations (2009 - 2024)

TiO2 is a semiconducting material that has been used extensively in many industrial applications, and recently has become a candidate for photocatalytic water splitting, fuel cell anode support materials, sensors, and other novel nanodevices. The interface of TiO2 with water, historically well-studied but still poorly understood, presents a ubiquitous environmental challenge towards the ultimate practical usefulness of these technologies. Ground-state density functional theory (DFT) calculations studying the characteristics of molecular adsorption on model surfaces have been studied for decades, showing constant improvement in the description of the energetics and electronic structure at interfaces. These simulations are invaluable in the …