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Full-Text Articles in Chemistry
Two Kinds Of Polaronsobservedin Polyanilinein Aqueous H_2so_4, Qin Zhou, Lin Zhuang, Jun-Tao Lu
Two Kinds Of Polaronsobservedin Polyanilinein Aqueous H_2so_4, Qin Zhou, Lin Zhuang, Jun-Tao Lu
Journal of Electrochemistry
Simultaneous electrochemistry electron spin resonance (ESR) conductance measurements were carried out on electropolymerized polyaniline and ESR spectra were obtained with high signal/noise ratio. Spectral simulation revealed that in the early stage of polymerization, there were two kinds of polarons. According to the potential dependence of the ESR line width and the corresponding conductivitychange of the polymer, the two polarons are thought to be in ordered and disordered domains, respectively. With increasing doping level, the two polarons underwent similar transfer from Curie spin to Pauli spin and both polarons were charge carriers in the conducting polymer. This deduction was further supported …
Study Of Anti-Corrosion Property On Poly(An-Co-Oas)/Epoxy, Qing-Wu Wang, Geng-Chao Wang
Study Of Anti-Corrosion Property On Poly(An-Co-Oas)/Epoxy, Qing-Wu Wang, Geng-Chao Wang
Journal of Electrochemistry
polyaniline, polyanisidine and their copolymer poly(An-co-oAs) were synthesized via the solution chemical oxidative polymerization of aniline and anisidine in an acidic aqueous medium, and their properties and structure were characterized. The electrochemical method were applied to evaluate the corrosion behavior of tined iron uncoated or coated by polyaniline, poly(An-o-oAs), polyanisidine and poly(An-co-oAs)/epoxy blend in acid or saline aqueous solution. The result showed that with the increase of anisidine content, the solubility of polymers is improved apparently but their oxidation extent decreases accordingly. It is also founded that polyaniline, poly(An-co-oAs) and polyanisidine all have good anti-corrosion properties, and their anti-corrosion capacity …