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Study Of Electrochemistry Of Aloe-Emodin And Determination Of It With 1.5th Order Derivative Anodic Stripping Voltammetry, Xin Hua Lin, Li Ying Huang, Wei Chen, Hong-Bin Luo, Bin Qiu, Chun-Yan Li
Study Of Electrochemistry Of Aloe-Emodin And Determination Of It With 1.5th Order Derivative Anodic Stripping Voltammetry, Xin Hua Lin, Li Ying Huang, Wei Chen, Hong-Bin Luo, Bin Qiu, Chun-Yan Li
Journal of Electrochemistry
In 0.1 mol/L HAc solution(pH=2.89),the voltammetric behaviours of aloe emodin at a glassy carbon electode has been studied. One pair of current peak of the voltammogram may be attributed to a quasireversible two electron transfer of aloe emodin molecules at the glassy carbon electrode. A new method, the derivative anodic stripping voltammetry, for aloe emodin determination is described. The adsorptive potential of aloe emodin is -0.80V(vs. SCE),while its stripping potential is -0.38V(vs.SCE). The peak current is propotional to the concentration of aloe emodin over the range of 2.0×10 -7 ~8.0×10 -6 mol/L. The method is simple, rapid and reliable for …
Voltammetry Of The Anticancer Drug Mitoxantrone And Dna, Arzum Erdem, Mehmet Özsöz
Voltammetry Of The Anticancer Drug Mitoxantrone And Dna, Arzum Erdem, Mehmet Özsöz
Turkish Journal of Chemistry
The interaction of mitoxantrone (MTX) with calf thymus double-stranded DNA (dsDNA) and calf thymus single-stranded DNA (ssDNA) was studied electrochemically by using differential pulse voltammetry (DPV) and cyclic voltammetry (CV) at a carbon paste electrode (CPE). The changes in the experimental parameters (the concentration of MTX, the concentration of DNA and the accumulation time of MTX) were studied by DPV; in addition, the detection limit and the reproducibility were determined. It was observed for the interaction of MTX with dsDNA and ssDNA that the signal of the bare electrode was higher than the signal of the dsDNA modified CPE. The …