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Dicarbonyldichloridobis(Trimethylphosphane)Iron(Ii)–Carbonyldichloridotris(Trimethylphosphane)Iron(Ii)–Tetrahydrofuran (1/1/2), Nigam P. Rath, Meghan Stouffer, Matthew K. Janssen, John R. Bleeke
Dicarbonyldichloridobis(Trimethylphosphane)Iron(Ii)–Carbonyldichloridotris(Trimethylphosphane)Iron(Ii)–Tetrahydrofuran (1/1/2), Nigam P. Rath, Meghan Stouffer, Matthew K. Janssen, John R. Bleeke
Nigam Rath
The asymmetric unit of the title crystal, [FeCl2(C3H9P)3(CO)]·[FeCl2(C3H9P)2(CO)2]·2C4H8O, contains half molecules of the two closely related FeII complexes lying on mirror planes and a tetrahydrofuran solvent molecule, one C atom of which is disordered over two sets of sites with site occupancy factors 0.633 (9) and 0.367 (9). In both FeII complex molecules, a distorted octahedral coordination geometry has been observed around the Fe atoms. Weak intermolecular C-H...O interactions are observed in the crystal structure.