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Articles 1 - 7 of 7
Full-Text Articles in Chemistry
Self-Assembly Of Black Cumin Oil-Based Nanoemulsion On Various Surfactants: A Molecular Dynamics Study, Aulia Fikri Hidayat, Taufik Muhammad Fakih
Self-Assembly Of Black Cumin Oil-Based Nanoemulsion On Various Surfactants: A Molecular Dynamics Study, Aulia Fikri Hidayat, Taufik Muhammad Fakih
Makara Journal of Science
Black cumin is commonly used as traditional medicine due to its wide range of pharmacological potential. Black cumin oil (BCO) was often prepared as nanoemulsion to improve its solubility, stability, and bioavailability. This study was conducted to investigate the molecular behavior as well as structural evolution of BCO-surfactant systems during self-assembly micellization using molecular dynamics (MD) simulations. Several BCO constituents and variations of surfactants were employed to model BCO-surfactant systems. 50 ns of MD simulations were performed to elucidate their evolution of structures and physicochemical properties during formation. Results showed that BCO-tween20 and BCO-lecithin were able to form spherical-shaped micelles …
Hemoglobin-Modified Core–Shell Fe3o4@Au Nanostructures For The Electrochemical Detection Of Acrylamide, Endang Saepudin, Tri Yuliani, Mochammad Arfin Fardiansyah Nasution, Munawar Khalil, Jong Wook Hong, Tribidasari Anggraningrum Ivandini
Hemoglobin-Modified Core–Shell Fe3o4@Au Nanostructures For The Electrochemical Detection Of Acrylamide, Endang Saepudin, Tri Yuliani, Mochammad Arfin Fardiansyah Nasution, Munawar Khalil, Jong Wook Hong, Tribidasari Anggraningrum Ivandini
Makara Journal of Science
In this study, electrochemical detection of acrylamide using hemoglobin (Hb)-modified core–shell Fe3O4@Au nanostructures was conducted. Fe3O4 nanoparticles (~4.9 nm) and core–shell Fe3O4@Au (5.0–6.4 nm) nanostructures were successfully synthesized by the thermal decomposition method. Electrochemical investigation revealed that the optimum amount of Hb of 2 mg/mL could be immobilized in 0.1 M acetate buffer solution (pH = 6). Moreover, the detection of acrylamide using Fe3O4@Au/Hb was evaluated by the cyclic voltammetry technique. A linear calibration curve (R2 = 0.98) in the concentration range of …
Synthesis And Complexation Of Monotosylated 4-Aminopyridine With Nickel (Ii) And Iron (Ii) Ions, Kingsley John Orie, Remy Ukachukwu Duru, Raphael I-Oro Ngochindo
Synthesis And Complexation Of Monotosylated 4-Aminopyridine With Nickel (Ii) And Iron (Ii) Ions, Kingsley John Orie, Remy Ukachukwu Duru, Raphael I-Oro Ngochindo
Makara Journal of Science
Tosylated 4-aminopyridine and other sulfonylated compounds of amines comprise a substantial class of pharmaceutical drugs used as antibiotics in the field of medicine. This research aimed at the synthesis of tosylated 4-aminopyridine and the complexation of the tosyated 4-aminopyridine with Ni(II) and Fe(II) ions. The sulfonamide was prepared by the action of tosyl chloride on 4-aminopyridine in an aqueous alkaline medium. The complexes were synthesized by the reaction of Ni(NO3)2.6H2O /Fe(NO3)2.6H2O with sulfonamide derivative. These compounds were characterized through Ultraviolet Visible spectroscopy (UV–Vis), Fourier Transform Infer-Red (FTIR) spectroscopy, …
Synthesis And Characterization Of Cellulose Acetate Membrane From Cotton Spinning Waste, Silvy Djayanti, Syarifa Arum Kusumastuti, Januar Fatkhurrahman, Agus Purwanto, Agung Budiarto, Alex Lukmanto Suherman
Synthesis And Characterization Of Cellulose Acetate Membrane From Cotton Spinning Waste, Silvy Djayanti, Syarifa Arum Kusumastuti, Januar Fatkhurrahman, Agus Purwanto, Agung Budiarto, Alex Lukmanto Suherman
Makara Journal of Science
Cellulose acetate membrane (CAM) was successfully synthesized and characterized from the cotton spinning waste of the textile industry. The membrane was produced through the isolation, acetylation, and phase inversion stages. The highest yields of cellulose fiber and α-cellulose contents were obtained using 3.0% and 6.0% v/v NaClO, respectively. The C–O acetyl bond detected by Fourier Transform Infrared (FTIR) analysis indicates the formation of the CAM. The resulting membrane can be potentially applied as an ultrafiltration membrane for water desalination purposes in water and wastewater treatment facilities. Furthermore, the utilization of cotton spinning waste as raw material aims to produce inexpensive …
Effects Of Different Extraction Solvents On The Extractive Removal And Properties Of Oil Palm Empty-Fruit Bunch Cellulosic Nanofibers, Achmad Solikhin, Yusuf Sudo Hadi, Muh Yusram Massijaya, Siti Nikmatin
Effects Of Different Extraction Solvents On The Extractive Removal And Properties Of Oil Palm Empty-Fruit Bunch Cellulosic Nanofibers, Achmad Solikhin, Yusuf Sudo Hadi, Muh Yusram Massijaya, Siti Nikmatin
Makara Journal of Science
In this study, the effect of different extraction solvents on the isolation and properties of cellulosic nanofibers (CNFs) were investigated. The unextracted and different solvent-extracted CNFs formed horn-like features and irregularly aggregated nanofibers after oven drying. Scanning electron microscopy at 10000× magnification revealed the smooth external surfaces of all extracted CNFs; this finding is attributed to the limited deposition of amorphous lignocellulosic components on the fibers. All resultant CNF solutions revealed aggregation, with a particle size distribution and zeta average of 21.39–513.00 nm and 162.26–342.13 nm, respectively. Extraction with different solvents and chemical treatment yielded CNF solutions with good transparency. …
Microfluidic Paper-Based Analytical Device (Μpad) For Determining Hydroquinone In Facial Whitening Cream Using Phloroglucinol Reagent, Hermin Sulistyarti, Paradhita Ayu Puspitaloka, Boyfannie Ivan Putra, Rurini Retnowati, Herman Tolle
Microfluidic Paper-Based Analytical Device (Μpad) For Determining Hydroquinone In Facial Whitening Cream Using Phloroglucinol Reagent, Hermin Sulistyarti, Paradhita Ayu Puspitaloka, Boyfannie Ivan Putra, Rurini Retnowati, Herman Tolle
Makara Journal of Science
A microfluidic paper-based analytical device (µPAD) is developed in this work to analyze hydroquinone in facial whitening creams using phloroglucinol. The µPAD features a hydrophobic barrier for detection and was fabricated using a wax printer with Whatman chromatographic paper. Detection was achieved by colorimetry based on the formation of an orange hydroquinone–phloroglucinol complex. The colored reaction product formed on the detection zone of the µPAD was scanned, and the images obtained were processed with Image-J software to determine their color intensity (RGB value). Optimization of the process conditions was conducted to achieve sensitive measurements. The optimum conditions yielding maximum sensitivity …
Elimination Of Gas And Particulate Emissions In Coal Boilers Using Plasma Precipitator System, Silvy Djayanti, Alex Lukmanto Suherman
Elimination Of Gas And Particulate Emissions In Coal Boilers Using Plasma Precipitator System, Silvy Djayanti, Alex Lukmanto Suherman
Makara Journal of Science
A plasma precipitator reactor is an essential part of the emission treatment. This device removes fine particles, such as dust, smoke, and various toxic gases, using the force of an induced plasma charge, minimally impeding the flow of gases through the unit. In this study, the plasma precipitator combines dust deposition-capture technology by magnetic force and emission gas removal with plasma. The reactor was successfully fabricated and tested in real-world applications of the textile industry to reduce gas and particulate emissions. Using this reactor, SO2, NO2, CO, and CO2 sulfur dioxide (SO2), nitrogen …