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Karbala International Journal of Modern Science

Journal

2021

Desulfurization of diesel fuel; solvent extraction

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Full-Text Articles in Chemistry

Novel Phenolic Deep Eutectic Solvents For Desulfurisation Of Petrodiesel, Idrees Bakr Qader, Jalil H. Kareem, Hani K. Ismail, Hawbash K. Mahmood Mar 2021

Novel Phenolic Deep Eutectic Solvents For Desulfurisation Of Petrodiesel, Idrees Bakr Qader, Jalil H. Kareem, Hani K. Ismail, Hawbash K. Mahmood

Karbala International Journal of Modern Science

In this work, a novel production of “deep eutectic solvents (DESs)” has been utilised for the elimination of sulfur composition, particularly from crude oil by liquid-liquid extraction. Herein, we present the first demonstration of the use of novel DESs formed by phenol, catechol, resorcinol and o-cresol as “hydrogen bond donors (HBDs)” with trimethyl hydroxyammonium chloride (ChCl) as the hydrogen bond acceptor to affect the efficient separation of organosulfur compounds from diesel. These DES electrolytes have been applied for the sulfur extraction from Iraqi real diesel fuel as determined using X-ray florescence sulfur measurements. The optimisation condition factors in this research …