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Journal of Electrochemistry

2002

Cyclic voltammetry

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Full-Text Articles in Chemistry

Electrochemical Behaviors Of Vanadium (V) Compounds In H_2so_4 Solution, Yang Liu, Hong Tao Liu, Xi Xia Feb 2002

Electrochemical Behaviors Of Vanadium (V) Compounds In H_2so_4 Solution, Yang Liu, Hong Tao Liu, Xi Xia

Journal of Electrochemistry

The electrochemical behaviors of vanadium(V) compounds(NH 4VO 3 and V 2O 5) in H 2SO 4 solutions were investigated by cyclic voltammetry (CV) and rotation ring disk electrode (RRDE) techniques. There were three anodic peaks and three cathodic peaks appeared on the CV plots at inert Pt electrode. But compared with the V 2O 5, the CV plot of NH 4VO 3 had one more anodic peak. There also appeared four anodic peaks at RRDE plots. We carefully analyzed these peaks and made some reasonable initial explaination.


Further Evidence For Surface Properties Of Porous Silicon Resulting In Electroluminescence, Zhan-Jun Zhang, Bin Wu, Jing-Jian Li, Zhong-Fan Liu, Sheng-Min Cai Feb 2002

Further Evidence For Surface Properties Of Porous Silicon Resulting In Electroluminescence, Zhan-Jun Zhang, Bin Wu, Jing-Jian Li, Zhong-Fan Liu, Sheng-Min Cai

Journal of Electrochemistry

The electroluminescence of porous silicon in solutions at positive biases was investigated by luminescence spectrometer. The electroluminescence of porous silicon in solutions mainly depended on its surface properties. The elelctroluminescence was much enhanced when the sample of porous silicon was electrolyzed once again which had undergone an electroluminescence test. The tests of both cyclic voltammetry and the luminescence of the sample of porous silicon prepared by repeated electrolysis provided further evidence that the electroluminescence of porous silicon in solutions at positive biases stemmed from the oxidation of Si_H on the surface of porous silicon. The voltage tunable emitting for porous …