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Multinuclear Solid-State Nuclear Magnetic Resonance Spectroscopy Of Microporous Materials, Jun Xu
Multinuclear Solid-State Nuclear Magnetic Resonance Spectroscopy Of Microporous Materials, Jun Xu
Electronic Thesis and Dissertation Repository
Microporous materials have attracted tremendous attention since 18th century due to their industrial importance. It is essential to understand the relationships between the properties of microporous materials and their structures. However, the structures of many microporous materials are determined from the more limited powder X-ray diffraction (XRD) data due to the lack of suitable single-crystals for XRD. In such cases, an unambiguous structure solution of microporous materials requires additional information from other techniques such as solid-state NMR (SSNMR) spectroscopy. This thesis is focused on the study of two types of microporous materials, metal–organic frameworks (MOFs) and titanosilicates, by multinuclear …