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Full-Text Articles in Chemistry
Deuteron Nuclear Magnetic Resonance Studies Of Molecular Motion In Solids, Tak Yan Tse
Deuteron Nuclear Magnetic Resonance Studies Of Molecular Motion In Solids, Tak Yan Tse
Dissertations, Theses, and Masters Projects
$\sp2$H-NMR is a powerful spectroscopic technique for investigating dynamics in solids. to extend the range of motional rates that can be quantitatively investigated, a new approach for measuring the quadrupolar spin-lattice relaxation time $T\sb{1Q}$ was developed. This uses a Broadband Jeener-Broekaert (BBJB) sequence with echo-detection, which avoids the frequency-discriminated excitation profile and spectral baseline distortion intrinsic to the conventional Jeener-Broekaert (JB) experiment. By combining the BBJB experiment with an Inversion-Recovery sequence with Quadrupole-Echo detection (IRQE), two independent longitudinal relaxation times, $T\sb{1Q}$ and $T\sb{1Z}$, can be measured. Spectral densities of motion $J\sb1(\omega\sb{o}$) and $J\sb2(2\omega\sb{o}$) are extracted from these relaxation times. The …
Characterization And Modeling Of Amino Epoxide Resins, Maria Anastasia Argiriadi
Characterization And Modeling Of Amino Epoxide Resins, Maria Anastasia Argiriadi
Dissertations, Theses, and Masters Projects
No abstract provided.
Physical And Mechanical Behavior Of Amorphous Poly(Arylene Ether-Co-Imidazole)S And Poly(Arylene Ether-Co-Imidazole) Modified Epoxies, Patricia D. Roberts-Mcdaniel
Physical And Mechanical Behavior Of Amorphous Poly(Arylene Ether-Co-Imidazole)S And Poly(Arylene Ether-Co-Imidazole) Modified Epoxies, Patricia D. Roberts-Mcdaniel
Dissertations, Theses, and Masters Projects
Due to the high crosslink density of cured epoxy resins they generally lack damage tolerance. A significant amount of research has been expended to improve the toughness of epoxies. Research into the area of thermoplastic epoxy modifiers has begun to overcome some of the limitations of early methods of epoxy toughening (i.e. lower modulus and thermal stability).;This study examines the physical and mechanical properties of random poly(arylene ether-co-imidazole) (PAE-co-Is) and the characterization of epoxies modified with poly(arylene ether-co-imidazole)s.;Poly(arylene ether-co-imidazole)s exhibited the highest solubility in N,N,N{dollar}\rm\sp\prime,N\sp\prime,{dollar}-tetraglycidyl- 4,4{dollar}\sp\prime{dollar} diaminodiphenyl methane (TGMDA) based resins. The high molecular weight polymers caused significant decreases in …
Correlation Between Electron Capture Negative Chemical Ionization Mass Spectrometric Fragmentation And Calculated Internal Energies For Polychlorinated Biphenyls, John Greaves, Ellen Harvey, William G. Macintyre
Correlation Between Electron Capture Negative Chemical Ionization Mass Spectrometric Fragmentation And Calculated Internal Energies For Polychlorinated Biphenyls, John Greaves, Ellen Harvey, William G. Macintyre
VIMS Articles
Correlations between molecular structure and fragmentation observed in electron capture negative chemical ionization mass spectra (moderator gas = methane) of 49 selected tetrachlorinated, pentachlorinated, and hexachlorinated biphenyls have been investigated by using molecular modeling. The semiempirical general molecular orbital program MOPAC was used to calculate molecular properties for biphenyl and the 209 polychlorinated biphenyls. The mass spectrometric ionization and fragmentation processes were found to be linked to the number of chlorine atoms present on the biphenyl, and to the number of those chlorine atoms in the ortho (2, 2', 6, and 6') positions. The intensity of molecular ions increased with …
The Synthesis Of 5-Benzoyl-1,3-Benzendediacids For The Double-Capping Of Beta-Cyclodextrin, Daniel Macdougall Williams
The Synthesis Of 5-Benzoyl-1,3-Benzendediacids For The Double-Capping Of Beta-Cyclodextrin, Daniel Macdougall Williams
Dissertations, Theses, and Masters Projects
No abstract provided.
Direct Determination Of Trace Metals In Saline Water Samples Using Gfaas, Michael Joseph Wassell
Direct Determination Of Trace Metals In Saline Water Samples Using Gfaas, Michael Joseph Wassell
Dissertations, Theses, and Masters Projects
No abstract provided.
The Requirements Of Patentability As Applied To The Chemical Arts, Joy L. Bryant
The Requirements Of Patentability As Applied To The Chemical Arts, Joy L. Bryant
Dissertations, Theses, and Masters Projects
No abstract provided.