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Full-Text Articles in Chemistry
Azidotetrakis(Trimethylphosphine)Nickel(Ii) Tetrafluoroborate, Caryn C. Carson, Robert D. Pike
Azidotetrakis(Trimethylphosphine)Nickel(Ii) Tetrafluoroborate, Caryn C. Carson, Robert D. Pike
Arts & Sciences Articles
The title complex, [Ni(N3)(C3H9P)4]BF4, is a nearly perfect trigonal bipyramid with the azide group at an apical position. The metal-azide bond angle, Nil-- NlmN2, of 138.6(5) ° is the largest observed for a terminal azide ligand.