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Nanojars: Versatile Platform For Pyrazole Synthesis And Chemistry, And Selective Extraction Of Anions, Basil Mohammed Ahmed
Nanojars: Versatile Platform For Pyrazole Synthesis And Chemistry, And Selective Extraction Of Anions, Basil Mohammed Ahmed
Dissertations
This work is centered around nanojars, a family of nano-sized anion-incarcerating agents. It addresses various aspects of nanojar chemistry, such as synthesis strategies (including green methodologies) for pyrazole ligands needed for the preparation of nanojars, characterization and study of the mechanism of assembly of nanojars, and selective extraction of anions from water using nanojars.
Nanojars are neutral, supramolecular coordination complexes of the general formula [anion⊂ {Cu(μ-OH)(μ-pz)}n], formed by the reaction of Cu2+, HO‒ and pyrazolate ions (C3H2N2‒, pz‒) in the presence of oxoanions with large hydration energy …