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Gas Phase Clustering Of N2 Molecules On To Tio+: Comparison With Ti+ And Evidence For The Octahedral Structure Of Tio+(N2)5, George M. Daly, M. Samy El-Shall
Gas Phase Clustering Of N2 Molecules On To Tio+: Comparison With Ti+ And Evidence For The Octahedral Structure Of Tio+(N2)5, George M. Daly, M. Samy El-Shall
Chemistry Publications
A striking difference in the clustering efficiency of Ti+ and TiO+ toward N2 or O2 has been observed in a laser vaporizationhigh pressure mass spectrometric source. Evidence for the magic number n=5 within the sequence TiO+(N2) n is presented. The results are consistent with an octahedral structure for TiO+(N2)5.