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Full-Text Articles in Chemistry
Use Of High-Energy Radiation For Degradation Of Environmental Pollutants, Robert D. Guthrie, Manjiri Patwardhan
Use Of High-Energy Radiation For Degradation Of Environmental Pollutants, Robert D. Guthrie, Manjiri Patwardhan
KWRRI Research Reports
The purpose of this project was to explore the advantages and/or limitations of high-energy radiation treatment as a method for degrading organic pollutants, particularly aryl halides, in an aqueous medium. We have done analyses of 60Co-irradiated samples and kinetic studies using pulsed electron beams. For aryl halides containing no more than two fused rings, the main products detected are those of simple halogen replacement by hydrogen, although the amount of aryl halide destroyed was always greater than the total amount of products detected. To accomplish halogen replacement by H, the reaction solvent may not be pure water but must …
Development Of Membrane Film Fiber Optic Based Sensors For The Remote Monitoring Of The Quality Of Surface And Groundwater, Leonidas G. Bachas
Development Of Membrane Film Fiber Optic Based Sensors For The Remote Monitoring Of The Quality Of Surface And Groundwater, Leonidas G. Bachas
KWRRI Research Reports
The objective of this study was the development of chromo- and fluoroionophores and their subsequent use in sensors capable of surface and groundwater monitoring. Several reagents (modified crown ethers and porphyrins) were synthesized based on principles of chemical recognition and used for metal and pH sensing. The modified crown ether reagents include a chromogenic or fluorogenic group. The selectivity of these reagents is controlled by the size of the crown ether ring and the type of the chromogenic or fluorogenic side-arm. In addition, a fluorogenic crown ether was synthesized that incorporates a fluorogenic side-arm and a perfluorinated carbon chain. The …