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Full-Text Articles in Chemistry

Design Of Stormwater Bmps For Surface And Groundwater Protection Based On Site-Scale Soil Properties: Phase I, Kelly Kibler, Lisa Chambers, Melanie Beazley Aug 2023

Design Of Stormwater Bmps For Surface And Groundwater Protection Based On Site-Scale Soil Properties: Phase I, Kelly Kibler, Lisa Chambers, Melanie Beazley

Florida DOT

Much of Earth’s nutrient cycling takes place in soils. Characteristics of soils control physical, chemical, and biological processes that determine rates of nutrient fluxes, storage, or transformation. As remediation of excess nutrients in stormwater runoff is one function of stormwater Best Management Practices (BMPs), the soil profile constitutes one of the most important factors of BMP design. Variation observed in BMP effectiveness (e.g., why one BMP design works effectively in one place and not another) can often be explained by variations in the soil profile, either through direct means or by a soil’s influence on hydraulics of stormwater flow through …


Photoluminescence Properties Of Polycyclic Aromatic Sulfur Heterocycles And Their Sorption And Desorption Onto Microplastics., Sadia Arif Jan 2021

Photoluminescence Properties Of Polycyclic Aromatic Sulfur Heterocycles And Their Sorption And Desorption Onto Microplastics., Sadia Arif

Electronic Theses and Dissertations, 2020-

Polycyclic aromatic sulfur heterocycles (PASHs) are sulfur analogues of polycyclic aromatic hydrocarbons (PAHs) commonly found in environmental samples exposed to oil contamination. The determination of PASHs in complex samples is far more difficult than PAHs because of the sulfur atom in the heterocyclic ring, which increases the total number of possible isomeric compounds. Since their toxicological properties vary considerably from isomer to isomer, the unambiguous determination of specific isomers in environmental samples is crucial for ecotoxicological purposes and human safety. GC-MS has been the primary analytical technique for the determination of PASHs in environmental samples. Unfortunately, as the number of …


Seaweed As A Carrier For Microplastics, Stephanie M. Rodriguez Jan 2020

Seaweed As A Carrier For Microplastics, Stephanie M. Rodriguez

Honors Undergraduate Theses

Analysis of seaweed as a vector for microplastics is an integral part of understanding the formation and deposition of micro-sized plastic waste in seawater. The project itself originated due to the influx of seaweed (and mismanaged plastic waste) residing on the shores of St. Kitts and Nevis and the constant deposition of plastic pollution intertwined within the seaweed. The natural occurrence of the two together lead to the consideration of fragmented plastics remaining on the seaweed. The objective of this research is to stain, identify, and quantify the concentration of microplastics sourced from both store-bought and environmental seaweed samples. A …


In Situ Cultivation Of Potential Pah Degrading Bacteria From Coastal Sediment, Kyle Benkel Jan 2020

In Situ Cultivation Of Potential Pah Degrading Bacteria From Coastal Sediment, Kyle Benkel

Honors Undergraduate Theses

Oil spills can introduce potentially carcinogenic pollutants, such as polycyclic aromatic hydrocarbons (PAHs), into coastal environments. Bioremediation uses the natural microorganisms in the environment to remove these pollutants. Traditional studies of these organisms are limited in the types of bacteria isolated due to the limitations of traditional culturing methods. In this study, diffusion chambers were used to culture and isolate potential PAH degrading bacteria from the coastal sediment obtained from the Chandeleur Islands. The diffusion chambers trapped bacteria in agar that contained 1 ppm benzo[a]pyrene. The bacteria were isolated from the diffusion chambers, and the 16S rRNA gene was sequenced …


A Model Experiment To Investigate The Possibility Of Glyphosate Contamination In St. Kitts And Nevis, Winston Fu Jan 2020

A Model Experiment To Investigate The Possibility Of Glyphosate Contamination In St. Kitts And Nevis, Winston Fu

Honors Undergraduate Theses

Glyphosate is a broad-spectrum herbicide that is used globally to combat the spread of weeds among crops. Not all countries around the world have been using the herbicide. For example, island countries such as Dominica and St. Kitts and Nevis do not use the herbicide on their crops. However, St. Kitts and Nevis imports food and other agricultural products from around the world, leading to the hypothesis that glyphosate is contaminating the soil through those imported products. The aim of this research project was to determine if glyphosate is present in the island country of St. Kitts and Nevis. A …


Time-Resolved Phosphorescence Spectroscopy At Cryogenic Temperatures For The Environmental Analysis Of Polycyclic Aromatic Sulfur Heterocycles In Oil Contaminated Sites., Maha Al-Tameemi Jan 2017

Time-Resolved Phosphorescence Spectroscopy At Cryogenic Temperatures For The Environmental Analysis Of Polycyclic Aromatic Sulfur Heterocycles In Oil Contaminated Sites., Maha Al-Tameemi

Electronic Theses and Dissertations

The large volume of crude oil released into the Gulf of Mexico by the Deepwater Horizon (DWH) accident has raised considerable concerns over potential ecosystem impacts. The dispersion of harmful oil components into the ocean waters could pose long term risks to flora and fauna. Due to the complexity of oil contaminated sites, the unambiguous identification and quantitation of environmental pollutants often requires the sequence of high-performance liquid chromatography (HPLC) and gas chromatography-mass spectrometry (GC-MS). A classic example is the analysis of the sixteen polycyclic aromatic hydrocarbons included in the priority pollutants list of the U.S. Environmental Protection Agency (EPA-PAHs). …