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Full-Text Articles in Chemistry
A Family Of Cyclooctatetraenyl Lanthanide(Iii) Chloridebridged Dimers : Synthesis, Characterization, And Magnetic Properties, Joshua Sky Greenough
A Family Of Cyclooctatetraenyl Lanthanide(Iii) Chloridebridged Dimers : Synthesis, Characterization, And Magnetic Properties, Joshua Sky Greenough
Legacy Theses & Dissertations (2009 - 2024)
Historically, the 10π-aromatic ligand, cyclooctatetraene (COT), has played a pivotal role
Chemical Reduction Of Polycyclic Aromatic Ligands With Heavy Group 2 Metals, Andrew Robert Uresk
Chemical Reduction Of Polycyclic Aromatic Ligands With Heavy Group 2 Metals, Andrew Robert Uresk
Legacy Theses & Dissertations (2009 - 2024)
The chemistry of the alkaline earth metals has received a renewed interest in the last decades. The lighter Group 2 metal, magnesium, has gathered the most attention, as it is a key component of Grignard reagents, while the heavier metals have been less studied. The early alkaline earth metals are known to exhibit some similarity with both the alkali and lanthanide metals in π-complexation reactions with planar aromatic hydrocarbons (PAHs). However, the products of heavier Group 2 elements such as strontium and barium were found to be more difficult to synthesize and isolate, thus requiring the development of new synthetic …