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Union College

Theses/Dissertations

1953

Articles 1 - 9 of 9

Full-Text Articles in Chemistry

The Catalytic Power Of Portland Cement Gels, Constantine Aloysius Neugebauer Jun 1953

The Catalytic Power Of Portland Cement Gels, Constantine Aloysius Neugebauer

Honors Theses

For several years research has been done at Union College investigating the possibility of using Portland Cement as a chemical raw material. Investigations by Clark in 1951 indicated that vigorous reactions take place when Portland cement and strong acids are mixed.


Studies On "Ludox" Silica Sol, Edward Francis Weyand Jun 1953

Studies On "Ludox" Silica Sol, Edward Francis Weyand

Honors Theses

The work presented in this paper is an extension of the work done by Petrucci in 1950. Here we wish to consider the process of gelation of Ludox by measuring the change in surface tension during gelation and also the possibility of treating BiO2-H2O-alcohol systems on a triangular phase diagram.


A Study Of Gel Formation With Sodium Methyl Siliconate, Alan Robert Winterberger Jun 1953

A Study Of Gel Formation With Sodium Methyl Siliconate, Alan Robert Winterberger

Honors Theses

This study of sodium methyl siliconate is the first done with this compound at Union College. It was believed that gels could be produced with sodium methyl siliconate and the object of this work was to verify the assumption. After the gels were obtained, they were to be investigated in the same way as many previous workers have done with sodium silicate.


Ultraviolet Spectrophotometric Determination Of Metals With Thiocarbanilide, John Jeremiah Gritmon Jun 1953

Ultraviolet Spectrophotometric Determination Of Metals With Thiocarbanilide, John Jeremiah Gritmon

Honors Theses

The ultraviolet absorption spectra of thiocarbanilide (diphenylthiourea) were determined in aqueous solutions of varying acidity. A correlation between the absorption spectra and data obtained has been attempted.


Szilard-Chalmers Reactions, Anita Camilli Mewherter Jun 1953

Szilard-Chalmers Reactions, Anita Camilli Mewherter

Honors Theses

Since discovery of radioactivity at the turn of the century, the use of radioactive isotopes has become increasingly significant to research in the fields of chemistry, biology, botany, and medicine. An important use of these radioactive isotopes is the tracer or indicator method. For example, a portion of radioactive potassium may be added to a sample of of stable potassium to be studied. The fact that a given isotope is radioactive does not, in most cases, affect its chemical properties. The presence of the active isotope allows the potassium now to be followed through a chemical or biological process. This …


The Catalytic Vapor Phase Alklation Of Phenol, Robert Andrew Clendinning Jun 1953

The Catalytic Vapor Phase Alklation Of Phenol, Robert Andrew Clendinning

Honors Theses

The purpose of this research is to study the reaction between ethyl alcohol and phenol over a chemically activated alumina catalyst at several temperatures. The reaction of phenol and ethyl alcohol is also studied over the support used in preparing the activated catalyst to determine the catalytic activity of the support. An attempt is also made to correlate the data obtained by previous workers at Union College, who have studied the reaction between phenol and methyl alcohol and the reaction between phenol and ethyl alcohol.


A Study Of The Oxidation Stability Of Lubricating Oils, Frank Albert Pepe Jun 1953

A Study Of The Oxidation Stability Of Lubricating Oils, Frank Albert Pepe

Honors Theses

This past year, research work was done on the oxidation of lubricating oils. Since this is the first year that this research project has been carried out, our work was mainly directed towards finding ways of attacking the study of the oxidation of lubricating oils. We have found a few paths which warrant further investigations.


A Study Of The Thallium Dithizone Complex Using Radioactive Tracer Techniques, Ferdinand J. Schuette Jun 1953

A Study Of The Thallium Dithizone Complex Using Radioactive Tracer Techniques, Ferdinand J. Schuette

Honors Theses

In the present work, use has been made of a radioactive isotope of thallium as a tracer in the study of the thallium dithizone complex.


Reactions In The Synthesis Of Indazole, John Earl Sigsby Jr. Jun 1953

Reactions In The Synthesis Of Indazole, John Earl Sigsby Jr.

Honors Theses

This work was undertaken in order to study the reactions that lead to the formation of Indazole. There are many possible variations that effect the final product. Some of them are studied here, such as the effect of heat upon the initial reaction, change of solvent, and the decomposition of the nitroso intermediate.