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Full-Text Articles in Chemistry

Development Of Quantitative Methods To Study Pfas Using Proton Induced Gamma-Ray Emission, Colin Langton Jun 2022

Development Of Quantitative Methods To Study Pfas Using Proton Induced Gamma-Ray Emission, Colin Langton

Honors Theses

Per- and polyfluoroalkyl substances (PFAS) are man-made chemicals that have become a major environmental concern. They can be found in a broad range of everyday products and pose a significant risk to the public due to their adverse health effects. They are persistent, bioaccumulate and do not break down in the environment. This project specifically aims to determine the concentration of Fluorine, a key identifier of PFAS, in environmental samples. To do this, we employ proton induced gamma-ray emission (PIGE) to screen for Fluorine within our samples. PIGE is performed at the Union College Ion Beam Analysis Laboratory using a …


Development Of Catalytic Chromia-Based Aerogels, Fiona Fitzgerald Jun 2020

Development Of Catalytic Chromia-Based Aerogels, Fiona Fitzgerald

Honors Theses

Over one billion automobiles are in use around the world, the majority of which employ internal combustion engines. Catalytic converters are used to convert the toxic compounds found in car exhaust -- carbon monoxide, nitrogen oxides (NOx) and hydrocarbons -- to less harmful gases. The typical catalytic converter employs as catalysts expensive raw materials (platinum, palladium and/or rhodium) wash-coated onto an alumina-based ceramic substrate. Aerogel materials have high surface area and thermal stability, properties that make them attractive for catalysis applications. Aerogels made with transition metal oxides are candidates to replace platinum in the catalytic converter. Chromium oxide (chromia) materials …


Synthesis And Characterization Of Organically Modified Hectorites For Sequestration Of Pfaas From Contaminated Drinking Water, Alexandra Pagano Jun 2018

Synthesis And Characterization Of Organically Modified Hectorites For Sequestration Of Pfaas From Contaminated Drinking Water, Alexandra Pagano

Honors Theses

Perfluoroalkyl Acids (PFAAs), a family of industrial chemicals, are found in household products such as pizza boxes, microwave popcorn bags, and non-stick pans. PFAAs of different carbon chain lengths and ionic head groups exist, such as PFOA (perfluorooctanoic acid) and PFOS (perfluorooctane sulfonic acid). Used without regulation in industry for decades, PFAAs only recently became recognized as contaminants of emerging concern, since they are bioaccumulative in organisms, persistent in the environment, and toxic. PFAAs are known to accumulate in the blood, liver and kidneys, and drinking water contaminated with PFAAs has been linked to certain types of cancer. Therefore, it …