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Full-Text Articles in Chemistry
Thermolysis Of Semicarbazones To The Corresponding Azines Through Reactive N-Substituted Isocyanate Intermediates, Shailesh N. Shah, N.K. Chudgar
Thermolysis Of Semicarbazones To The Corresponding Azines Through Reactive N-Substituted Isocyanate Intermediates, Shailesh N. Shah, N.K. Chudgar
Faculty Publications
Thermolysis of semicarbazones (I) to azines (II) occurs through reactive N-substituted isocyanate intermediates (Ia) which can be converted in situ to carbamates and N-substituted ureas.
Effect Of Interfacial Tension On Propagating Polymerization Fronts, R. Texier-Picard, John A. Pojman, Vitaly Volpert
Effect Of Interfacial Tension On Propagating Polymerization Fronts, R. Texier-Picard, John A. Pojman, Vitaly Volpert
Faculty Publications
This paper is devoted to the investigation of polymerization fronts converting a liquid monomer into a liquid polymer. We assume that the monomer and the polymer are immiscible and study the influence of the interfacial tension on the front stability. The mathematical model consists of the reaction-diffusion equations coupled with the Navier-Stokes equations through the convection terms. The jump conditions at the interface take into account the interfacial tension. Simple physical arguments show that the same temperature distribution could not lead to Marangoni instability for a nonreacting system. We fulfill a linear stability analysis and show that interaction of the …
Trimethyl(Trifluorovinyl)Silane, Roxana M. Trifu, George L. Gould
Trimethyl(Trifluorovinyl)Silane, Roxana M. Trifu, George L. Gould
Faculty Publications
No abstract provided.