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Full-Text Articles in Chemistry

Space-Group Revision For 4-Formylphenylboronic Acid, Frank R. Fronczek, Nadia N. St Luce, Robert M. Strongin Dec 2001

Space-Group Revision For 4-Formylphenylboronic Acid, Frank R. Fronczek, Nadia N. St Luce, Robert M. Strongin

Chemistry Faculty Publications and Presentations

The space group of the title compound, C7H7BO3, previously reported to be P, is properly Cc. There is no disorder of the formyl group or in the H atoms of the B(OH)2 group. Molecules lie on approximate twofold axes and are related by approximate centers, which relate all but the formyl O atom and boronic acid H atoms. The B-O distances are 1.363 (2) and 1.370 (2) Å.


Trimethylsulfonium Methanesulfonate, Frank R. Fronczek, Rolanda J. Johnson, Robert M. Strongin May 2001

Trimethylsulfonium Methanesulfonate, Frank R. Fronczek, Rolanda J. Johnson, Robert M. Strongin

Chemistry Faculty Publications and Presentations

In the title compound, C3H9S+.CH3O3S-, a thermal decomposition product of dimethyl sulfoxide, both cation and anion lie on mirror planes. In the cation, the S atom lies 0.792 (2) Å out of the plane defined by the three C atoms, with S-C distances of 1.781 (2) and 1.786 (3) Å. In the anion, the S-O distances are 1.4556 (14) and 1.4646 (19) Å, and the S-C distance is 1.759 (3) Å.