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Chemical And Electrochemical Studies Of Cl2Fes2Ms2Fecl2N- Clusters [M = Mo (N = 2), W (N = 2), V (N = 3)], Yanming Liu, Jinhai Chen, Michael D. Ryan

Chemistry Faculty Research and Publications

The electrochemistry and spectroelectrochemistry of [Cl₂FeS₂MS₂FeCl₂]^n- clusters (where n = 2 for M = Mo and W and n = 3 for M = V; Ia, Ib, and Ic, respectively) and the dimetal complex [Cl₂FeS₂MoS₂]^2- (IIIa) were examined in order to characterize the structures and properties of the one-electron-reduced complexes. A stable reduction product for Ia was observed spectroelectrochemically at −1.05 V, which could be oxidized back to the starting complex. Reduction at more negative potentials caused …