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Articles 1 - 4 of 4
Full-Text Articles in Chemistry
The Legacy Of Mining In Southwest Missouri: Past And Present Conditions Of The Tri-State Mining District, Anastasia M C Mcclanahan
The Legacy Of Mining In Southwest Missouri: Past And Present Conditions Of The Tri-State Mining District, Anastasia M C Mcclanahan
MSU Graduate Theses
The historic Tri-State Mining District (TSMD) of southwestern Missouri, southeastern Kansas, and northeastern Oklahoma has a history of lead and zinc mining that extended over a hundred years. During the district’s peak production period, the TSMD was one of the world’s largest producers of lead and zinc. The mining activities in the TSMD produced economic growth that supported the local communities and were essential to the victory of the Allied Forces during World War I and World War II. Beginning in the 1920s, the mining activities in the district slowly began to cease due to depletion of metal ores and …
An In-Situ Study Of The Aqueous Speciation Of Uranium (Vi) Under Hydrothermal Conditions, Diwash Dhakal
An In-Situ Study Of The Aqueous Speciation Of Uranium (Vi) Under Hydrothermal Conditions, Diwash Dhakal
MSU Graduate Theses
Rigorous study of the speciation distribution of uranyl-chloride bearing solutions under hydrothermal conditions is important to understand the transport mechanism of uranium underground, which is of uttermost interest to parties studying the geological uranium deposits and those studying the possibilities of geological repositories for spent nuclear waste. I report an in-situ Raman spectroscopic study of the speciation distribution of aqueous uranyl-chloride complexes upto 500°C conducted using a HDAC as the high PT spectroscopic cell. The samples studied contained the species UO22+, UO2Cl+, UO2Cl20 and UO2Cl3- …
Diamond Intracrystalline Stable Isotope Chemical Image Analysis By Time-Of-Flight Secondary Ionization Mass Spectrometery, Tyler J. Sundell
Diamond Intracrystalline Stable Isotope Chemical Image Analysis By Time-Of-Flight Secondary Ionization Mass Spectrometery, Tyler J. Sundell
MSU Graduate Theses
The chemical resistance of diamond allows in-situ study of the diamond source regions. For a majority of gem quality diamonds, this source region is the sublithospheric mantle keel of a cratonic nuclei. Through analysis of stable isotopes, radiogenic isotopes and trace elements, diamond geochemical analyses can define chemical fluxes in the mantle keel. However, such studies require multiple methodologies for each chemical suite, high spatial resolution and analytical precision. Here, I evaluate Time-of-Flight Secondary Ionization Mass Spectrometer (ToF-SIMS) as an alternative method for diamond geochemical analyses. ToF-SIMS analysis can perform in cation and anion mode to measure the entire periodic …
Channel Bar Morphology, Distribution, And Mining-Related Geochemistry In The Big River, St. Francois County, Missouri: Implications For Geomorphic Recovery, Lindsay Marie Olson
Channel Bar Morphology, Distribution, And Mining-Related Geochemistry In The Big River, St. Francois County, Missouri: Implications For Geomorphic Recovery, Lindsay Marie Olson
MSU Graduate Theses
Tailings releases associated with large-scale historical Pb mining in St. Francois County, Missouri resulted in system-wide contamination of Pb and excess sediment in the Big River. Previous studies have addressed basin and segment scale variability of the contaminants; however, little is known about reach and bar scale variability. This study addresses how mining sediment inputs influence bar form and geochemistry across a range of scales. Bar sediment samples were collected at 21 reaches and analyzed for particle size and geochemistry, while air photo analysis was used to evaluate channel morphology, bar type, and area. Bar area is initially low in …