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Synthesis And Characterization Of A Copper(I)-Phenyl Complex, Max Cushner, Thabiso Kunene May 2014

Synthesis And Characterization Of A Copper(I)-Phenyl Complex, Max Cushner, Thabiso Kunene

CLAS: Colby Liberal Arts Symposium

Compounds or complexes combining an organic species and a copper ion are amongst the most widely used organometallic reagents in synthetic organic chemistry. However, the chemistry for such organocopper compounds is underdeveloped including that for copper(I)-arene complexes, which are quite rare. Nonetheless, once the chemical properties of such copper-arene complexes are better understood, it will be easier to find uses for them, for instance as catalysts. Previous work on this project has produced evidence that copper(I)-arene complexes bearing phenyl and naphthyl groups behave differently from one another in arene replacement reactions. Thus, the phenyl does not seem to bind as …