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Articles 1 - 30 of 131
Full-Text Articles in Chemistry
Enhancing Urban Water Quality Through Biological-Chemical Treatment: Aquatic Macroinvertebrate Community And Temporal Chlorophyll-A Response, Matthew Chaffee
Enhancing Urban Water Quality Through Biological-Chemical Treatment: Aquatic Macroinvertebrate Community And Temporal Chlorophyll-A Response, Matthew Chaffee
Department of Biological Systems Engineering: Dissertations and Theses
With a growing human population, urbanization is impeding a plethora of natural waterways. Of these, urban ponds play a vital role in nutrient sequestration, flood prevention, and habitat sanctuaries. However, nutrient loading can reduce habitat effectiveness and promote harmful algae blooms. To reduce internal nutrient loads, a biological-chemical treatment strategy consisting of floating treatment wetlands (FTWs) and lanthanum were applied to two urban retention ponds, Densmore and Wilderness Ridge Ponds. To measure effectiveness, chlorophyll-a samples were collected and correlated with Sentinel-2. A novel band algorithm termed 3BR1 produced a strong correlation (R2 = 0.72) to physical chlorophyll-a …
Speciation Of Elements Via A Sequential Extraction Procedure In Municipal Wastewater Biosolids From Three Rural Wwtp In East Texas (Usa), Kefa K. Onchoke
Speciation Of Elements Via A Sequential Extraction Procedure In Municipal Wastewater Biosolids From Three Rural Wwtp In East Texas (Usa), Kefa K. Onchoke
Faculty Publications
In this data article, the bioavailability of elements in municipal wastewater sludge (also known as biosolids) in samples collected from three treatment plants in East Texas, USA was evaluated. Although detailed speciation of the metals were assessed by using inductively coupled plasma optical spectroscopy (ICP-OES), and were discussed in the research article titled “Evaluating bioavailability of elements in municipal wastewater sludge (Biosolids) from three rural wastewater treatment plants in East Texas (USA) by a sequential extraction procedure” [1], this report presents the absolute raw concentrations and fractionations of the 26 metals from the biosolids (Nacogdoches Wastewater Sludge, Lufkin Wastewater Sludge, …
Design Of Stormwater Bmps For Surface And Groundwater Protection Based On Site-Scale Soil Properties: Phase I, Kelly Kibler, Lisa Chambers, Melanie Beazley
Design Of Stormwater Bmps For Surface And Groundwater Protection Based On Site-Scale Soil Properties: Phase I, Kelly Kibler, Lisa Chambers, Melanie Beazley
Florida DOT
Much of Earth’s nutrient cycling takes place in soils. Characteristics of soils control physical, chemical, and biological processes that determine rates of nutrient fluxes, storage, or transformation. As remediation of excess nutrients in stormwater runoff is one function of stormwater Best Management Practices (BMPs), the soil profile constitutes one of the most important factors of BMP design. Variation observed in BMP effectiveness (e.g., why one BMP design works effectively in one place and not another) can often be explained by variations in the soil profile, either through direct means or by a soil’s influence on hydraulics of stormwater flow through …
Benthic Algal And Macroinvertebrate Response To The Removal Of Dreissenid Mussels In The Nearshore Zone Of Lake Michigan, Tyler Alexander Kunze
Benthic Algal And Macroinvertebrate Response To The Removal Of Dreissenid Mussels In The Nearshore Zone Of Lake Michigan, Tyler Alexander Kunze
Theses and Dissertations
Dreissenid mussels (Dreissena polymorpha and Dreissena rostriformis bugensis) have changed the fundamental community structure and biogeochemical processes of the Lake Michigan nearshore zone. There is evidence that dreissenids promote the nuisance growth of benthic algae, especially Cladophora sp. In addition, benthic macroinvertebrates have benefitted from the presence of dreissenid mussels due to the increased structural complexity along with greater nutrient availability in the benthos. These effects of the dreissenid mussel invasion are well documented; however, little is known about how these systems respond to the removal of dreissenid mussels from a once-populated area. Therefore, it is important to further our …
Cadmium And Salinity Stressor Antagonism On Vallisneria Neotropicalis, Christopher P. Mikolaitis
Cadmium And Salinity Stressor Antagonism On Vallisneria Neotropicalis, Christopher P. Mikolaitis
<strong> Theses and Dissertations </strong>
Submerged macrophytes form the foundation of freshwater ecosystems. These organisms are sessile and are very susceptible to shifts in their environment. Heavy metals are of particular concern as they can be sequestered indefinitely in sediments and are readily taken up by rooted vegetation. In the presence of saltwater intrusions, these metals can interact with salt ions potentially changing their availability to submerged vegetation. In this study a freshwater macrophyte, Vallisneria neotropicalis, was used as a test species for interactive effects between Cd, a non-essential heavy metal, and salt stress. The metrics used to establish the individual as well as …
Small Community Water Systems Have The Highest Prevalence Of Mn In Drinking Water In California, Usa, Miranda Aiken, Samantha C. Ying
Small Community Water Systems Have The Highest Prevalence Of Mn In Drinking Water In California, Usa, Miranda Aiken, Samantha C. Ying
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
Manganese (Mn) is currently regulated as a secondary contaminant in California, USA; however, recent revisions of the World Health Organization drinking water guidelines have increased regulatory attention of Mn in drinking water due to increasing reports of neurotoxic effects in infants and children. In this study, Mn concentrations reported to California’s Safe Drinking Water Information System were used to estimate the potentially exposed population within California based on system size. We estimate that between 2011 and 2021, over 525,000 users in areas with reported Mn data are potentially exposed to Mn concentrations exceeding the WHO health-based guideline (80 μg L …
How Akron Affects The Water Quality Of The Cuyahoga River, Allyson Darst
How Akron Affects The Water Quality Of The Cuyahoga River, Allyson Darst
Williams Honors College, Honors Research Projects
The purpose of this study was to analyze whether the city of Akron had negative effects on the Cuyahoga river, and determine if the Cuyahoga River was naturally able to remediate these effects downstream. The pollutants measured in this study include hardness, bromine, residual chlorine, iron, copper, lead, nitrate, nitrite, ammonium chloride, total chlorine, fluoride, carbonate, pH, total alkalinity and cyanuric acid. This study was done using water testing strips (JNW Direct) to test the water at four different locations along the Cuyahoga River downstream (North) of Akron. This study found that the city of Akron does have a negative …
Contrasting Seasonal Cycling Of Arsenic In A Series Of Subarctic Shield Lakes With Different Morphometric Properties, Jeremy Harbinson
Contrasting Seasonal Cycling Of Arsenic In A Series Of Subarctic Shield Lakes With Different Morphometric Properties, Jeremy Harbinson
Theses and Dissertations (Comprehensive)
The subarctic shield near Yellowknife, Northwest Territories (NWT), is populated with thousands of small lakes (<1.5 km2) and several large lakes. Historic mining activities in the region have left a legacy of environmental impacts and widespread arsenic (As) contamination in both aquatic and terrestrial environments. In particular, several small subarctic lakes near Yellowknife have been previously documented to be contaminated with high levels of As. Subarctic lakes are characterized by seasonal ice-cover that can persist for more than half of the year, yet little is known about the under-ice spatial and seasonal dynamics of As cycling. The objective of …1.5>
Development Of A Novel Ionic Liquid-Coated Adsorbent For Treating Emerging Contaminants In Recycled Water On The International Space Station, Madeline Carroll, Gabson Baguma, Savanna Vacek
Development Of A Novel Ionic Liquid-Coated Adsorbent For Treating Emerging Contaminants In Recycled Water On The International Space Station, Madeline Carroll, Gabson Baguma, Savanna Vacek
Undergraduate Research Symposium Posters
Synthesize at least 3 biobased ionic liquids. Optimize method for conducting liquid-liquid extractions. Analyze and quantify how much DMSO2 is removed by the ionic liquids. Coat biochar with the most effective biobased ionic liquids.
The Interaction Of Different Primary Producers And Physical And Chemical Dynamics Of An Urban Shallow Lake, Majid Sahin
The Interaction Of Different Primary Producers And Physical And Chemical Dynamics Of An Urban Shallow Lake, Majid Sahin
Dissertations, Theses, and Capstone Projects
An artificial urban shallow lake, Prospect Park Lake (PPL), is situated on a terminal moraine in Brooklyn New York, and supplied with municipal water treated with ortho-phosphates. The constant input of the phosphate nutrient is the primary source of eutrophication in the lake. The numerous pools along the water course houses various aquatic phototrophs, which influence the water quality and the state of the system, driving conditions into favoring the survival of their species. In the first half of the dissertation, the focus of the project is on analyzing how the different primary producers in different regions of PPL affect …
Low-Cost Adsorbent For Disinfection Byproduct Removal From Drinking Water, Savanna Vacek, Suraj Pochampally
Low-Cost Adsorbent For Disinfection Byproduct Removal From Drinking Water, Savanna Vacek, Suraj Pochampally
Undergraduate Research Symposium Posters
Disinfection byproducts (DBPs) are harmful contaminants that are unintentionally created in disinfected water after chlorination. Activated carbon, often expensive and difficult to acquire in low-income and rural areas, has previously been used to remove DBPs from drinking water. Biochar is made from agricultural waste (i.e. feedstock) and has been identified as a low-cost yet effective adsorbent to remote contaminants from drinking water. This work focuses on the efficacy of biochar and activated carbon to remove DBPs from drinking water for the purpose of treating drinking water after emergency chlorination. This study has the potential to help water distributors and disadvantaged …
Biochar Hydrophilicity Characterization By A Smartphone-Based Apparatus: Design, Construction, And Measurement Calibration, Emma Letourneau, Suraj Pochampally
Biochar Hydrophilicity Characterization By A Smartphone-Based Apparatus: Design, Construction, And Measurement Calibration, Emma Letourneau, Suraj Pochampally
Undergraduate Research Symposium Posters
Water contact angles are used to determine hydrophilicity, which is a material's attraction to water. A water contact angle of greater than 90 degrees indicates a hydrophobic material that repels water, whereas a contact angle of less than 90 degrees indicates a hydrophilic material [Fig. 1]. Water contact angles are measured through a goniometer, which can cost between $2000 to $10,000.
Biochar is a porous carbon material created from biological waste products, that is pyrolyzed (i.e. burned) in a low-oxygen, high heat environment. Biochar can be used to remove contaminants from water and remediate soil while reusing waste, making it …
Synthesis Of Modified Walnut Shell Biochar And Material Characterization In Ground Water Treatment, Maaike Parajes, Suraj Pochampally
Synthesis Of Modified Walnut Shell Biochar And Material Characterization In Ground Water Treatment, Maaike Parajes, Suraj Pochampally
Undergraduate Research Symposium Posters
Biochar (BC) is a carbon-rich material synthesized from the pyrolysis of biomasses and developed to remove soil and wastewater contaminants. The pyrolysis process involves thermally decomposing the organic materials in the absence of oxygen. Biochar has the potential to be an eco-friendly and effective adsorbent for heavy metals and toxic organic compounds. An adsorbent is a material that attracts other substances on its surface, chemically and physically. Walnut shells were chosen for the biochar modification to improve the surface morphology, pore structure, and adsorption capability.
Landscape Materials: Impact On Water Quality At Different Temperatures, Vignesh Tiruvannamalai '24
Landscape Materials: Impact On Water Quality At Different Temperatures, Vignesh Tiruvannamalai '24
Distinguished Student Work
The purpose of this experiment is to analyze how commonly used landscaping materials (wood mulch, rubber mulch, and landscape stones) will affect the quality and chemical composition of runoff water they come into contact with, and how this will be impacted by different temperatures experienced in different climatic regions.
In order to conduct this experiment, always wear safety goggles and gloves when handling experiment materials. First, prepare the landscaping materials and rinse the containers and lids. Then, place the designated amount of landscaping materials in each container and fill each with 2.27 liters of filtered water, subsequently covering them and …
Phosphorus And Metal Cycling In A Drinking Water Source, Amanda Modica
Phosphorus And Metal Cycling In A Drinking Water Source, Amanda Modica
Senior Theses and Projects
This project sought to investigate the cycling of phosphorus and metals in Lake Auburn, a drinking water source, specifically to analyze the impacts of an alum treatment on the lake for the purpose of decreasing concentrations of eutrophication-promoting phosphorus. The alum addition was performed in the summer of 2019 in two phases. Water samples were collected from the surface to the deepest point at five sites around the lake from February 2019 to November 2021. Data showed that the added alum slowly sank to the bottom of the lake. Total and dissolved metals data showed increased metals concentrations at sampling …
Partially Oxidised Boron Nitride As A 2d Nanomaterial For Nanofiltration Applications, Natalia Garcıa Domenech, Aine Coogan, Finn Purcell Milton, María Luisa Casasín Garcia, Adrián Sanz Arjona, Marc Brunet Cabré, Aran Rafferty, Kim Mckelvey, Peter Dunne, Yurii K. Gun'ko
Partially Oxidised Boron Nitride As A 2d Nanomaterial For Nanofiltration Applications, Natalia Garcıa Domenech, Aine Coogan, Finn Purcell Milton, María Luisa Casasín Garcia, Adrián Sanz Arjona, Marc Brunet Cabré, Aran Rafferty, Kim Mckelvey, Peter Dunne, Yurii K. Gun'ko
Articles
Access to clean water has become increasingly scarce in recent years due to various factors, such as increasing population density, urbanisation, and inequality, among others.1 The development of new, inexpensive, and reliable methods for the removal of various impurities and toxins from water is therefore vital. In recent years, the emergence of nanofiltration (NF) membranes has become an exciting prospect for water purification. NF can be described as a type of filtration which exhibits separation characteristics in between reverse osmosis and ultrafiltration, and typically has molecular weight cut-offs in the region of 200–1000 Daltons.2,3 Various nanomaterials have been implemented in …
Identification Of Phosphorous Loading Point Source Facilities To 303(D) Listed Nutrient Impaired Waters Through Watershed Delineation Using Arcgis For Life Cycle Assessment Applications, John Zimmerman
Chemical Engineering Undergraduate Honors Theses
The work done for this project is part of a larger “life cycle assessment (LCA) of novel electrochemical phosphorus recovery technology at the wastewater treatment plant and U.S. watershed scales” (Morrissey 2019). The goal of that LCA is to determine “environmental impacts of implementing electrochemical struvite recovery at the wastewater treatment plant, U.S watershed, and global scales” (Morrissey 2019). This project’s goal is to identify locations deemed more sensitive to eutrophication impacts. The results will be used as part of the life cycle inventory (LCI) accounting for geographically explicit phosphorus flows. The waters identified as impaired were sourced from the …
Ligands For Complexation, Extraction, And Sensing Of Mercury(Ii) For Application To High-Level Waste (Hlw) At The Savannah River Site (Srs), Adenike O. Fasiku
Ligands For Complexation, Extraction, And Sensing Of Mercury(Ii) For Application To High-Level Waste (Hlw) At The Savannah River Site (Srs), Adenike O. Fasiku
FIU Electronic Theses and Dissertations
Mercury (Hg) separation and sensing is of high significance due to Hg(II) environmental mobility and toxicity. Furthermore, the use of Hg in nuclear applications has resulted in its accumulation in several DOE sites, such as in Oak Ridge and Savannah River reservations. Organic mercury species have been found in low activity waste (LAW) streams resulting from high-level waste (HLW) processing at the Savannah River Site (SRS), therefore posing a threat to humans and the environment. Mercury, being a soft Lewis acid, has a strong affinity for softer Lewis bases, such as S- or N-donor ligands. Therefore, we focus on …
Impacts Of Oil And Gas Wastes On Landfill Leachate, Sewage Treatment Plants, And The Environment, Lauren Badertscher
Impacts Of Oil And Gas Wastes On Landfill Leachate, Sewage Treatment Plants, And The Environment, Lauren Badertscher
Electronic Theses and Dissertations
Between January 2011 and March 2021 oil and gas wells in Pennsylvania produced
305,637,795 barrels of liquid waste and 6,992,957 tons of solid waste with the majority from
Marcellus Shale unconventional wells. This waste is not considered hazardous and over 89% of
the solid waste generated by unconventional and conventional oil and gas extraction has been
disposed of in landfills over the past decade. This study examined trends in the quantity of waste
produced and methods of disposal. Landfills accepting this waste were identified and their
general method of leachate treatment, using onsite facilities or offsite at wastewater treatment
plants, …
Laboratory Investigation Of Cyanide Evolution During Reaction Between Hypochlorous Acid And Glycine, Luz Chavez
Laboratory Investigation Of Cyanide Evolution During Reaction Between Hypochlorous Acid And Glycine, Luz Chavez
Electronic Theses, Projects, and Dissertations
Fresh water treatment and conservation is of great importance in a society with a growing population. Ensuring water safety is a crucial task for water treatment plants. Advances in science and technology have allowed for the testing and study of potentially harmful side substances produced by water sanitation methods, one of those substances is cyanide (-CN). Previous research correlated a significant increase of cyanide levels in effluent water sanitized with a chlorination method. Research has also proposed a mechanism for the formation of cyanogen chloride (CNCl) from reactions with amino acids during the chlorination process. Flow injection analysis was chosen …
Dissolved Organic Carbon And The Potential Role To Stream Acidity In The Great Smoky Mountains National Park, Jason R. Brown
Dissolved Organic Carbon And The Potential Role To Stream Acidity In The Great Smoky Mountains National Park, Jason R. Brown
Masters Theses
A substantial societal shift towards environmental awareness has focused research efforts on the impacts of pollution on natural landscapes. Improvements to pollutant regulations and technology have resulted in sizeable reductions of atmospheric deposition of anthropogenic acids, especially nitrates and sulfates, which has altered the role of these ions in the environment. As such, understandings of environmental chemistry dynamics have required regular updating.
Through the National Park Service Vital Signs monitoring program, increases in precipitation pH observed in Great Smoky Mountains National Park (GRSM) has been attributed to the reduction of inorganic acid concentrations. Unfortunately, these improvements have not been uniformly …
Engineered Nanostructured Nitrogen-Doped Carbon Network (Ndc) Electrodes With Unprecedented Cycling Stability For Water Capacitive Deionization In Harsh Conditions, Soha Essam Anwar
Theses and Dissertations
Capacitive deionization (CDI) is a feasible low-cost desalination technique for low-to-medium (brackish) salinity water. However, cycling stability and regeneration of the CDI electrodes are the bottlenecks hindering the practical application of the technology on large scale. Oxidation of the electrodes during the sequential adsorption-desorption processes is one of the most challenging problems hindering their long-term cycling performance. Herein, we demonstrated the ability to design and fabricate exceptionally stable CDI electrodes via a one-pot pyrolysis protocol. The optimized pyrolysis of nitrogen-carbon precursors at different temperatures enabled the fabrication of carbon materials with a controlled amount nitrogen dopant (NDCs) with exceptional cycling …
Effects Of Environmental Change On Ancestral Pueblo Fishing In The Middle Rio Grande, Jonathan W. Dombrosky Dr.
Effects Of Environmental Change On Ancestral Pueblo Fishing In The Middle Rio Grande, Jonathan W. Dombrosky Dr.
Anthropology ETDs
It has long been assumed that fishes were unimportant in the diet of past Pueblo people in the U.S. Southwest. Yet, small numbers of fish remains are consistently recovered from Late pre-Hispanic/Early Historic archaeological sites in the Middle Rio Grande of New Mexico. The end of drought conditions may have impacted food choice and fishing decisions during this time. I use behavioral ecology to understand how fishing could have been an optimal food-getting strategy for Ancestral Pueblo farmers. Stable isotope analysis offers a way to account for environmental change. I provide a refined 13C Suess correction model to support …
Coastal Watershed Monitoring And Management: Geomorphology, Geochemistry, And Hydrologic Modeling Of Los Peñasquitos Creek, Ca, Ravleen Khalsa-Basra
Coastal Watershed Monitoring And Management: Geomorphology, Geochemistry, And Hydrologic Modeling Of Los Peñasquitos Creek, Ca, Ravleen Khalsa-Basra
Theses
Rivers in semi-arid climates are directly influenced by local geographic and hydrologic conditions and impacted by modifications to hydrology via urbanization. Changes can influence erosion, morphology, habitat sustainability, and watershed health. In highly urbanized southern California coastal regions, these rare open spaces provide vital ecosystem services. Los Peñasquitos Creek in San Diego County is one such watershed. Using stream surveying and laboratory methods we quantified channel characteristics, grain size distribution, total metal concentration [M], organic carbon (%OC), and phosphate to longitudinally characterize the creek for improved management. Results identified three distinct reaches in the watershed (upper, middle, lower). Downstream, depth …
The Quantitative Assessment Of Pond Scum: An Examination Of The Biogeochemistry Of Phosphorus Cycling In The Belgrade Lakes, Abbey M. Sykes
The Quantitative Assessment Of Pond Scum: An Examination Of The Biogeochemistry Of Phosphorus Cycling In The Belgrade Lakes, Abbey M. Sykes
Honors Theses
The internal recycling phosphorus in freshwater lake bottom sediments represents a significant source of hypolimnetic phosphorus (P) release for many of Maine’s lakes. In summer months, Maine lakes often thermally stratify and the lake hypolimnion develops anoxia, leading to a reduction in redox potential at the sediment-water interface. These reducing conditions facilitate the reductive dissolution of ferric iron, and, since phosphorus is often present in freshwater lake sediments as solid FeOOH-PO4 complexes, results in release of soluble phosphorus into the water column. Our current study presents field and laboratory data from sediment fractionation extractions designed to quantify concentrations of …
Bow Lake (Station 1 - Ledges) 2021 Water Quality Highlight Report, Amanda Mcquaid, Robert Craycraft
Bow Lake (Station 1 - Ledges) 2021 Water Quality Highlight Report, Amanda Mcquaid, Robert Craycraft
UNH Cooperative Extension
A Water Quality Highlight Report by UNH CE Lakes Lay Monitoring Program for Bow Lake, Station 1 Ledges (Barrington and Northwood, NH) for 2021.
Baboosic Lake 2021 Water Quality Highlight Report, Amanda Mcquaid, Robert Craycraft
Baboosic Lake 2021 Water Quality Highlight Report, Amanda Mcquaid, Robert Craycraft
UNH Cooperative Extension
A Water Quality Highlight Report by UNH CE Lakes Lay Monitoring Program for Baboosic Lake (Amherst and Merrimack, NH) for 2021.
Pine River Pond 2021 Water Quality Highlight Report, Amanda Mcquaid, Robert Craycraft
Pine River Pond 2021 Water Quality Highlight Report, Amanda Mcquaid, Robert Craycraft
UNH Cooperative Extension
No abstract provided.
Lake Ivanhoe 2021 Water Quality Highlight Report, Amanda Mcquaid, Robert Craycraft
Lake Ivanhoe 2021 Water Quality Highlight Report, Amanda Mcquaid, Robert Craycraft
UNH Cooperative Extension
A Water Quality Highlight Report by UNH CE Lakes Lay Monitoring Program for Lake Ivanhoe (Wakefield, NH) for sampling efforts in 2021.
Belleau Lake 2021 Water Quality Highlight Report, Amanda Mcquaid, Robert Craycraft
Belleau Lake 2021 Water Quality Highlight Report, Amanda Mcquaid, Robert Craycraft
UNH Cooperative Extension
A Water Quality Highlight Report by UNH CE Lakes Lay Monitoring Program for Belleau Lake in Wakefield, NH for 2021.