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Full-Text Articles in Chemistry
Formulation To Application: Thermomechanical Characterization Of Flexible Polyimides And The Improvement Of Their Properties Via Chain Interaction, Alejandro Rivera Nicholls
Formulation To Application: Thermomechanical Characterization Of Flexible Polyimides And The Improvement Of Their Properties Via Chain Interaction, Alejandro Rivera Nicholls
USF Tampa Graduate Theses and Dissertations
In this work, Polyimides were synthesized by incorporating an aromatic diamine monomer with a methylene linker, 4,4'-methylenebis(2,6-dimethylaniline) (MBDMA), to make a robust main chain along with aliphatic polyetherdiamine backbone linkers to reduce rigidity. The polymers were designed to exhibit thermal properties in between those of conventional aromatic polyimides and polymers with wholly aliphatic ether diamine links. Through dynamic mechanical analysis and differential scanning calorimetry, it is shown that control of the molar ratios of the aromatic MBDMA and the composition and size of the aliphatic polyetherdiamine can be used to tune the glass transition temperature. The materials were characterized and …
Thermo-Oxidative Degradation Of Hdpe Geomembranes: Effect Of Phenolic Antioxidant And Hindered Amine Light Stabilizer Concentrations, Yasin Kocak
USF Tampa Graduate Theses and Dissertations
High density polyethylene (HDPE) geomembrane is most common geomembrane which is mainly used for civil engineering applications. However, HDPE geomembrane loses its properties under oxidative degradation progress. This study aims to assess geomembranes which have different percentage of phenolic antioxidant and hindered amine light stabilizer (HALS) with under the six months of the thermal-oxidative degradation. The interactions between phenolic antioxidant, HALS and carbon black can affect the mechanical, physical and chemical properties. To monitor these properties, Differential Scanning Calorimetry (DSC), Fourier-transform Infrared Spectroscopy (FTIR), Thermogravimetric Analysis (TGA), Scanning Electron Microscopy coupled with Energy Dispersive X-ray spectroscopy (SEM/EDX), Melt Index tests, …
Conducting Polymer Based Gel Electrolytes For Ph Sensitivity, Aditya Jagannath Kashyap
Conducting Polymer Based Gel Electrolytes For Ph Sensitivity, Aditya Jagannath Kashyap
USF Tampa Graduate Theses and Dissertations
The evaluation of concentration of ions and molecules with the help of biosensors have been regarded as an emerging technology. Bio and chemical sensors have a variety of applications in the field of medicine, military, environmental and food industries alike. With an estimated investment growth of over 4.31% in the development of pH sensors in the next five year, the objective of a developing a robust measurement system is all the more required. The scope of this research is to evaluate the ability of conducting polymer-based gel electrolytes for pH sensitivity, as a function of the transistor characteristics using an …