Open Access. Powered by Scholars. Published by Universities.®
- Keyword
-
- Acrylate (1)
- Bis-alkynyl metallocenes (1)
- Co(I) polymers (1)
- Complementary (1)
- CpCoCb polymers (1)
-
- Double Helix (1)
- Functionalized cyclopentadienyl ligands (1)
- Hydrogen Bond (1)
- Isothermal Titration Calorimetry (1)
- Metallacyclophanes (1)
- NMR Titrations (1)
- Pendent alkyne (1)
- Side-chain metallopolymers (1)
- Substituent Effect (1)
- Supramolecular Polymer (1)
- [2+2] cyclization (1)
- [2]cobaltoarenophanes (1)
Articles 1 - 2 of 2
Full-Text Articles in Chemistry
Double Helical Hydrogen-Bonded Aaa-Ddd Complexes And Supramolecular Polymers, Hong-Bo Wang
Double Helical Hydrogen-Bonded Aaa-Ddd Complexes And Supramolecular Polymers, Hong-Bo Wang
Electronic Thesis and Dissertation Repository
The design and characterization of linear oligomers that self-assemble into double helical structures has been a subject of interest to chemists since the elucidation of the double helix structure of DNA in 1953. Transition metal templates have been widely used in the construction of artificial double helical complexes from linear multidentate ligands. The use of other non-covalent interactions as the driving force in the self-assembly of these types of complexes is less common. Aromatic stacking interactions, anion templates, and salt-bridges have all been applied in this context. The great majority of these investigations have been concerned with the dimerization of …
Exploring The Chemistry Of Cyclopentadienyl-Cobalt-Cyclobutadiene (Cpcocb) Complexes And Synthesis Of Side-Chain Cpcocb Polymers, Preeti Chadha
Exploring The Chemistry Of Cyclopentadienyl-Cobalt-Cyclobutadiene (Cpcocb) Complexes And Synthesis Of Side-Chain Cpcocb Polymers, Preeti Chadha
Electronic Thesis and Dissertation Repository
Synthetic metallopolymers have acquired ample attention recently due to their potential applications as precursors to functional soft materials. Organometallic polymers combine the best of both organic and inorganic polymers. Polyferrocenes comprise the major portion of organometallic polymers. Therefore, quest for new monomeric precursors to organometallic polymers has expediated. One efficient method for obtaining main-chain metallopolymers is by the ring opening polymerization (ROP) of strained cyclic metallacylophanes(MCPs). Organometallic polymers containing cyclopentadienyl-cobalt-cyclobutadiene (CpCoCb) have been targeted since early 1990’s due to their isoelectronic nature (cf. ferrocene) with three major groups working in this area. The early CpCoCb containing polymers were prepared …